93
26. Godula K, Sames D (2006) C-H bond functionalization in complex organic synthesis. Science
312(5770):67–72
27. Labinger JA, Bercaw JE (2002) Understanding and exploiting C-H bond activation. Nature
417(6888):507–514
28. Ritleng V, Sirlin C, Pfeffer M (2002) Ru-, Rh-, and Pd-catalyzed C-C bond formation involving C-H Activation and addition on unsaturated substrates: reactions and mechanistic aspects.
Chem Rev 102(5):1731–1769
29. Shilov AE, Shul'pin GB (1997) Activation of C-H bonds by metal complexes. Chem Rev
97(8):2879–2932
30. Ryabov AD (1990) Mechanisms of intramolecular activation of carbon-hydrogen bonds in
transition-metal complexes. Chem Rev 90(2):403–424
31. Hartwig JF (2008) Carbon-heteroatom bond formation catalysed by organometallic complexes. Nature 455(7211):314–322
32. Bergman RG (2007) Organometallic chemistry: C-H activation. Nature 446(7134):391–393
33. Engle KM, Yu J-Q, Davies HML, Xi Z, You S-L, Shi Z-J (2012) Transition metal-catalyzed
C-H functionalization: synthetically enabling reactions for building molecular complexity.
In: Organic chemistry – breakthroughs and perspectives. Wiley-VCH Verlag GmbH & Co.
KGaA, Weinheim, pp 279–333
34. Ackermann L (2014) Carboxylate-assisted ruthenium-catalyzed alkyne annulations by C-H/
Het-H bond functionalizations. Acc Chem Res 47(2):281–295
35. Daugulis O, Do H-Q, Shabashov D (2009) Palladium- and copper-catalyzed arylation of
carbon-hydrogen bonds. Acc Chem Res 42(8):1074–1086
36. Jia C, Kitamura T, Fujiwara Y (2001) Catalytic functionalization of arenes and alkanes via
C-H bond activation. Acc Chem Res 34(8):633–639
37. Chen X, Engle KM, Wang D-H, Yu J-Q (2009) Palladium(II)-catalyzed C-H activation/C-C
cross-coupling reactions: versatility and practicality. Angew Chem Int Ed 48(28):5094–5115
38. Rouquet G, Chatani N (2013) Catalytic functionalization of C(sp2)-H and C(sp3)-H bonds by
using bidentate directing groups. Angew Chem Int Ed 52(45):11726–11743
39. Colby DA, Bergman RG, Ellman JA (2010) Rhodium-catalyzed C-C bond formation via
heteroatom-directed C-H bond activation. Chem Rev 110(2):624–655
40. Lyons TW, Sanford MS (2010) Palladium-catalyzed ligand-directed C-H functionalization
reactions. Chem Rev 110(2):1147–1169
41. Mkhalid IAI, Barnard JH, Marder TB, Murphy JM, Hartwig JF (2010) C-H activation for the
construction of C-B bonds. Chem Rev 110(2):890–931
42. Ackermann L (2011) Carboxylate-assisted transition-metal-catalyzed C-H bond functionalizations: mechanism and scope. Chem Rev 111(3):1315–1345
43. Davies HML, Du Bois J, Yu J-Q (2011) C-H functionalization in organic synthesis. Chem
Soc Rev 40(4):1855–1856
44. Beck EM, Gaunt MJ (2010) Pd-catalyzed C-H bond functionalization on the indole and pyrrole nucleus. Top Curr Chem 292(C-H Activation):85–121
45. Su Y, Jiao N (2011) Palladium-catalyzed oxidative Heck reaction. Curr Org Chem
15(18):3362–3388
46. Karimi B, Behzadnia H, Elhamifar D, Akhavan PF, Esfahani FK, Zamani A (2010) Transitionmetal- catalyzed oxidative Heck reactions. Synthesis 2010(9):1399–1427
47. Oi S, Fukita S, Inoue Y (1998) Rhodium-catalyzed direct ortho arylation of 2-arylpyridines
with arylstannanes via C-H activation. Chem Commun 22:2439–2440
48. Peterson AA, McNeill K (2006) Catalytic dehalogenation of sp2 C-F and C-Cl bonds in
Fluoro- and chloroalkenes. Organometallics 25(21):4938–4940
49. Kawai H, Kobayashi Y, Oi S, Inoue Y (2008) Direct C-H bond arylation of arenes with aryltin
reagents catalysed by palladium complexes. Chem Commun 12:1464–1466
50. Chen X, Li J-J, Hao X-S, Goodhue CE, Yu J-Q (2006) Palladium-catalyzed alkylation of
aryl C-H bonds with sp3 organotin reagents using benzoquinone as a crucial promoter. J Am
Chem Soc 128(1):78–79
3 Oxidative Coupling Reactions Between Hydrocarbons and Organometallic Reagents…
26. Godula K, Sames D (2006) C-H bond functionalization in complex organic synthesis. Science
312(5770):67–72
27. Labinger JA, Bercaw JE (2002) Understanding and exploiting C-H bond activation. Nature
417(6888):507–514
28. Ritleng V, Sirlin C, Pfeffer M (2002) Ru-, Rh-, and Pd-catalyzed C-C bond formation involving C-H Activation and addition on unsaturated substrates: reactions and mechanistic aspects.
Chem Rev 102(5):1731–1769
29. Shilov AE, Shul'pin GB (1997) Activation of C-H bonds by metal complexes. Chem Rev
97(8):2879–2932
30. Ryabov AD (1990) Mechanisms of intramolecular activation of carbon-hydrogen bonds in
transition-metal complexes. Chem Rev 90(2):403–424
31. Hartwig JF (2008) Carbon-heteroatom bond formation catalysed by organometallic complexes. Nature 455(7211):314–322
32. Bergman RG (2007) Organometallic chemistry: C-H activation. Nature 446(7134):391–393
33. Engle KM, Yu J-Q, Davies HML, Xi Z, You S-L, Shi Z-J (2012) Transition metal-catalyzed
C-H functionalization: synthetically enabling reactions for building molecular complexity.
In: Organic chemistry – breakthroughs and perspectives. Wiley-VCH Verlag GmbH & Co.
KGaA, Weinheim, pp 279–333
34. Ackermann L (2014) Carboxylate-assisted ruthenium-catalyzed alkyne annulations by C-H/
Het-H bond functionalizations. Acc Chem Res 47(2):281–295
35. Daugulis O, Do H-Q, Shabashov D (2009) Palladium- and copper-catalyzed arylation of
carbon-hydrogen bonds. Acc Chem Res 42(8):1074–1086
36. Jia C, Kitamura T, Fujiwara Y (2001) Catalytic functionalization of arenes and alkanes via
C-H bond activation. Acc Chem Res 34(8):633–639
37. Chen X, Engle KM, Wang D-H, Yu J-Q (2009) Palladium(II)-catalyzed C-H activation/C-C
cross-coupling reactions: versatility and practicality. Angew Chem Int Ed 48(28):5094–5115
38. Rouquet G, Chatani N (2013) Catalytic functionalization of C(sp2)-H and C(sp3)-H bonds by
using bidentate directing groups. Angew Chem Int Ed 52(45):11726–11743
39. Colby DA, Bergman RG, Ellman JA (2010) Rhodium-catalyzed C-C bond formation via
heteroatom-directed C-H bond activation. Chem Rev 110(2):624–655
40. Lyons TW, Sanford MS (2010) Palladium-catalyzed ligand-directed C-H functionalization
reactions. Chem Rev 110(2):1147–1169
41. Mkhalid IAI, Barnard JH, Marder TB, Murphy JM, Hartwig JF (2010) C-H activation for the
construction of C-B bonds. Chem Rev 110(2):890–931
42. Ackermann L (2011) Carboxylate-assisted transition-metal-catalyzed C-H bond functionalizations: mechanism and scope. Chem Rev 111(3):1315–1345
43. Davies HML, Du Bois J, Yu J-Q (2011) C-H functionalization in organic synthesis. Chem
Soc Rev 40(4):1855–1856
44. Beck EM, Gaunt MJ (2010) Pd-catalyzed C-H bond functionalization on the indole and pyrrole nucleus. Top Curr Chem 292(C-H Activation):85–121
45. Su Y, Jiao N (2011) Palladium-catalyzed oxidative Heck reaction. Curr Org Chem
15(18):3362–3388
46. Karimi B, Behzadnia H, Elhamifar D, Akhavan PF, Esfahani FK, Zamani A (2010) Transitionmetal- catalyzed oxidative Heck reactions. Synthesis 2010(9):1399–1427
47. Oi S, Fukita S, Inoue Y (1998) Rhodium-catalyzed direct ortho arylation of 2-arylpyridines
with arylstannanes via C-H activation. Chem Commun 22:2439–2440
48. Peterson AA, McNeill K (2006) Catalytic dehalogenation of sp2 C-F and C-Cl bonds in
Fluoro- and chloroalkenes. Organometallics 25(21):4938–4940
49. Kawai H, Kobayashi Y, Oi S, Inoue Y (2008) Direct C-H bond arylation of arenes with aryltin
reagents catalysed by palladium complexes. Chem Commun 12:1464–1466
50. Chen X, Li J-J, Hao X-S, Goodhue CE, Yu J-Q (2006) Palladium-catalyzed alkylation of
aryl C-H bonds with sp3 organotin reagents using benzoquinone as a crucial promoter. J Am
Chem Soc 128(1):78–79
3 Oxidative Coupling Reactions Between Hydrocarbons and Organometallic Reagents…