94
51. Sloan OD, Thornton P (1986) Mixed copper(II)-palladium(II) acetates. Inorg Chim Acta
120(2):173–175
52. Kumaraswamy G, Murthy AN, Pitchaiah A (2010) FeCl3-catalyzed Oxidative allylation of
sp2 and sp3 C-H bond adjacent to a nitrogen atom: easy access to homoallyl tertiary amines.
J Org Chem 75(11):3916–3919
53. Kakiuchi F, Kan S, Igi K, Chatani N, Murai S (2003) A ruthenium-catalyzed reaction of aromatic ketones with arylboronates: a new method for the arylation of aromatic compounds via
C-H bond cleavage. J Am Chem Soc 125(7):1698–1699
54. Kakiuchi F, Matsuura Y, Kan S, Chatani N (2005) A RuH2(CO)(PPh3)3-catalyzed regioselective arylation of aromatic ketones with arylboronates via carbon-hydrogen bond cleavage.
J Am Chem Soc 127(16):5936–5945
55. Chen X, Goodhue CE, Yu J-Q (2006) Palladium-catalyzed alkylation of sp2 and sp3 C-H
bonds with methylboroxine and alkylboronic acids: two distinct C-H activation pathways.
J Am Chem Soc 128(39):12634–12635
56. Wang D-H, Mei T-S, Yu J-Q (2008) Versatile Pd(II)-catalyzed C-H activation/Aryl-Aryl coupling of benzoic and phenyl acetic acids. J Am Chem Soc 130(52):17676–17677
57. Engle KM, Yu J-Q (2013) Developing ligands for palladium(II)-catalyzed C-H functionalization: intimate dialogue between ligand and substrate. J Org Chem 78(18):8927–8955
58. Musaev DG, Figg TM, Kaledin AL (2014) Versatile reactivity of Pd-catalysts: mechanistic
features of the mono-N-protected amino acid ligand and cesium-halide base in Pd-catalyzed
C-H bond functionalization. Chem Soc Rev 43(14):5009–5031
59. Shi B-F, Maugel N, Zhang Y-H, Yu J-Q (2008) PdII-catalyzed enantioselective activation of
C(sp2)-H and C(sp3)-H bonds using monoprotected amino acids as chiral ligands. Angew
Chem Int Ed 47(26):4882–4886
60. Laforteza BN, Chan KSL, Yu J-Q (2015) Enantioselective ortho-C-H cross-coupling of diarylmethylamines with organoborons. Angew Chem Int Ed 54(38):11143–11146
61. Gao D-W, Shi Y-C, Gu Q, Zhao Z-L, You S-L (2013) Enantioselective synthesis of planar
chiral ferrocenes via palladium-catalyzed direct coupling with arylboronic acids. J Am Chem
Soc 135(1):86–89
62. Du Z-J, Guan J, Wu G-J, Xu P, Gao L-X, Han F-S (2015) Pd(II)-catalyzed enantioselective
synthesis of P-stereogenic phosphinamides via desymmetric C-H arylation. J Am Chem Soc
137(2):632–635
63. Shi Z, Li B, Wan X, Cheng J, Fang Z, Cao B, Qin C, Wang Y (2007) Suzuki-Miyaura coupling reaction by PdII-catalyzed aromatic C-H bond activation directed by an N-alkyl acetamino group. Angew Chem Int Ed 46(29):5554–5558
64. Sun C-L, Liu N, Li B-J, Yu D-G, Wang Y, Shi Z-J (2010) Pd-catalyzed C-H functionalizations
of O-methyl oximes with arylboronic acids. Org Lett 12(1):184–187
65. Chu J-H, Chen C-C, Wu M-J (2008) Palladium-catalyzed arylation and alkylation of 3,5- diphenylisoxazole with boronic acids via C-H activation. Organometallics
27(20):5173–5176
66. Kirchberg S, Vogler T, Studer A (2008) Directed palladium-catalyzed oxidative C-H arylation
of (hetero)arenes with arylboronic acids by using TEMPO. Synlett 18:2841–2845
67. Yang S-D, Sun C-L, Fang Z, Li B-J, Li Y-Z, Shi Z-J (2008) Palladium-catalyzed direct arylation of (hetero)arenes with aryl boronic acids. Angew Chem Int Ed 47(8):1473–1476
68. Mochida K, Kawasumi K, Segawa Y, Itami K (2011) Direct arylation of polycyclic aromatic
hydrocarbons through palladium catalysis. J Am Chem Soc 133(28):10716–10719
69. Kirchberg S, Tani S, Ueda K, Yamaguchi J, Studer A, Itami K (2011) Oxidative biaryl coupling of thiophenes and thiazoles with arylboronic acids through palladium catalysis: otherwise difficult C4-selective C-H arylation enabled by boronic acids. Angew Chem Int Ed
50(10):2387–2391
70. Wei Y, Kan J, Wang M, Su W, Hong M (2009) Palladium-catalyzed direct arylation of
electron- deficient polyfluoroarenes with arylboronic acids. Org Lett 11(15):3346–3349
C. He
51. Sloan OD, Thornton P (1986) Mixed copper(II)-palladium(II) acetates. Inorg Chim Acta
120(2):173–175
52. Kumaraswamy G, Murthy AN, Pitchaiah A (2010) FeCl3-catalyzed Oxidative allylation of
sp2 and sp3 C-H bond adjacent to a nitrogen atom: easy access to homoallyl tertiary amines.
J Org Chem 75(11):3916–3919
53. Kakiuchi F, Kan S, Igi K, Chatani N, Murai S (2003) A ruthenium-catalyzed reaction of aromatic ketones with arylboronates: a new method for the arylation of aromatic compounds via
C-H bond cleavage. J Am Chem Soc 125(7):1698–1699
54. Kakiuchi F, Matsuura Y, Kan S, Chatani N (2005) A RuH2(CO)(PPh3)3-catalyzed regioselective arylation of aromatic ketones with arylboronates via carbon-hydrogen bond cleavage.
J Am Chem Soc 127(16):5936–5945
55. Chen X, Goodhue CE, Yu J-Q (2006) Palladium-catalyzed alkylation of sp2 and sp3 C-H
bonds with methylboroxine and alkylboronic acids: two distinct C-H activation pathways.
J Am Chem Soc 128(39):12634–12635
56. Wang D-H, Mei T-S, Yu J-Q (2008) Versatile Pd(II)-catalyzed C-H activation/Aryl-Aryl coupling of benzoic and phenyl acetic acids. J Am Chem Soc 130(52):17676–17677
57. Engle KM, Yu J-Q (2013) Developing ligands for palladium(II)-catalyzed C-H functionalization: intimate dialogue between ligand and substrate. J Org Chem 78(18):8927–8955
58. Musaev DG, Figg TM, Kaledin AL (2014) Versatile reactivity of Pd-catalysts: mechanistic
features of the mono-N-protected amino acid ligand and cesium-halide base in Pd-catalyzed
C-H bond functionalization. Chem Soc Rev 43(14):5009–5031
59. Shi B-F, Maugel N, Zhang Y-H, Yu J-Q (2008) PdII-catalyzed enantioselective activation of
C(sp2)-H and C(sp3)-H bonds using monoprotected amino acids as chiral ligands. Angew
Chem Int Ed 47(26):4882–4886
60. Laforteza BN, Chan KSL, Yu J-Q (2015) Enantioselective ortho-C-H cross-coupling of diarylmethylamines with organoborons. Angew Chem Int Ed 54(38):11143–11146
61. Gao D-W, Shi Y-C, Gu Q, Zhao Z-L, You S-L (2013) Enantioselective synthesis of planar
chiral ferrocenes via palladium-catalyzed direct coupling with arylboronic acids. J Am Chem
Soc 135(1):86–89
62. Du Z-J, Guan J, Wu G-J, Xu P, Gao L-X, Han F-S (2015) Pd(II)-catalyzed enantioselective
synthesis of P-stereogenic phosphinamides via desymmetric C-H arylation. J Am Chem Soc
137(2):632–635
63. Shi Z, Li B, Wan X, Cheng J, Fang Z, Cao B, Qin C, Wang Y (2007) Suzuki-Miyaura coupling reaction by PdII-catalyzed aromatic C-H bond activation directed by an N-alkyl acetamino group. Angew Chem Int Ed 46(29):5554–5558
64. Sun C-L, Liu N, Li B-J, Yu D-G, Wang Y, Shi Z-J (2010) Pd-catalyzed C-H functionalizations
of O-methyl oximes with arylboronic acids. Org Lett 12(1):184–187
65. Chu J-H, Chen C-C, Wu M-J (2008) Palladium-catalyzed arylation and alkylation of 3,5- diphenylisoxazole with boronic acids via C-H activation. Organometallics
27(20):5173–5176
66. Kirchberg S, Vogler T, Studer A (2008) Directed palladium-catalyzed oxidative C-H arylation
of (hetero)arenes with arylboronic acids by using TEMPO. Synlett 18:2841–2845
67. Yang S-D, Sun C-L, Fang Z, Li B-J, Li Y-Z, Shi Z-J (2008) Palladium-catalyzed direct arylation of (hetero)arenes with aryl boronic acids. Angew Chem Int Ed 47(8):1473–1476
68. Mochida K, Kawasumi K, Segawa Y, Itami K (2011) Direct arylation of polycyclic aromatic
hydrocarbons through palladium catalysis. J Am Chem Soc 133(28):10716–10719
69. Kirchberg S, Tani S, Ueda K, Yamaguchi J, Studer A, Itami K (2011) Oxidative biaryl coupling of thiophenes and thiazoles with arylboronic acids through palladium catalysis: otherwise difficult C4-selective C-H arylation enabled by boronic acids. Angew Chem Int Ed
50(10):2387–2391
70. Wei Y, Kan J, Wang M, Su W, Hong M (2009) Palladium-catalyzed direct arylation of
electron- deficient polyfluoroarenes with arylboronic acids. Org Lett 11(15):3346–3349
C. He