92
6. Luo FT, Wang RT (1993) A novel synthesis of cyanoalkynes via iodide-catalyzed cyanation
of terminal acetylenes with cuprous cyanide. Tetrahedron Lett 34(37):5911–5914
7. Luo F-T, Wang M-W, Wang RT (1998) Preparation of cyanoalkynes: 3-phenyl-2propynenitrile (2-propynenitrile, 3-phenyl-). Org Synth 75:146–152
8. Cheng Z-Y, Li W-J, He F, Zhou J-M, Zhu X-F (2007) Synthesis and biological evaluation of
4-aryl-5-cyano-2H-1,2,3-triazoles as inhibitor of HER2 tyrosine kinase. Bioorg Med Chem
15(3):1533–1538
9. Chen M, Zheng X, Li W, He J, Lei A (2010) Palladium-catalyzed aerobic oxidative
cross-coupling reactions of terminal alkynes with alkylzinc reagents. J Am Chem Soc
132(12):4101–4103
10. Fairlamb IJS (2008) π-Acidic alkene ligand effects in Pd-catalysed cross-coupling processes:
exploiting the interaction of dibenzylidene acetone (dba) and related ligands with Pd(0) and
Pd(ii). Org Biomol Chem 6(20):3645–3656
11. Li H-M, Xu C, Duan L-M, Lou X-H, Wang Z-Q, Li Z, Fan Y-T (2013) N-heterocyclic carbene adducts of cyclopalladated ferrocenylpyridine containing chloride or iodide anions: synthesis, crystal structures and application in the coupling of terminal alkynes with arylboronic
acids. Transit Met Chem 38(3):313–318
12. Li L, Nan C, Peng Q, Li Y (2012) Selective synthesis of Cu 2 O nanocrystals as shape- dependent
catalysts for oxidative arylation of phenylacetylene. Chem Eur J 18(34):10491–10496
13. Lu L, Chellan P, Smith GS, Zhang X, Yan H, Mao J (2014) Thiosemicarbazone salicylaldiminato palladium(II)-catalyzed alkynylation couplings between arylboronic acids and alkynes
or alkynyl carboxylic acids. Tetrahedron 70(35):5980–5985
14. Mitsudo K, Shiraga T, J-i M, Suga S, Tanaka H (2010) Electrochemical generation of silver
acetylides from terminal alkynes with a Ag anode and integration into sequential Pd-catalyzed
coupling with arylboronic acids. Chem Commun 46(48):9256–9258
15. Nie X, Liu S, Zong Y, Sun P, Bao J (2011) Facile synthesis of substituted alkynes by nanopalladium catalyzed oxidative cross-coupling reaction of arylboronic acids with terminal
alkynes. J Organomet Chem 696(8):1570–1573
16. Pan C, Luo F, Wang W, Ye Z, Cheng J (2009) Ligand-free copper(I)-catalyzed Sonogashiratype coupling of arylboronic acids with terminal alkynes. Tetrahedron Lett 50(35):5044–5046
17. Truong T, Nguyen CK, Tran TV, Nguyen TT, Phan NTS (2014) Nickel-catalyzed oxidative coupling of alkynes and arylboronic acids using the metal-organic framework
Ni2(BDC)2(DABCO) as an efficient heterogeneous catalyst. Cat Sci Technol 4(5):1276–1285
18. Yang F, Wu Y (2007) Facile synthesis of substituted alkynes by cyclopalladated ferrocenylimine catalyzed cross-coupling of arylboronic acids/esters with terminal alkynes. Eur J Org
Chem 2007(21):3476–3479
19. Yasukawa T, Miyamura H, Kobayashi S (2011) Copper-catalyzed, aerobic oxidative crosscoupling of alkynes with arylboronic acids: remarkable selectivity in 2,6-lutidine media. Org
Biomol Chem 9(18):6208–6210
20. Zhou M-B, Wei W-T, Xie Y-X, Lei Y, Li J-H (2010) Palladium-catalyzed cross-coupling of
electron-poor terminal alkynes with arylboronic acids under ligand-free and aerobic conditions. J Org Chem 75(16):5635–5642
21. Zou G, Zhu J, Tang J (2003) Cross-coupling of arylboronic acids with terminal alkynes in air.
Tetrahedron Lett 44(48):8709–8711
22. Chu L, Qing F-L (2010) Copper-mediated aerobic oxidative trifluoromethylation of terminal
alkynes with Me 3 SiCF 3 . J Am Chem Soc 132(21):7262–7263
23. Arndtsen BA, Bergman RG, Mobley TA, Peterson TH (1995) Selective intermolecular
carbon- hydrogen bond activation by synthetic metal complexes in homogeneous solution.
Acc Chem Res 28(3):154–162
24. Crabtree RH (2003) C-H Activation approaches for the application of molecular recognition
to organometallic chemistry and homogeneous catalysis. Dalton Trans 21:3985–3990
25. Dyker G (1999) Transition metal catalyzed coupling reactions under C-H activation. Angew
Chem Int Ed 38(12):1699–1712
C. He
6. Luo FT, Wang RT (1993) A novel synthesis of cyanoalkynes via iodide-catalyzed cyanation
of terminal acetylenes with cuprous cyanide. Tetrahedron Lett 34(37):5911–5914
7. Luo F-T, Wang M-W, Wang RT (1998) Preparation of cyanoalkynes: 3-phenyl-2propynenitrile (2-propynenitrile, 3-phenyl-). Org Synth 75:146–152
8. Cheng Z-Y, Li W-J, He F, Zhou J-M, Zhu X-F (2007) Synthesis and biological evaluation of
4-aryl-5-cyano-2H-1,2,3-triazoles as inhibitor of HER2 tyrosine kinase. Bioorg Med Chem
15(3):1533–1538
9. Chen M, Zheng X, Li W, He J, Lei A (2010) Palladium-catalyzed aerobic oxidative
cross-coupling reactions of terminal alkynes with alkylzinc reagents. J Am Chem Soc
132(12):4101–4103
10. Fairlamb IJS (2008) π-Acidic alkene ligand effects in Pd-catalysed cross-coupling processes:
exploiting the interaction of dibenzylidene acetone (dba) and related ligands with Pd(0) and
Pd(ii). Org Biomol Chem 6(20):3645–3656
11. Li H-M, Xu C, Duan L-M, Lou X-H, Wang Z-Q, Li Z, Fan Y-T (2013) N-heterocyclic carbene adducts of cyclopalladated ferrocenylpyridine containing chloride or iodide anions: synthesis, crystal structures and application in the coupling of terminal alkynes with arylboronic
acids. Transit Met Chem 38(3):313–318
12. Li L, Nan C, Peng Q, Li Y (2012) Selective synthesis of Cu 2 O nanocrystals as shape- dependent
catalysts for oxidative arylation of phenylacetylene. Chem Eur J 18(34):10491–10496
13. Lu L, Chellan P, Smith GS, Zhang X, Yan H, Mao J (2014) Thiosemicarbazone salicylaldiminato palladium(II)-catalyzed alkynylation couplings between arylboronic acids and alkynes
or alkynyl carboxylic acids. Tetrahedron 70(35):5980–5985
14. Mitsudo K, Shiraga T, J-i M, Suga S, Tanaka H (2010) Electrochemical generation of silver
acetylides from terminal alkynes with a Ag anode and integration into sequential Pd-catalyzed
coupling with arylboronic acids. Chem Commun 46(48):9256–9258
15. Nie X, Liu S, Zong Y, Sun P, Bao J (2011) Facile synthesis of substituted alkynes by nanopalladium catalyzed oxidative cross-coupling reaction of arylboronic acids with terminal
alkynes. J Organomet Chem 696(8):1570–1573
16. Pan C, Luo F, Wang W, Ye Z, Cheng J (2009) Ligand-free copper(I)-catalyzed Sonogashiratype coupling of arylboronic acids with terminal alkynes. Tetrahedron Lett 50(35):5044–5046
17. Truong T, Nguyen CK, Tran TV, Nguyen TT, Phan NTS (2014) Nickel-catalyzed oxidative coupling of alkynes and arylboronic acids using the metal-organic framework
Ni2(BDC)2(DABCO) as an efficient heterogeneous catalyst. Cat Sci Technol 4(5):1276–1285
18. Yang F, Wu Y (2007) Facile synthesis of substituted alkynes by cyclopalladated ferrocenylimine catalyzed cross-coupling of arylboronic acids/esters with terminal alkynes. Eur J Org
Chem 2007(21):3476–3479
19. Yasukawa T, Miyamura H, Kobayashi S (2011) Copper-catalyzed, aerobic oxidative crosscoupling of alkynes with arylboronic acids: remarkable selectivity in 2,6-lutidine media. Org
Biomol Chem 9(18):6208–6210
20. Zhou M-B, Wei W-T, Xie Y-X, Lei Y, Li J-H (2010) Palladium-catalyzed cross-coupling of
electron-poor terminal alkynes with arylboronic acids under ligand-free and aerobic conditions. J Org Chem 75(16):5635–5642
21. Zou G, Zhu J, Tang J (2003) Cross-coupling of arylboronic acids with terminal alkynes in air.
Tetrahedron Lett 44(48):8709–8711
22. Chu L, Qing F-L (2010) Copper-mediated aerobic oxidative trifluoromethylation of terminal
alkynes with Me 3 SiCF 3 . J Am Chem Soc 132(21):7262–7263
23. Arndtsen BA, Bergman RG, Mobley TA, Peterson TH (1995) Selective intermolecular
carbon- hydrogen bond activation by synthetic metal complexes in homogeneous solution.
Acc Chem Res 28(3):154–162
24. Crabtree RH (2003) C-H Activation approaches for the application of molecular recognition
to organometallic chemistry and homogeneous catalysis. Dalton Trans 21:3985–3990
25. Dyker G (1999) Transition metal catalyzed coupling reactions under C-H activation. Angew
Chem Int Ed 38(12):1699–1712
C. He