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133. Lin T, Yang C, Wang Z, Yin H, Lu X, Huang F, Lin J, Xie X, Jiang M (2014) Effective
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134. Feng N, Liu F, Huang M, Zheng A, Wang Q, Chen T, Cao G, Xu J, Fan J, Deng F (2016)
Unravelling the efficient photocatalytic activity of boron-induced Ti
3+ species in the surface
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135. Xing M, Zhang J, Qiu B, Tian B, Anpo M, Che M (2015) A brown mesoporous TiO 2-x /MCF
composite with an extremely high quantum yield of solar energy photocatalysis for H 2
evolution. Small 11(16):1920–1929
136. Xing J, Chen J, Li Y, Yuan W, Zhou Y, Zheng L, Wang H, Hu P, Wang Y, Zhao H, Wang Y,
Yang H (2014) Stable isolated metal atoms as active sites for photocatalytic hydrogen
evolution. Chem Eur J 20(8):2138–2144
137. Yuan X, Wang X, Liu X, Ge H, Yin G, Dong C, Huang F (2016) Ti
3+ -promoted high oxygenreduction activity of Pd nanodots supported by black titania nanobelts. ACS Appl Mater Inter
8(41):27654–27660
138. Bonneviot L, Haller GL (1988) EPR characterization of Ti
3+ ions at the metal-support
interface in PtTiO 2 catalysts. J Catal 113(1):96–105
139. Lian Z, Wang W, Li G, Tian F, Schanze KS, Li H (2016) Pt-enhanced mesoporous Ti
3+ /TiO 2
with rapid bulk to surface electron transfer for photocatalytic hydrogen evolution. ACS Appl
Mater Inter
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(29):295202
122. Yabuuchi N, Kubota K, Dahbi M, Komaba S (2014) Research development on sodium-ion
batteries. Chem Rev 114(23):11636–11682
123. Chen J, Ding Z, Wang C, Hou H, Zhang Y, Wang C, Zou G, Ji X (2016) Black anatase titania
with ultrafast sodium-storage performances stimulated by oxygen vacancies. ACS Appl Mater
Inter 8(14):9142–9151
124. Asahi R, Morikawa T, Ohwaki T, Aoki K, Taga Y (2001) Visible-light photocatalysis in
nitrogen-doped titanium oxides. Science 293(5528):269–271
125. Di Valentin C, Pacchioni G, Selloni A, Livraghi S, Giamello E (2005) Characterization of
paramagnetic species in N-doped TiO 2 powders by EPR spectroscopy and DFT calculations. J
Phys Chem B 109(23):11414–11419
126. Sayed FN, Jayakumar OD, Sasikala R, Kadam RM, Bharadwaj SR, Kienle L, Schürmann U,
Kaps S, Adelung R, Mittal JP, Tyagi AK (2012) Photochemical hydrogen generation using
nitrogen-doped TiO 2 -Pd nanoparticles: facile synthesis and effect of Ti
3+ incorporation. J Phys
Chem C 116(23):12462–12467
127. Hoang S, Berglund SP, Hahn NT, Bard AJ, Mullins CB (2012) Enhancing visible light photooxidation of water with TiO 2 nanowire arrays via cotreatment with H 2 and NH 3 : synergistic
effects between Ti
3+ and N. J Am Chem Soc 134(8):3659–3662
128. Zhou Y, Yi Q, Xing M, Shang L, Zhang T, Zhang J (2016) Graphene modified mesoporous
titania single crystals with controlled and selective photoredox surfaces. Chem Commun 52
(8):1689–1692
129. Chen Y, Cao X, Lin B, Gao B (2013) Origin of the visible-light photoactivity of NH 3 -treated
TiO 2 : effect of nitrogen doping and oxygen vacancies. Appl Surf Sci 264:845–852
130. Zhang K, Zhou W, Chi L, Zhang X, Hu W, Jiang B, Pan K, Tian G, Jiang Z (2016) Black N/HTiO 2 nanoplates with a flower-like hierarchical architecture for photocatalytic hydrogen
evolution. ChemSusChem 9(19):2841–2848
131. Li B, Zhao Z, Zhou Q, Meng B, Meng X, Qiu J (2014) Highly efficient low-temperature
plasma-assisted modification of TiO 2 nanosheets with exposed {001} facets for enhanced
visible-light photocatalytic activity. Chem Eur J 20(45):14763–14770
132. Li G, Li J, Li G, Jiang G (2015) N and Ti
3+ co-doped 3D anatase TiO 2 superstructures
composed of ultrathin nanosheets with enhanced visible light photocatalytic activity. J Mater
Chem A 3(44):22073–22080
133. Lin T, Yang C, Wang Z, Yin H, Lu X, Huang F, Lin J, Xie X, Jiang M (2014) Effective
nonmetal incorporation in black titania with enhanced solar energy utilization. Energy Environ
Sci 7(3):967–972
134. Feng N, Liu F, Huang M, Zheng A, Wang Q, Chen T, Cao G, Xu J, Fan J, Deng F (2016)
Unravelling the efficient photocatalytic activity of boron-induced Ti
3+ species in the surface
layer of TiO 2 . Sci Rep 6:34765
135. Xing M, Zhang J, Qiu B, Tian B, Anpo M, Che M (2015) A brown mesoporous TiO 2-x /MCF
composite with an extremely high quantum yield of solar energy photocatalysis for H 2
evolution. Small 11(16):1920–1929
136. Xing J, Chen J, Li Y, Yuan W, Zhou Y, Zheng L, Wang H, Hu P, Wang Y, Zhao H, Wang Y,
Yang H (2014) Stable isolated metal atoms as active sites for photocatalytic hydrogen
evolution. Chem Eur J 20(8):2138–2144
137. Yuan X, Wang X, Liu X, Ge H, Yin G, Dong C, Huang F (2016) Ti
3+ -promoted high oxygenreduction activity of Pd nanodots supported by black titania nanobelts. ACS Appl Mater Inter
8(41):27654–27660
138. Bonneviot L, Haller GL (1988) EPR characterization of Ti
3+ ions at the metal-support
interface in PtTiO 2 catalysts. J Catal 113(1):96–105
139. Lian Z, Wang W, Li G, Tian F, Schanze KS, Li H (2016) Pt-enhanced mesoporous Ti
3+ /TiO 2
with rapid bulk to surface electron transfer for photocatalytic hydrogen evolution. ACS Appl
Mater Inter
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103
