DOPA (3,4-dihydroxyphenylalanine), 32
Doyle’s catalyst, 146
Dual catalysis, 139
E
Early–late heterobimetallic complexes, 139
Energy, 233
Enol esters, 155
Enynes, 50, 109
Epoxides, ring-opening, 144
Ethylene, 150
C–H activation, 46
carbonylation, 164
dimerization, 158
F
FCAT, 260
[FeFe]-hydrogenases, 236
Fe(0) porphyrins, 260
Fe/Ti, 150
Fe/Zr, 150
Feinberg deficiency criteria, 211
Ferrocene, 151, 152, 170, 246
Fischer–Tropsch synthesis, 167
Formate dehydrogenase (FDH), 233, 243
Frustrated Lewis pairs (FLPs), 142
FTIR spectroscopy, 220
Furyls, 65
G
Glycidyl methacrylate/styrene
copolymerization, 176
Gold, 115–121, 128, 179
H
Hafnocenyl diphosphane, 155
Haloacetophenones, 149
HCo(CO) 4 , 2
Hemitantallocene, 177
Hemititanocene, 175
1-Heptene, 26
Heptynol, 121
N-Heterocyclic carbene (NHC), 73, 83, 95
1-Hexene, 5, 34, 79, 151, 161–177
hydroformylation, 161
trans-4-Hexenyl sulfamate, 93
1-Hexyne, silylformylation, 118
Homogeneous catalysis, 31
Horiuti criteria, 211
HPNPP, phosphodiester transesterification,
144
HRh(CO) 4 , 4
Hydride-carbonyl complexes, 2
Hydrides, 1, 36, 225
Hydroaminations, 126, 226
chiral bimetallic catalysts, 129
Hydrocarboxylation, 124
Hydrocyanations, 226
Hydroelementation, 106, 118
Hydroformylation, 1, 32, 146, 187
Hydrogenases, 233, 235
Hydrogen bonding/deactivation, 225
Hydrogen, elimination, β-, 35
photocatalytic production, 252
production, 244
Hydrophosphinylation, 174
Hydrosilations, 226
I
Imidazolium, 73
Imines, 49, 52, 77, 88, 126
hydroalkynylation, 53
hydrogenation, 49
Indoles, 126
Intermetallic cooperation, 31
Iridium, 31
complexes, homobimetallic, 47
Ir/Ta, 169
Ir/Zr, 169
Isopropanol, dehydrogenation, 52, 54
1-Isopropyl-3-(5,7-dimethyl-1,8-naphthyrid-2yl)imidazole (PIN), 75
Isotopic exchange, 169–172
Isotopic labelling, 204, 222
K
Kalck’s thiolate-bridged rhodium complex, 4
Ketones, α-allylated α,β-unsaturated, 178
cyanosilylation, 144
hydrosilylation, 160
reduction, 141
Kumada coupling, 159, 160, 174
L
Lactams, 85–87
Index
275