Lactides, 152, 153
Lanthanum, 128
Lewis acid/base, 141
Ligands, migration, 31, 35
Linear low-density polyethylene (LLDPE), 175
M
Malonic ester amides, 86
Manganese, 259
Mesocatalysts, 7
Metal acetylides, 106
Metal–ligand cooperation, 59
Metalloenzymes, 104, 144, 234, 261
Metal–metal bonds, 59
Metal nitrides, 59
Methyl-2-acetamido-3-phenylacrylate,
hydrogenation, 167
Methyl diazoacetate, 82
Methyl vinyldiazoacetate, 88
Migratory insertion, 35
MoCu, 256
MoCu-CODH, 240
Mo–Mo, 64
Mo/W, 243
Multiwalled carbon nanotubes
(MWCNTs), 175
N
Naphos, 24
1,8-Naphthyridine, 65
Nickel, 27, 149, 238, 250
Ni-CODHs, 242, 256
[NiFe]-hydrogenases, 238
[NiFeSe]-hydrogenase, 255
Nitrogen atom insertion, 93
Ni/Zr, 173
Nucleophilic substitution, 107
O
1-Octene, 26, 149, 163
1-Octyne, 126, 174
hydrophosphinylation, 174
Olefins, 80, 84
hydroformylation, 146, 147, 164
hydrogenation, 172
polymerization, 165, 175
Oxathiazinane heterocycle, 93
Oxazaborolidine, 141
Oxidative addition/reductive elimination, 34
Oxiranes, ring opening, 177
α-Oxo acids, metallaphotoredox
decarboxylative arylation 149
P
Paddlewheel, 61
Paracyclophane, 67
Pauson–Khand reaction (PKR), 106, 116–118,
148
Pd/Ti, 180
1-Pentene, 2
1-Phenylethanol, 52
Phenylpyridine, 146
Phosphines, 1, 25, 69, 117, 210, 246
Photosensitizer, 253, 255
Photosynthesis, 252
Platinum, 179, 244
Poly[block(LA-minor-CL)-block(CL-minorLA)], 153
Polyethylenes, 149, 158, 173, 176
branched, 149
linear low-density (LLDPE), 175
Porphyrins, 260
Propargylic alcohols, etherification, 156
nucleophilic substitution, 112
Propylene, 26, 150, 165, 173
Protein kinases, 180
Proton reduction, electrocatalysts, 247
Pt/Ti, 180
Pyridyls, 65
Pyrroles, 65, 73, 126, 258
R
Regioselectivity, 210
Rhodium, 1, 32, 50, 146, 161, 187, 216, 225
Rh–Rh, 64
Rh/Ti, Rh/Zr, and Rh/Hf, 161
Ru/Ti, Ru/Zr, Ru/Hf, Ru/Ta, 153
Ruthenium, 50, 54, 109, 143, 148, 154,
179, 254
polypyridyl photosensitizers, 253
S
Saccharinate, 82
Silanes, 106, 118
Silylformylation, 106, 116–118
β-Silylvinyl aldehydes, 117
276
Index
Lanthanum, 128
Lewis acid/base, 141
Ligands, migration, 31, 35
Linear low-density polyethylene (LLDPE), 175
M
Malonic ester amides, 86
Manganese, 259
Mesocatalysts, 7
Metal acetylides, 106
Metal–ligand cooperation, 59
Metalloenzymes, 104, 144, 234, 261
Metal–metal bonds, 59
Metal nitrides, 59
Methyl-2-acetamido-3-phenylacrylate,
hydrogenation, 167
Methyl diazoacetate, 82
Methyl vinyldiazoacetate, 88
Migratory insertion, 35
MoCu, 256
MoCu-CODH, 240
Mo–Mo, 64
Mo/W, 243
Multiwalled carbon nanotubes
(MWCNTs), 175
N
Naphos, 24
1,8-Naphthyridine, 65
Nickel, 27, 149, 238, 250
Ni-CODHs, 242, 256
[NiFe]-hydrogenases, 238
[NiFeSe]-hydrogenase, 255
Nitrogen atom insertion, 93
Ni/Zr, 173
Nucleophilic substitution, 107
O
1-Octene, 26, 149, 163
1-Octyne, 126, 174
hydrophosphinylation, 174
Olefins, 80, 84
hydroformylation, 146, 147, 164
hydrogenation, 172
polymerization, 165, 175
Oxathiazinane heterocycle, 93
Oxazaborolidine, 141
Oxidative addition/reductive elimination, 34
Oxiranes, ring opening, 177
α-Oxo acids, metallaphotoredox
decarboxylative arylation 149
P
Paddlewheel, 61
Paracyclophane, 67
Pauson–Khand reaction (PKR), 106, 116–118,
148
Pd/Ti, 180
1-Pentene, 2
1-Phenylethanol, 52
Phenylpyridine, 146
Phosphines, 1, 25, 69, 117, 210, 246
Photosensitizer, 253, 255
Photosynthesis, 252
Platinum, 179, 244
Poly[block(LA-minor-CL)-block(CL-minorLA)], 153
Polyethylenes, 149, 158, 173, 176
branched, 149
linear low-density (LLDPE), 175
Porphyrins, 260
Propargylic alcohols, etherification, 156
nucleophilic substitution, 112
Propylene, 26, 150, 165, 173
Protein kinases, 180
Proton reduction, electrocatalysts, 247
Pt/Ti, 180
Pyridyls, 65
Pyrroles, 65, 73, 126, 258
R
Regioselectivity, 210
Rhodium, 1, 32, 50, 146, 161, 187, 216, 225
Rh–Rh, 64
Rh/Ti, Rh/Zr, and Rh/Hf, 161
Ru/Ti, Ru/Zr, Ru/Hf, Ru/Ta, 153
Ruthenium, 50, 54, 109, 143, 148, 154,
179, 254
polypyridyl photosensitizers, 253
S
Saccharinate, 82
Silanes, 106, 118
Silylformylation, 106, 116–118
β-Silylvinyl aldehydes, 117
276
Index