Binaphtholates, 143
Binuclear complexes, 31
Binuclear elimination, 187, 219
Bio-inspired metallocomplexes, 233
Biomimicry, 233
Bis(chromium–salen) catalyst, 144
Bis(1-pyrazolyl)methane, 122
Bis(2-pyridyl)amine, 69
Bis(vinylidene)s, 50
Bisbi, 24
Bond activation, 31
Bromopyridonate, 80
Butadiene, 44, 47, 110
ruthenacycle, 110
1-Butene, 26, 158, 168, 175
hydrogenation, 171
2-Butene, 44, 158, 171
C
C–C bond formation, 74
C–H activation, 59, 69
allylic, 59
C–H amination, 61, 92
C–H insertion, 146
Calix [4]arenedicarboxylate, 85
Calixarenes, 86
ε-Caprolactone, 153
Carbene transfer, 84
Carbenoid C–H insertion, 59, 61, 85
Carbon dioxide, reduction, 256
Carbon monoxide, hydrogenation, 167
Carbon monoxide dehydrogenase (CODHs),
233, 240
Carboxylic acids, 106, 118
Catalysis, 103, 233
bifunctional, 139, 141
cooperative, 139
heterobimetallic, 149
homobimetallic, 144
homogeneous, 31
synergistic, 178
two-component, 148
Catalysts, bimetallic, 103
binding sites, 25
Catalytic binuclear elimination reaction
(CBER), 187, 191
Chemometrics, 193
Cisplatin, 179, 180
[Co 5 Rh 2 (CO) 12 ], 4
Co/Ti, Co/Zr, Co/Hf, 157, 173
Connectivity, 195
Cooperativity, 103, 139
Corey–Bakshi–Shibata catalyst, 141
Cr–Cr, 64
Cyanoesters, allylic alkylation, 147
Cyanohydrins, 144
Cyanosilylation, 144
Cyclohexane, 2
Cyclohexanone, α-allylic alkylation, 142
Cyclohexene, 79, 147
hydroformylation, 147, 203
Cyclooctene, 79, 203
Cyclopentadiene, 88
Cyclopentadienyl dilanthanum catalysts, 128
Cyclopentene, 196
Cyclopentenone, 106, 116
Cyclopropanation, 59, 61, 79, 146
Cyclopropenation, 146
Cyclotrimerisation, 107
Cytotoxicity, 180
D
DABCO, 77
Dehydrogenase, carbon monoxide, 233, 240
formate, 233, 235, 243
Dehydrogenation, 52, 59, 76, 78, 152, 155, 178
alcohol, 76
DFT calculations, 1, 9
Diallyltosylamide, 153
Diaminoferrocene, 151
α-Diazoacetamides, 85
2-Diazo-acetoacetamides, 86
Diazocarboxamides, 87
N,N-Dibutyldiazoacetamide, 85
Dicarbonylruthenium carboxylate, 80
N,N-Diethyldiazoacetamide, 85
Diiridium complexes, 31
N,N-Diisopropyldiazoacetamide, 85
Dimerisation, 107
Dimethybutene, hydroformylation, 217
Diphenylacetylene, 47
1,2-Diphenylethane, 48
Diphosphanes, 167
Dirhodium catalyst, dicationic, 7
monocationic, 17
Dirhodium tetraacetate, 61
Dirhodium tetraphosphine,
hydroformylation, 4
Diruthenium compounds, 59, 61, 109, 112
DNA, interaction, 179, 180
274
Index
Binuclear complexes, 31
Binuclear elimination, 187, 219
Bio-inspired metallocomplexes, 233
Biomimicry, 233
Bis(chromium–salen) catalyst, 144
Bis(1-pyrazolyl)methane, 122
Bis(2-pyridyl)amine, 69
Bis(vinylidene)s, 50
Bisbi, 24
Bond activation, 31
Bromopyridonate, 80
Butadiene, 44, 47, 110
ruthenacycle, 110
1-Butene, 26, 158, 168, 175
hydrogenation, 171
2-Butene, 44, 158, 171
C
C–C bond formation, 74
C–H activation, 59, 69
allylic, 59
C–H amination, 61, 92
C–H insertion, 146
Calix [4]arenedicarboxylate, 85
Calixarenes, 86
ε-Caprolactone, 153
Carbene transfer, 84
Carbenoid C–H insertion, 59, 61, 85
Carbon dioxide, reduction, 256
Carbon monoxide, hydrogenation, 167
Carbon monoxide dehydrogenase (CODHs),
233, 240
Carboxylic acids, 106, 118
Catalysis, 103, 233
bifunctional, 139, 141
cooperative, 139
heterobimetallic, 149
homobimetallic, 144
homogeneous, 31
synergistic, 178
two-component, 148
Catalysts, bimetallic, 103
binding sites, 25
Catalytic binuclear elimination reaction
(CBER), 187, 191
Chemometrics, 193
Cisplatin, 179, 180
[Co 5 Rh 2 (CO) 12 ], 4
Co/Ti, Co/Zr, Co/Hf, 157, 173
Connectivity, 195
Cooperativity, 103, 139
Corey–Bakshi–Shibata catalyst, 141
Cr–Cr, 64
Cyanoesters, allylic alkylation, 147
Cyanohydrins, 144
Cyanosilylation, 144
Cyclohexane, 2
Cyclohexanone, α-allylic alkylation, 142
Cyclohexene, 79, 147
hydroformylation, 147, 203
Cyclooctene, 79, 203
Cyclopentadiene, 88
Cyclopentadienyl dilanthanum catalysts, 128
Cyclopentene, 196
Cyclopentenone, 106, 116
Cyclopropanation, 59, 61, 79, 146
Cyclopropenation, 146
Cyclotrimerisation, 107
Cytotoxicity, 180
D
DABCO, 77
Dehydrogenase, carbon monoxide, 233, 240
formate, 233, 235, 243
Dehydrogenation, 52, 59, 76, 78, 152, 155, 178
alcohol, 76
DFT calculations, 1, 9
Diallyltosylamide, 153
Diaminoferrocene, 151
α-Diazoacetamides, 85
2-Diazo-acetoacetamides, 86
Diazocarboxamides, 87
N,N-Dibutyldiazoacetamide, 85
Dicarbonylruthenium carboxylate, 80
N,N-Diethyldiazoacetamide, 85
Diiridium complexes, 31
N,N-Diisopropyldiazoacetamide, 85
Dimerisation, 107
Dimethybutene, hydroformylation, 217
Diphenylacetylene, 47
1,2-Diphenylethane, 48
Diphosphanes, 167
Dirhodium catalyst, dicationic, 7
monocationic, 17
Dirhodium tetraacetate, 61
Dirhodium tetraphosphine,
hydroformylation, 4
Diruthenium compounds, 59, 61, 109, 112
DNA, interaction, 179, 180
274
Index