Index
A
Acetoacetamides, 86
Acetophenone, 52, 149, 166, 169
haloacetophenones, 149
hydrogenation, 52–54
hydrosilylation, 166, 169
transfer hydrogenation, 52
Acetoxylation, 146, 147
Acetylacetone, 142
Alcohols, 74, 106, 118
dehydrogenation, acceptorless, 59, 61,
76, 77
naphthyridine-derived, 74, 75
oxidations, 88
propargylic, 112, 156, 178
Aldehydes, 1, 2, 161, 163, 203
α-allylic alkylation, 142
olefination, 84
silylcyanation, 144
Alkane/alkene coupling, 178
Alkenes, 2, 105
cycloaddition, 106, 113
hydroamination, 126
hydrogenation/isomerization, 168, 171
N-Alkenyl ureas, hydroamination, 131
Alkynes, activation, 103
C–C coupling, 50
cycloaddition, 106, 113, 115
cyclotrimerisation, 107
dimerisation, 109
hydroalkoxylation, 120
hydroamination, 126
hydrocarboxylation, 124
hydrosilylation, 118
silylformylation, 117
2-Alkynylanilines, hydroamination, 126
Allenes, cycloaddition, 106, 113, 115, 126
hydroamination, 126
Allenynes, 115
Allylic C–H activation, 59
Amidinate, 92
Amine boranes, dehydrogenation, 156
Amine thiourea derivatives, 142
Amines, 84, 88, 89, 106, 112, 118, 249–251
Amino-allenes, hydroamination, 130
Anticancer agents, 179
Aryl phosphines, 69
Au/Ti, 180
Auranofin, 179
Axial reactivity, 59
Azide–alkyne cycloaddition, 113
Azides, 91, 144, 200
cycloaddition, 106, 113
Aziridines, 93
carbonylative ring expansion, 177
B
Band-target entropy minimization (BTEM),
220
Benzyl alcohol, 77
1-Benzyl-3-(5,7-dimethyl-1,8-naphthyrid2-yl)imidazole (BIN), 75
Benzylidene amino pyridines, 69
Benzylidene aniline, 48
Benzylidene benzylamine, 77
N-Benzyl-N-isopropyldiazoacetamide, 86
Bifunctional catalysis, 139, 141
Bimetallic complexes, 103, 139
Bimetallic cooperativity, 1
273
A
Acetoacetamides, 86
Acetophenone, 52, 149, 166, 169
haloacetophenones, 149
hydrogenation, 52–54
hydrosilylation, 166, 169
transfer hydrogenation, 52
Acetoxylation, 146, 147
Acetylacetone, 142
Alcohols, 74, 106, 118
dehydrogenation, acceptorless, 59, 61,
76, 77
naphthyridine-derived, 74, 75
oxidations, 88
propargylic, 112, 156, 178
Aldehydes, 1, 2, 161, 163, 203
α-allylic alkylation, 142
olefination, 84
silylcyanation, 144
Alkane/alkene coupling, 178
Alkenes, 2, 105
cycloaddition, 106, 113
hydroamination, 126
hydrogenation/isomerization, 168, 171
N-Alkenyl ureas, hydroamination, 131
Alkynes, activation, 103
C–C coupling, 50
cycloaddition, 106, 113, 115
cyclotrimerisation, 107
dimerisation, 109
hydroalkoxylation, 120
hydroamination, 126
hydrocarboxylation, 124
hydrosilylation, 118
silylformylation, 117
2-Alkynylanilines, hydroamination, 126
Allenes, cycloaddition, 106, 113, 115, 126
hydroamination, 126
Allenynes, 115
Allylic C–H activation, 59
Amidinate, 92
Amine boranes, dehydrogenation, 156
Amine thiourea derivatives, 142
Amines, 84, 88, 89, 106, 112, 118, 249–251
Amino-allenes, hydroamination, 130
Anticancer agents, 179
Aryl phosphines, 69
Au/Ti, 180
Auranofin, 179
Axial reactivity, 59
Azide–alkyne cycloaddition, 113
Azides, 91, 144, 200
cycloaddition, 106, 113
Aziridines, 93
carbonylative ring expansion, 177
B
Band-target entropy minimization (BTEM),
220
Benzyl alcohol, 77
1-Benzyl-3-(5,7-dimethyl-1,8-naphthyrid2-yl)imidazole (BIN), 75
Benzylidene amino pyridines, 69
Benzylidene aniline, 48
Benzylidene benzylamine, 77
N-Benzyl-N-isopropyldiazoacetamide, 86
Bifunctional catalysis, 139, 141
Bimetallic complexes, 103, 139
Bimetallic cooperativity, 1
273