56. Whyman R (1970) Dirhodium octacarbonyl. J Chem Soc D 1194–1195
57. Hanlan LA, Ozin GA (1974) Synthesis using transition metal diatomic molecules. Dirhodium
octacarbonyl and diiridium octacarbonyl. J Am Chem Soc 96(20):6324–6329
58. Vidal JL, Walker WE (1981) Rhodium carbonyl cluster chemistry under high pressure of
carbon monoxide and hydrogen. 3. Synthesis, characterization, and reactivity of HRh(CO) 4 .
Inorg Chem 20(1):249–254
59. Li CZ, Widjaja E, Chew W, Garland M (2002) Rhodium tetracarbonyl hydride: the elusive
metal carbonyl hydride. Angew Chem 114(20):3939–3943
60. King RB, King AD Jr, Iqbal MZ (1979) Alkylrhodium tetracarbonyl derivatives as catalytic
intermediates in homogeneous hydroformylation reactions. An infrared spectroscopic study. J
Am Chem Soc 101(17):4893–4896
61. Li CZ, Guo LF, Garland M (2004) Homogeneous hydroformylation of ethylene catalyzed by
Rh 4 (CO) 12 . The application of BTEM to identify a new class of rhodium carbonyl spectra:
RCORh(CO)3(π-C2H4). Organometallics 23(9):2201–2204
62. Li CZ, Guo LF, Garland M (2004) Identification of rhodium À rhenium nonacarbonyl RhRe
(CO) 9 . Spectroscopic and thermodynamic aspects. Organometallics 23(22):5275–5279
63. Li CZ, Widjaja E, Garland M (2004) Rh 4 (CO) 12 -catalyzed hydroformylation of cyclopentene
promoted with HMn(CO) 5 . Another example of Rh 4 (CO) 12 /HMn(CO) 5 bimetallic catalytic
binuclear elimination. Organometallics 23:4131–4138
64. Garland M, Bor G (1989) Infrared spectroscopic studies on metal carbonyl compounds. 24.
Observation of the infrared spectrum of an acylrhodium tetracarbonyl during the hydroformylation of olefins with rhodium-containing catalyst precursors. Inorg Chem 28(3):410–413
65. Zhang J, Poliakoff M, George MW (2003) Rhodium-catalyzed hydroformylation of alkenes
using in situ high-pressure IR and polymer matrix techniques. Organometallics 22
(8):1612–1618
66. Csontos S, Heil B, Marko L (1974) Hydroformylation of olefins with rhodium carbonyls as
catalysts. IV. Mechanism of the reaction. Ann N Y Acad 239:47–54
67. Wender I, Pino P (1968) Organic syntheses via metal carbonyls, vol 1. Wiley, New York
68. Wender I, Pino P (1977) Organic syntheses via metal carbonyls, vol 2. Wiley, New York
69. Pino P, Oldani F, Consiglio G (1983) On hydrogen activation in the hydroformylation of
olefins with Rh 4 (CO) 12 or Co 2 (CO) 8 as catalyst precursors. J Organomet Chem 250:491–497
70. Garland M, Horvath IT, Bor G, Pino P (1991) Thermodynamic parameters for the formation of
cobalt-rhodium heptacarbonyl and cobalt-rhodium octacarbonyl. Organometallics 10
(3):559–567
71. Fyhr C, Garland M (1993) Phenomenological aspects of homogeneous catalysis. The case of
equilibrium-controlled precursor conversion. Organometallics 12(5):1753–1764
72. Ungvary F (1972) Kinetics and mechanism of the reaction between dicobalt octacarbonyl and
hydrogen. J Organomet Chem 36:363
73. Beletskaya IP, Magomedov GK, Voskoboinikov AZ (1990) Heterometallic catalysts. Cobalt
carbonyl derivatives of lanthanides in catalysis of octene-1 hydroformylation. J Organomet
Chem 385:289–295
74. Li CZ, Widjaja E, Garland M (2003) The Rh 4 (CO) 12 -catalyzed hydroformylation of
3,3-dimethylbut-1-ene promoted with HMn(CO) 5 . Bimetallic catalytic binuclear elimination
as an origin for synergism in homogeneous catalysis. J Am Chem Soc 125:5540–5548
75. Li CZ, Chen L, Garland M (2007) Synchronicity of mononuclear and dinuclear events in
homogeneous catalysis. Hydroformylation of cyclopentene using Rh 4 (CO) 12 and HRe(CO) 5 as
precursors. J Am Chem Soc 129:13327–13334
76. Li CZ, Chen L, Garland M (2008) Synthetic applications of synergism using catalytic
binuclear elimination reactions. Further examples of rhodium-manganese and rhodiumrhenium-catalyzed hydroformylations. Adv Synth Catal 350:679–690
77. Li CZ, Cheng S, Tjahjono M, Schreyer M, Garland M (2010) Concurrent synergism and
inhibition in bimetallic catalysis: catalytic binuclear elimination, solute-solute interactions and
230
M. Garland
57. Hanlan LA, Ozin GA (1974) Synthesis using transition metal diatomic molecules. Dirhodium
octacarbonyl and diiridium octacarbonyl. J Am Chem Soc 96(20):6324–6329
58. Vidal JL, Walker WE (1981) Rhodium carbonyl cluster chemistry under high pressure of
carbon monoxide and hydrogen. 3. Synthesis, characterization, and reactivity of HRh(CO) 4 .
Inorg Chem 20(1):249–254
59. Li CZ, Widjaja E, Chew W, Garland M (2002) Rhodium tetracarbonyl hydride: the elusive
metal carbonyl hydride. Angew Chem 114(20):3939–3943
60. King RB, King AD Jr, Iqbal MZ (1979) Alkylrhodium tetracarbonyl derivatives as catalytic
intermediates in homogeneous hydroformylation reactions. An infrared spectroscopic study. J
Am Chem Soc 101(17):4893–4896
61. Li CZ, Guo LF, Garland M (2004) Homogeneous hydroformylation of ethylene catalyzed by
Rh 4 (CO) 12 . The application of BTEM to identify a new class of rhodium carbonyl spectra:
RCORh(CO)3(π-C2H4). Organometallics 23(9):2201–2204
62. Li CZ, Guo LF, Garland M (2004) Identification of rhodium À rhenium nonacarbonyl RhRe
(CO) 9 . Spectroscopic and thermodynamic aspects. Organometallics 23(22):5275–5279
63. Li CZ, Widjaja E, Garland M (2004) Rh 4 (CO) 12 -catalyzed hydroformylation of cyclopentene
promoted with HMn(CO) 5 . Another example of Rh 4 (CO) 12 /HMn(CO) 5 bimetallic catalytic
binuclear elimination. Organometallics 23:4131–4138
64. Garland M, Bor G (1989) Infrared spectroscopic studies on metal carbonyl compounds. 24.
Observation of the infrared spectrum of an acylrhodium tetracarbonyl during the hydroformylation of olefins with rhodium-containing catalyst precursors. Inorg Chem 28(3):410–413
65. Zhang J, Poliakoff M, George MW (2003) Rhodium-catalyzed hydroformylation of alkenes
using in situ high-pressure IR and polymer matrix techniques. Organometallics 22
(8):1612–1618
66. Csontos S, Heil B, Marko L (1974) Hydroformylation of olefins with rhodium carbonyls as
catalysts. IV. Mechanism of the reaction. Ann N Y Acad 239:47–54
67. Wender I, Pino P (1968) Organic syntheses via metal carbonyls, vol 1. Wiley, New York
68. Wender I, Pino P (1977) Organic syntheses via metal carbonyls, vol 2. Wiley, New York
69. Pino P, Oldani F, Consiglio G (1983) On hydrogen activation in the hydroformylation of
olefins with Rh 4 (CO) 12 or Co 2 (CO) 8 as catalyst precursors. J Organomet Chem 250:491–497
70. Garland M, Horvath IT, Bor G, Pino P (1991) Thermodynamic parameters for the formation of
cobalt-rhodium heptacarbonyl and cobalt-rhodium octacarbonyl. Organometallics 10
(3):559–567
71. Fyhr C, Garland M (1993) Phenomenological aspects of homogeneous catalysis. The case of
equilibrium-controlled precursor conversion. Organometallics 12(5):1753–1764
72. Ungvary F (1972) Kinetics and mechanism of the reaction between dicobalt octacarbonyl and
hydrogen. J Organomet Chem 36:363
73. Beletskaya IP, Magomedov GK, Voskoboinikov AZ (1990) Heterometallic catalysts. Cobalt
carbonyl derivatives of lanthanides in catalysis of octene-1 hydroformylation. J Organomet
Chem 385:289–295
74. Li CZ, Widjaja E, Garland M (2003) The Rh 4 (CO) 12 -catalyzed hydroformylation of
3,3-dimethylbut-1-ene promoted with HMn(CO) 5 . Bimetallic catalytic binuclear elimination
as an origin for synergism in homogeneous catalysis. J Am Chem Soc 125:5540–5548
75. Li CZ, Chen L, Garland M (2007) Synchronicity of mononuclear and dinuclear events in
homogeneous catalysis. Hydroformylation of cyclopentene using Rh 4 (CO) 12 and HRe(CO) 5 as
precursors. J Am Chem Soc 129:13327–13334
76. Li CZ, Chen L, Garland M (2008) Synthetic applications of synergism using catalytic
binuclear elimination reactions. Further examples of rhodium-manganese and rhodiumrhenium-catalyzed hydroformylations. Adv Synth Catal 350:679–690
77. Li CZ, Cheng S, Tjahjono M, Schreyer M, Garland M (2010) Concurrent synergism and
inhibition in bimetallic catalysis: catalytic binuclear elimination, solute-solute interactions and
230
M. Garland