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32. Broussard ME, Juma B, Train SG, Peng WJ, Laneman SA, Stanley GG (1993) A bimetallic
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33. Hansen KB, Leighton JL, Jacobsen EN (1996) On the mechanism of asymmetric nucleophilic
ring-opening of epoxides catalyzed by (salen)CrIII complexes. J Am Chem Soc
118:10924–10925
34. Schaus SE, Jacobsen EN (2000) Asymmetric ring opening of meso epoxides with TMSCN
catalyzed by (pybox)lanthanide complexes. Org Lett 2:1001–1004
35. Whyman R (1974) In situ infrared spectral studies on the cobalt carbonyl-catalysed hydroformylation of olefins. J Organomet Chem 66(1):C23–C25
36. Whyman R (1974) The hydroformylation of olefins catalysed by cobalt carbonyls: a high
pressure infrared spectral study. J Organomet Chem 81(1):97–106
37. Alemdaro glu NH, Penninger ML, Oltay E (1976) Study of the mechanism of hydroformylation
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38. Mirbach MF (1984) On the mechanism of the Co 2 (CO) 8 catalyzed hydroformylation of olefins
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97:798–810
41. Bor G, Noack K (1974) On the infrared spectrum of dicobalt octacarbonyl. Results of
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CO
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42. Bor G, Dietler UK, Noack K (1976) High temperature infrared spectrum of dicobalt
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43. Hieber W, Mu ¨hlbauer F, Ehmann EA (1932) Derivate des Kobalt- und Nickelcarbonyls. Ber
Dtsch Chem Ges 65(7):1090
44. Roelen O (1938) Process for preparing valuable oxo products. Patent Germany, 849.548
45. Pino P, Ercoli R, Calderazzo F (1955) Sinntesi di aldeidid a temperature ambiente per reazione
fra olefin dicobalto-ottacarrbonile e idrogeno. Chim Ind 37:782
46. Kirch L, Orchin M (1959) On the mechanism for the Oxo reaction. J Am Chem Soc
81:3597–3599
47. Natta G, Ercoli R, Castelano S (1955) Cinetica dell’ossosintesi. Chim Ind 37:6
48. Falbe J (ed) (1980) New syntheses with carbon monoxide. Springer, Heidelberg
49. Liu G, Volken R, Garland M (1999) Unmodified rhodium-catalyzed hydroformylation of
alkenes using tetrarhodium dodecacarbonyl. The infrared characterization of 15 acyl rhodium
tetracarbonyl intermediates. Organometallics 18(17):3429–3436
50. Feng J, Garland M (1999) Unmodified homogeneous rhodium-catalyzed hydroformylation of
styrene. The detailed kinetics of the regioselective synthesis. Organometallics 18(3):417–427
51. Feng J, Garland M (1999) The unmodified homogeneous rhodium-catalyzed hydroformylation
of cyclohexene and the search for monometallic catalytic binuclear elimination. Organometallics 18(8):1542–1546
52. Liu G, Li CZ, Guo LF, Garland M (2006) Experimental evidence for a significant
homometallic catalytic binuclear elimination reaction: Linear-quadratic kinetics in the rhodium catalyzed hydroformylation of cyclooctene. J Catal 237(1):67–78
53. Wei CH, Dahl LF (1966) Molecular structures of triiron dodecacarbonyl and tetracobalt
dodecacarbonyl. J Am Chem Soc 88:1821–1822
54. Corey ER, Dahl LF, Beck W (1963) Rh6(CO)16 and its identity with previously reported Rh4
(CO)11. J Am Chem Soc 85:1202–1203
55. Allian AD, Garland M (2005) Spectral resolution of fluxional organometallics. The observation and FTIR characterization of all-terminal Rh 4 (CO) 12 . Dalton Trans 1957–1965
The Catalytic Binuclear Elimination Reaction: Importance of Non-linear. . .
229
N Y Acad Sci 213:5
32. Broussard ME, Juma B, Train SG, Peng WJ, Laneman SA, Stanley GG (1993) A bimetallic
hydroformylation catalyst: high regioselectivity and reactivity through homobimetallic
cooperativity. Science 260:1784–1788
33. Hansen KB, Leighton JL, Jacobsen EN (1996) On the mechanism of asymmetric nucleophilic
ring-opening of epoxides catalyzed by (salen)CrIII complexes. J Am Chem Soc
118:10924–10925
34. Schaus SE, Jacobsen EN (2000) Asymmetric ring opening of meso epoxides with TMSCN
catalyzed by (pybox)lanthanide complexes. Org Lett 2:1001–1004
35. Whyman R (1974) In situ infrared spectral studies on the cobalt carbonyl-catalysed hydroformylation of olefins. J Organomet Chem 66(1):C23–C25
36. Whyman R (1974) The hydroformylation of olefins catalysed by cobalt carbonyls: a high
pressure infrared spectral study. J Organomet Chem 81(1):97–106
37. Alemdaro glu NH, Penninger ML, Oltay E (1976) Study of the mechanism of hydroformylation
at industrial reaction conditions. Monatsh Chem 107(4):1153–1165
38. Mirbach MF (1984) On the mechanism of the Co 2 (CO) 8 catalyzed hydroformylation of olefins
in hydrocarbon solvents. A high pressure UV and IR study. J Organomet Chem 265
(2):205–213
39. Mond L, Hirzt H, Cowap MD (1910) Einige neue metallkarbonyle. Z Anorg Allg Chem
68:207–219
40. Mond L, Hirzt H, Cowap MD (1910) LIV.—some new metallic carbonyls. J Chem Soc Trans
97:798–810
41. Bor G, Noack K (1974) On the infrared spectrum of dicobalt octacarbonyl. Results of
13
CO
enrichment studies. J Organomet Chem 64:367–373
42. Bor G, Dietler UK, Noack K (1976) High temperature infrared spectrum of dicobalt
octacarbonyl: predominance of the third isomer. J Chem Soc Chem Commun 914–916
43. Hieber W, Mu ¨hlbauer F, Ehmann EA (1932) Derivate des Kobalt- und Nickelcarbonyls. Ber
Dtsch Chem Ges 65(7):1090
44. Roelen O (1938) Process for preparing valuable oxo products. Patent Germany, 849.548
45. Pino P, Ercoli R, Calderazzo F (1955) Sinntesi di aldeidid a temperature ambiente per reazione
fra olefin dicobalto-ottacarrbonile e idrogeno. Chim Ind 37:782
46. Kirch L, Orchin M (1959) On the mechanism for the Oxo reaction. J Am Chem Soc
81:3597–3599
47. Natta G, Ercoli R, Castelano S (1955) Cinetica dell’ossosintesi. Chim Ind 37:6
48. Falbe J (ed) (1980) New syntheses with carbon monoxide. Springer, Heidelberg
49. Liu G, Volken R, Garland M (1999) Unmodified rhodium-catalyzed hydroformylation of
alkenes using tetrarhodium dodecacarbonyl. The infrared characterization of 15 acyl rhodium
tetracarbonyl intermediates. Organometallics 18(17):3429–3436
50. Feng J, Garland M (1999) Unmodified homogeneous rhodium-catalyzed hydroformylation of
styrene. The detailed kinetics of the regioselective synthesis. Organometallics 18(3):417–427
51. Feng J, Garland M (1999) The unmodified homogeneous rhodium-catalyzed hydroformylation
of cyclohexene and the search for monometallic catalytic binuclear elimination. Organometallics 18(8):1542–1546
52. Liu G, Li CZ, Guo LF, Garland M (2006) Experimental evidence for a significant
homometallic catalytic binuclear elimination reaction: Linear-quadratic kinetics in the rhodium catalyzed hydroformylation of cyclooctene. J Catal 237(1):67–78
53. Wei CH, Dahl LF (1966) Molecular structures of triiron dodecacarbonyl and tetracobalt
dodecacarbonyl. J Am Chem Soc 88:1821–1822
54. Corey ER, Dahl LF, Beck W (1963) Rh6(CO)16 and its identity with previously reported Rh4
(CO)11. J Am Chem Soc 85:1202–1203
55. Allian AD, Garland M (2005) Spectral resolution of fluxional organometallics. The observation and FTIR characterization of all-terminal Rh 4 (CO) 12 . Dalton Trans 1957–1965
The Catalytic Binuclear Elimination Reaction: Importance of Non-linear. . .
229