a hetero-bimetallic hydrogen-bonded complex in Rh-Mo hydroformylations. J Am Chem Soc
2010:4589–4599
78. Li CZ, Chen L, Widjaja E, Garland M (2010) The catalytic binuclear elimination reaction:
confirmation from in situ FTIR studies of homogeneous rhodium catalyzed hydroformylation.
Catal Today 155:261–265
79. Li CZ, Gao F, Cheng S, Tjahjono M, van Meurs M, Tay BY, Jacob C, Guo LF, Garland M
(2011) From stoichiometric to catalytic binuclear elimination in Rh–W hydroformylations.
Identification of two new heterobimetallic intermediates. Organometallics 30:4292–4296
80. Trost B (1991) The atom economy – a search for synthetic efficiency. Science 254:1471–1477
81. Noyes RM, Furrow SD (1982) The oscillatory Briggs–Rauscher reaction. 3. A skeleton
mechanism for oscillations. J Am Chem Soc 104(1):45–48
82. Turing AM (1952) The chemical basis of morphogenesis. Philos Trans R Soc B 237:37–72
83. Feinberg M (1995) The existence and uniqueness of steady states for a class of chemical
reaction networks. Arch Ration Mech Anal 132:311–370
84. Wegscheider R (1901) U ¨ ber simultane Gleichgewichte und die Beziehungen zwischen
Thermodynamik und Reactionskinetik homogener Systeme. Monatsh Chem 32(8):849–906
85. Garland M (1993) Heterometallic clusters as catalyst precursors. Synergism arising from the
facile generation of a reactive fragment. Organometallics 12(2):535–543
86. Liu G, Hakimifard M, Garland M (2001) An in situ spectroscopic study of the ruthenium
catalyzed carbonylation of piperidine starting with triruthenium dodecacarbonyl: the importance of path dependence in homogeneous catalysis. J Mol Catal A Chem 168:33–37
87. Haynes A, Maitlis PM, Morris GE, Sunley GJ, Adams H, Badger PW, Bowers CM, Cook DB,
Elliott PIP, Ghaffar T, Green H, Griffin TR, Payne M, Pearson JM, Taylor JM, Vickers PW,
Watt RJ (2004) Mechanistic studies of the cativa process. J Am Chem Soc 2004
(126):2847–2861
88. James BR (1973) Homogeneous hydrogenation. Wiley, New York
89. Spindler F, Bor G, Dietler UK, Pino P (1981) The formation of a new mixed cobalt rhodium
carbonyl from Co 2 (CO) 8 and Rh 4 (CO) 12 : infrared spectroscopic characterization under carbon
monoxide pressure. J Organomet Chem 213:303–312
90. Horvath IT, Bor G, Garland M, Pino P (1986) Cobalt-rhodium heptacarbonyl: a coordinatively
unsaturated dinuclear metal carbonyl. Organometallics 5(7):1441–1445
91. Horvath IT, Bor G, Garland M, Pino P (1988) Low temperature activation of molecular
hydrogen in CO/H 2 mixtures in the presence of CoRh(CO) 7 . J Organomet Chem 358:C17–C22
92. Garland M, Pino P (1990) Kinetics of molecular hydrogen activation by cobaltrhodium
heptacarbonyl. Organometallics 9(6):1943–1949
93. Kla ¨hn M, Garland M (2015) On the mechanism of the catalytic binuclear elimination reaction
in hydroformylation systems. ACS Catal 5:2301–2316
The Catalytic Binuclear Elimination Reaction: Importance of Non-linear. . .
231
2010:4589–4599
78. Li CZ, Chen L, Widjaja E, Garland M (2010) The catalytic binuclear elimination reaction:
confirmation from in situ FTIR studies of homogeneous rhodium catalyzed hydroformylation.
Catal Today 155:261–265
79. Li CZ, Gao F, Cheng S, Tjahjono M, van Meurs M, Tay BY, Jacob C, Guo LF, Garland M
(2011) From stoichiometric to catalytic binuclear elimination in Rh–W hydroformylations.
Identification of two new heterobimetallic intermediates. Organometallics 30:4292–4296
80. Trost B (1991) The atom economy – a search for synthetic efficiency. Science 254:1471–1477
81. Noyes RM, Furrow SD (1982) The oscillatory Briggs–Rauscher reaction. 3. A skeleton
mechanism for oscillations. J Am Chem Soc 104(1):45–48
82. Turing AM (1952) The chemical basis of morphogenesis. Philos Trans R Soc B 237:37–72
83. Feinberg M (1995) The existence and uniqueness of steady states for a class of chemical
reaction networks. Arch Ration Mech Anal 132:311–370
84. Wegscheider R (1901) U ¨ ber simultane Gleichgewichte und die Beziehungen zwischen
Thermodynamik und Reactionskinetik homogener Systeme. Monatsh Chem 32(8):849–906
85. Garland M (1993) Heterometallic clusters as catalyst precursors. Synergism arising from the
facile generation of a reactive fragment. Organometallics 12(2):535–543
86. Liu G, Hakimifard M, Garland M (2001) An in situ spectroscopic study of the ruthenium
catalyzed carbonylation of piperidine starting with triruthenium dodecacarbonyl: the importance of path dependence in homogeneous catalysis. J Mol Catal A Chem 168:33–37
87. Haynes A, Maitlis PM, Morris GE, Sunley GJ, Adams H, Badger PW, Bowers CM, Cook DB,
Elliott PIP, Ghaffar T, Green H, Griffin TR, Payne M, Pearson JM, Taylor JM, Vickers PW,
Watt RJ (2004) Mechanistic studies of the cativa process. J Am Chem Soc 2004
(126):2847–2861
88. James BR (1973) Homogeneous hydrogenation. Wiley, New York
89. Spindler F, Bor G, Dietler UK, Pino P (1981) The formation of a new mixed cobalt rhodium
carbonyl from Co 2 (CO) 8 and Rh 4 (CO) 12 : infrared spectroscopic characterization under carbon
monoxide pressure. J Organomet Chem 213:303–312
90. Horvath IT, Bor G, Garland M, Pino P (1986) Cobalt-rhodium heptacarbonyl: a coordinatively
unsaturated dinuclear metal carbonyl. Organometallics 5(7):1441–1445
91. Horvath IT, Bor G, Garland M, Pino P (1988) Low temperature activation of molecular
hydrogen in CO/H 2 mixtures in the presence of CoRh(CO) 7 . J Organomet Chem 358:C17–C22
92. Garland M, Pino P (1990) Kinetics of molecular hydrogen activation by cobaltrhodium
heptacarbonyl. Organometallics 9(6):1943–1949
93. Kla ¨hn M, Garland M (2015) On the mechanism of the catalytic binuclear elimination reaction
in hydroformylation systems. ACS Catal 5:2301–2316
The Catalytic Binuclear Elimination Reaction: Importance of Non-linear. . .
231