89. Goffri S, Muller C, Stingelin-Stutzmann N, Breiby DW, Radano CP, Andreasen JW,
Thompson R, Janssen RAJ, Nielsen MM, Smith P et al (2006) Multicomponent semiconducting polymer systems with low crystallization-induced percolation threshold. Nat Mater
5:950–956
90. Kim FS, Jenekhe SA (2012) Charge transport in poly(3-butylthiophene) nanowires and their
nanocomposites with an insulating polymer. Macromolecules 45:7514–7519
91. Kim HC, Park SM, Hinsberg WD (2010) Block copolymer based nanostructures: materials,
processes, and applications to electronics. Chem Rev 110:146–177
92. Liu J, Haynes D, Balliet C, Zhang R, Kowalewski T, McCullough RD (2012) Self encapsulated poly(3-hexylthiophene)-poly(fluorinated alkyl methacrylate) rod-coil block copolymers
with high field effect mobilities on bare Sio2. Adv Funct Mater 22:1024–1032
93. Yu X, Xiao K, Chen J, Lavrik NV, Hong K, Sumpter BG, Geohegan DB (2011) Highperformance field-effect transistors based on polystyrene-B-poly(3-hexylthiophene) diblock
copolymers. Acs Nano 5:3559–3567
94. Sauve ´ G, McCullough RD (2007) High field-effect mobilities for diblock copolymers of poly
(3-hexylthiophene) and poly(methyl acrylate). Adv Mater 19:1822–1825
95. Lee J-Y, Lin C-J, Lo C-T, Tsai J-C, Chen W-C (2013) Synthesis, morphology, and fieldeffect transistor characteristics of crystalline diblock copolymers consisted of poly
(3-hexylthiophene) and syndiotactic polypropylene. Macromolecules 46:3005–3014
96. Lin J-C, Lee W-Y, Kuo C-C, Li C, Mezzenga R, Chen W-C (2012) Synthesis, morphology,
and field-effect transistor characteristics of new crystalline–crystalline diblock copolymers of
poly(3-hexylthiophene-block-steryl acrylate). J Polym Sci A Polym Chem 50:686–695
97. Mu ¨ller C, Goffri S, Breiby DW, Andreasen JW, Chanzy HD, Janssen RAJ, Nielsen MM,
Radano CP, Sirringhaus H, Smith P et al (2007) Tough, semiconducting polyethylene-poly
(3-hexylthiophene) diblock copolymers. Adv Funct Mater 17:2674–2679
98. Radano CP, Scherman OA, Stingelin-Stutzmann N, Mu ¨ller C, Breiby DW, Smith P, Janssen
RAJ, Meijer EW (2005) Crystalline–crystalline block copolymers of regioregular poly
(3-hexylthiophene) and polyethylene by ring-opening metathesis polymerization. J Am
Chem Soc 127:12502–12503
99. Arias AC, Endicott F, Street RA (2006) Surface-induced self-encapsulation of polymer thinfilm transistors. Adv Mater 18:2900–2904
100. Abdou MSA, Orfino FP, Son Y, Holdcroft S (1997) Interaction of oxygen with conjugated
polymers: charge transfer complex formation with poly(3-alkylthiophenes). J Am Chem Soc
119:4518–4524
101. Liao H-H, Yang C-M, Liu C-C, Horng S-F, Meng H-F, Shy J-T (2008) Dynamics and
reversibility of oxygen doping and De-doping for conjugated polymer. J Appl Phys
103:104506–104508
102. Liu C-C, Yang C-M, Liu W-H, Liao H-H, Horng S-F, Meng H-F (2009) Interface effect of
oxygen doping in polythiophene. Synth Met 159:1131–1134
103. Sperlich A, Kraus H, Deibel C, Blok H, Schmidt J, Dyakonov V (2011) Reversible and
irreversible interactions of poly(3-hexylthiophene) with oxygen studied by spin-sensitive
methods. J Phys Chem B 115:13513–13518
104. Ong BS, Wu YL, Liu P, Gardner S (2004) High-performance semiconducting polythiophenes
for organic thin-film transistors. J Am Chem Soc 126:3378–3379
105. Xia Y, Zhang W, Ha M, Cho JH, Renn MJ, Kim CH, Frisbie CD (2010) Printed sub-2V gelelectrolyte-gated polymer transistors and circuits. Adv Funct Mater 20:587–594
106. Wang S, Ha M, Manno M, Daniel Frisbie C, Leighton C (2012) Hopping transport and the
hall effect near the insulator–metal transition in electrochemically gated poly
(3-hexylthiophene) transistors. Nat Commun 3:1210
107. Li J, Zhao Y, Tan HS, Guo Y, Di C-A, Yu G, Liu Y, Lin M, Lim SH, Zhou Y et al (2012) A
stable solution-processed polymer semiconductor with record high-mobility for printed
transistors. Sci Rep 2:754
136
J. Zaumseil
Thompson R, Janssen RAJ, Nielsen MM, Smith P et al (2006) Multicomponent semiconducting polymer systems with low crystallization-induced percolation threshold. Nat Mater
5:950–956
90. Kim FS, Jenekhe SA (2012) Charge transport in poly(3-butylthiophene) nanowires and their
nanocomposites with an insulating polymer. Macromolecules 45:7514–7519
91. Kim HC, Park SM, Hinsberg WD (2010) Block copolymer based nanostructures: materials,
processes, and applications to electronics. Chem Rev 110:146–177
92. Liu J, Haynes D, Balliet C, Zhang R, Kowalewski T, McCullough RD (2012) Self encapsulated poly(3-hexylthiophene)-poly(fluorinated alkyl methacrylate) rod-coil block copolymers
with high field effect mobilities on bare Sio2. Adv Funct Mater 22:1024–1032
93. Yu X, Xiao K, Chen J, Lavrik NV, Hong K, Sumpter BG, Geohegan DB (2011) Highperformance field-effect transistors based on polystyrene-B-poly(3-hexylthiophene) diblock
copolymers. Acs Nano 5:3559–3567
94. Sauve ´ G, McCullough RD (2007) High field-effect mobilities for diblock copolymers of poly
(3-hexylthiophene) and poly(methyl acrylate). Adv Mater 19:1822–1825
95. Lee J-Y, Lin C-J, Lo C-T, Tsai J-C, Chen W-C (2013) Synthesis, morphology, and fieldeffect transistor characteristics of crystalline diblock copolymers consisted of poly
(3-hexylthiophene) and syndiotactic polypropylene. Macromolecules 46:3005–3014
96. Lin J-C, Lee W-Y, Kuo C-C, Li C, Mezzenga R, Chen W-C (2012) Synthesis, morphology,
and field-effect transistor characteristics of new crystalline–crystalline diblock copolymers of
poly(3-hexylthiophene-block-steryl acrylate). J Polym Sci A Polym Chem 50:686–695
97. Mu ¨ller C, Goffri S, Breiby DW, Andreasen JW, Chanzy HD, Janssen RAJ, Nielsen MM,
Radano CP, Sirringhaus H, Smith P et al (2007) Tough, semiconducting polyethylene-poly
(3-hexylthiophene) diblock copolymers. Adv Funct Mater 17:2674–2679
98. Radano CP, Scherman OA, Stingelin-Stutzmann N, Mu ¨ller C, Breiby DW, Smith P, Janssen
RAJ, Meijer EW (2005) Crystalline–crystalline block copolymers of regioregular poly
(3-hexylthiophene) and polyethylene by ring-opening metathesis polymerization. J Am
Chem Soc 127:12502–12503
99. Arias AC, Endicott F, Street RA (2006) Surface-induced self-encapsulation of polymer thinfilm transistors. Adv Mater 18:2900–2904
100. Abdou MSA, Orfino FP, Son Y, Holdcroft S (1997) Interaction of oxygen with conjugated
polymers: charge transfer complex formation with poly(3-alkylthiophenes). J Am Chem Soc
119:4518–4524
101. Liao H-H, Yang C-M, Liu C-C, Horng S-F, Meng H-F, Shy J-T (2008) Dynamics and
reversibility of oxygen doping and De-doping for conjugated polymer. J Appl Phys
103:104506–104508
102. Liu C-C, Yang C-M, Liu W-H, Liao H-H, Horng S-F, Meng H-F (2009) Interface effect of
oxygen doping in polythiophene. Synth Met 159:1131–1134
103. Sperlich A, Kraus H, Deibel C, Blok H, Schmidt J, Dyakonov V (2011) Reversible and
irreversible interactions of poly(3-hexylthiophene) with oxygen studied by spin-sensitive
methods. J Phys Chem B 115:13513–13518
104. Ong BS, Wu YL, Liu P, Gardner S (2004) High-performance semiconducting polythiophenes
for organic thin-film transistors. J Am Chem Soc 126:3378–3379
105. Xia Y, Zhang W, Ha M, Cho JH, Renn MJ, Kim CH, Frisbie CD (2010) Printed sub-2V gelelectrolyte-gated polymer transistors and circuits. Adv Funct Mater 20:587–594
106. Wang S, Ha M, Manno M, Daniel Frisbie C, Leighton C (2012) Hopping transport and the
hall effect near the insulator–metal transition in electrochemically gated poly
(3-hexylthiophene) transistors. Nat Commun 3:1210
107. Li J, Zhao Y, Tan HS, Guo Y, Di C-A, Yu G, Liu Y, Lin M, Lim SH, Zhou Y et al (2012) A
stable solution-processed polymer semiconductor with record high-mobility for printed
transistors. Sci Rep 2:754
136
J. Zaumseil