222. Zitlalpopoca-Soriano AG, Vivaldo-Lima E, Flores-Tlacuahuac A (2010) Grade transition
dynamic optimization of the living nitroxide-mediated radical polymerization of styrene in a
tubular reactor. Macromol React Eng 4:516–533
223. Stridsberg KM, Ryner M, Albertsson AC (2002) Controlled ring opening polymerization:
polymers with controlled architecture. In: Albertsson AC (ed) Advances in polymers science.
Springer, Berlin
224. Sanda F, Endo T (1999) Syntheses and functions of polymers based on amino acids.
Macromol Chem Phys 200:2651–2661
225. Deming TJ (2000) Living polymerization of a-amino acid-N-carboxyanhydrides. J Polym Sci
A Polym Chem 38:3011–3018
226. Bamfold CH, Block H (1961) The initiation step in the polymerization of N-carboxy a-amino
acid anhydrides. J Chem Soc IV:4989–4991
227. Honda T, Miyazaki M, Nakamura H et al (2005) Controllable polymerization of N-carboxy
anhydrides in a microreaction system. Lab Chip 5:812–818
228. Yamaguchi Y, Ogino K, Yamashita K et al (2004) Rapid micromixing based on multilayer
laminar flows. J Chem Eng Jpn 37:1265–1270
229. Miyazaki M, Honda T, Nakamura H et al (2007) Development of a microreactor for amino
acid polymerization. Chem Eng Technol 30:300–304
230. Kainthan RK, Janzen J, Levin E et al (2006) Biocompatibility testing of branched and linear
polyglycidol. Biomacromolecules 7:703–709
231. Wilms D, Nieberle J, Klos J et al (2007) Synthesis of hyperbranched polyglycerol in a
continuous flow microreactor. Chem Eng Technol 30:1519–1524
232. Paulus RM, Erdmenger T, Becer CR et al (2007) Scale-up of microwave-assisted
polymerizations in continuous-flow mode: cationic ring-opening polymerization of 2-ethyl2-oxazoline. Macromol Rapid Commun 28:484–491
233. Rogers ME, Long TE, Turner SR (2003) Introduction to synthetic methods in step-growth
polymers. In: Rogers ME, Long TE (eds) Synthetic methods in step-growth polymers. Wiley,
Chichester, pp 1–16
234. Kuboyama T, Yoshida J (2005) Synthesis of terminally modified polymer with a micromixer.
In: Proceedings of the 8th topical conference on microreaction technology. American
Institute of Chemical Engineers, New York, 132d
235. Liu S, Chang CH (2007) High rate convergent synthesis and deposition of polyamide
dendrimers using a continuous-flow microreactor. Chem Eng Technol 30:334–340
236. Miller RD (1999) In search of low-k dielectrics. Science 286:421–423
237. Chiang CL, Ma CCM (2003) Synthesis, characterization and properties of novolac ladderlike polysilsesquioxanes containing phosphorus. J Polym Sci A Polym Chem 41:1371–1379
238. Kessler D, Theato P (2008) Synthesis of functional inorganic-organic hybrid polymers based
on poly(silsesquioxanes) and their thin film properties. Macromolecules 41:5237–5244
239. de Boer B, Simon HK, Werts MPL et al (2000) “Living” free radical photopolymerization
initiated from surface-grafted iniferter monolayers. Macromolecules 33:349–356
240. Kessler D, L€ owe H, Theato P (2009) Synthesis of defined poly(silsesquioxane)s: fast polycondensation of trialkoxysilanes in a continuous-flow microreactor. Macromol Chem Phys
210:807–813
241. Andresen A, Cordes HG, Herwig H et al (1976) Influence of long-chain branching on the
viscoelastic properties of low-density polyethylenes. Angew Chem Int Ed 15:630–632
242. Sinn H, Kaminsky W, Vollmer HJ et al (1980) Living polymers on polymerization with
extremely productive Ziegler catalysts. Angew Chem Int Ed 19:390–392
243. Santos LS, Metzger JO (2006) Study of homogeneously catalyzed Ziegler-Natta polymerization of ethene by ESI-MS. Angew Chem Int Ed 45:977–981
244. Luo N, Hutchinson JB, Anseth KS et al (2002) Integrated surface modification of fully
polymeric microfluidic devices using living radical photopolymerization chemistry.
J Polym Sci A Polym Chem 40:1885–1891
245. Luo N, Metters AT, Hutchison JB et al (2003) Methacrylated photoiniferter as a chemical
basis for microlithography: micropatterning based on photografting polymerization.
Macromolecules 36:6739–6745
Controlled Polymerization in Flow Microreactor Systems
49
dynamic optimization of the living nitroxide-mediated radical polymerization of styrene in a
tubular reactor. Macromol React Eng 4:516–533
223. Stridsberg KM, Ryner M, Albertsson AC (2002) Controlled ring opening polymerization:
polymers with controlled architecture. In: Albertsson AC (ed) Advances in polymers science.
Springer, Berlin
224. Sanda F, Endo T (1999) Syntheses and functions of polymers based on amino acids.
Macromol Chem Phys 200:2651–2661
225. Deming TJ (2000) Living polymerization of a-amino acid-N-carboxyanhydrides. J Polym Sci
A Polym Chem 38:3011–3018
226. Bamfold CH, Block H (1961) The initiation step in the polymerization of N-carboxy a-amino
acid anhydrides. J Chem Soc IV:4989–4991
227. Honda T, Miyazaki M, Nakamura H et al (2005) Controllable polymerization of N-carboxy
anhydrides in a microreaction system. Lab Chip 5:812–818
228. Yamaguchi Y, Ogino K, Yamashita K et al (2004) Rapid micromixing based on multilayer
laminar flows. J Chem Eng Jpn 37:1265–1270
229. Miyazaki M, Honda T, Nakamura H et al (2007) Development of a microreactor for amino
acid polymerization. Chem Eng Technol 30:300–304
230. Kainthan RK, Janzen J, Levin E et al (2006) Biocompatibility testing of branched and linear
polyglycidol. Biomacromolecules 7:703–709
231. Wilms D, Nieberle J, Klos J et al (2007) Synthesis of hyperbranched polyglycerol in a
continuous flow microreactor. Chem Eng Technol 30:1519–1524
232. Paulus RM, Erdmenger T, Becer CR et al (2007) Scale-up of microwave-assisted
polymerizations in continuous-flow mode: cationic ring-opening polymerization of 2-ethyl2-oxazoline. Macromol Rapid Commun 28:484–491
233. Rogers ME, Long TE, Turner SR (2003) Introduction to synthetic methods in step-growth
polymers. In: Rogers ME, Long TE (eds) Synthetic methods in step-growth polymers. Wiley,
Chichester, pp 1–16
234. Kuboyama T, Yoshida J (2005) Synthesis of terminally modified polymer with a micromixer.
In: Proceedings of the 8th topical conference on microreaction technology. American
Institute of Chemical Engineers, New York, 132d
235. Liu S, Chang CH (2007) High rate convergent synthesis and deposition of polyamide
dendrimers using a continuous-flow microreactor. Chem Eng Technol 30:334–340
236. Miller RD (1999) In search of low-k dielectrics. Science 286:421–423
237. Chiang CL, Ma CCM (2003) Synthesis, characterization and properties of novolac ladderlike polysilsesquioxanes containing phosphorus. J Polym Sci A Polym Chem 41:1371–1379
238. Kessler D, Theato P (2008) Synthesis of functional inorganic-organic hybrid polymers based
on poly(silsesquioxanes) and their thin film properties. Macromolecules 41:5237–5244
239. de Boer B, Simon HK, Werts MPL et al (2000) “Living” free radical photopolymerization
initiated from surface-grafted iniferter monolayers. Macromolecules 33:349–356
240. Kessler D, L€ owe H, Theato P (2009) Synthesis of defined poly(silsesquioxane)s: fast polycondensation of trialkoxysilanes in a continuous-flow microreactor. Macromol Chem Phys
210:807–813
241. Andresen A, Cordes HG, Herwig H et al (1976) Influence of long-chain branching on the
viscoelastic properties of low-density polyethylenes. Angew Chem Int Ed 15:630–632
242. Sinn H, Kaminsky W, Vollmer HJ et al (1980) Living polymers on polymerization with
extremely productive Ziegler catalysts. Angew Chem Int Ed 19:390–392
243. Santos LS, Metzger JO (2006) Study of homogeneously catalyzed Ziegler-Natta polymerization of ethene by ESI-MS. Angew Chem Int Ed 45:977–981
244. Luo N, Hutchinson JB, Anseth KS et al (2002) Integrated surface modification of fully
polymeric microfluidic devices using living radical photopolymerization chemistry.
J Polym Sci A Polym Chem 40:1885–1891
245. Luo N, Metters AT, Hutchison JB et al (2003) Methacrylated photoiniferter as a chemical
basis for microlithography: micropatterning based on photografting polymerization.
Macromolecules 36:6739–6745
Controlled Polymerization in Flow Microreactor Systems
49