180. Matyjaszewski K (2000) Controlled/living radical polymerization: progress in ATRP, NMP,
and RAFT, vol 768. American Chemical Society, Washington
181. Otsu T (2000) Iniferter concept and living radical polymerization. J Polym Sci Polym Chem
38:2121–2136
182. Matyjaszewski K, Xia J (2001) Atom transfer radical polymerization. Chem Rev
101:2921–2990
183. Ouchi M, Terashima T, Sawamoto M (2008) Precision control of radical polymerization via
transition metal catalysis: from dormant species to designed catalysts for precision functional
polymers. Acc Chem Res 41:1120–1132
184. Kamigaito M, Ando T, Sawamoto M (2001) Metal-catalyzed living radical polymerization.
Chem Rev 101:3689–3746
185. Wang J, Matyjaszewski K (1995) Controlled/“living” radical polymerization. Halogen atom
transfer radical polymerization promoted by a Cu(I)/Cu(II) redox process. Macromolecules
28:7901–7910
186. Wang J, Matyjaszewski K (1995) Atom transfer radical polymerization in the presence of
transition metal complexes. J Am Chem Soc 117:5614–5615
187. Kato M, Kamigaito M, Sawamoto M et al (1995) Polymerization of methyl methacrylate with
the carbon tetrachloride/dichlorotris-(triphenylphosphine)ruthenium(II)/methylaluminum bis
(2,6-di-tert-butylphenoxide) initiating system: possibility of living radical polymerization.
Macromolecules 28:1721–1723
188. Moad G, Rizzardo E, Thang SH (2008) Radical addition-fragmentation chemistry in polymer
synthesis. Polymer 49:1079–1131
189. L€ owe AB, McCormick CL (2007) Reversible addition-fragmentation chain transfer (RAFT)
radical polymerization and the synthesis of water-soluble (co)polymers under homogeneous
conditions in organic and aqueous media. Prog Polym Sci 32:283–351
190. Chiefari J, Chong YKB, Ercole F et al (1998) Living free-radical polymerization by reversible
addition-fragmentation. Chain transfer: the RAFT process. Macromolecules 31:5559–5562
191. Hawker CJ, Bosman AW, Harth E (2001) New polymer synthesis by nitroxide mediated
living radical polymerizations. Chem Rev 101:3661–3688
192. Studer A (2004) Tin-free radical chemistry using the persistent radical effect: alkoxyamine
isomerization, addition reactions and polymerizations. Chem Soc Rev 33:267–273
193. Grubbs RB (2011) Nitroxide-mediated radical polymerization: limitations and versatility.
Polym Rev 51:104–137
194. David G, Boyer C, Tonnar J, Ameduri B et al (2006) Use of iodocompounds in radical
polymerization. Chem Rev 106:3936–3962
195. Poli R (2006) Relationship between one-electron transition-metal reactivity and radical
polymerization processes. Angew Chem Int Ed 45:5058–5070
196. Yamago S (2009) Precision polymer synthesis by degenerative transfer controlled/living
radical polymerization using organotellurium, organostibine, and organobismuthine chain
transfer agents. Chem Rev 109:5051–5068
197. Yamago S (2006) The development of organotellurium-mediated and organostibinemediated living radical polymerization reactions. J Polym Sci A Polym Chem 44:1–12
198. Goto A, Kwak Y, Fukuda T et al (2003) Mechanism-based invention of high-speed living
radical polymerization using organotellurium compounds and azo-initiators. J Am Chem Soc
125:8720–8721
199. Yamago S, Iida K, Yoshida J (2002) Organotellurium compounds as novel initiators
for controlled/living radical polymerizations. Synthesis of functionalized polystyrenes and
end-group modifications. J Am Chem Soc 124:2874–2875
200. Kwak Y, Goto A, Fukuda T et al (2006) A systematic study on activation processes in
organotellurium-mediated living radical polymerizations (TERPs) of styrene, methyl
methacrylate, methyl acrylate, and vinyl acetate. Macromolecules 39:4671–4679
201. Yamago S, Iida K, Yoshida J (2002) Synthesis of poly(meth)acrylate derivatives and their diand triblock copolymers. J Am Chem Soc 124:13666–13667
Controlled Polymerization in Flow Microreactor Systems
47
and RAFT, vol 768. American Chemical Society, Washington
181. Otsu T (2000) Iniferter concept and living radical polymerization. J Polym Sci Polym Chem
38:2121–2136
182. Matyjaszewski K, Xia J (2001) Atom transfer radical polymerization. Chem Rev
101:2921–2990
183. Ouchi M, Terashima T, Sawamoto M (2008) Precision control of radical polymerization via
transition metal catalysis: from dormant species to designed catalysts for precision functional
polymers. Acc Chem Res 41:1120–1132
184. Kamigaito M, Ando T, Sawamoto M (2001) Metal-catalyzed living radical polymerization.
Chem Rev 101:3689–3746
185. Wang J, Matyjaszewski K (1995) Controlled/“living” radical polymerization. Halogen atom
transfer radical polymerization promoted by a Cu(I)/Cu(II) redox process. Macromolecules
28:7901–7910
186. Wang J, Matyjaszewski K (1995) Atom transfer radical polymerization in the presence of
transition metal complexes. J Am Chem Soc 117:5614–5615
187. Kato M, Kamigaito M, Sawamoto M et al (1995) Polymerization of methyl methacrylate with
the carbon tetrachloride/dichlorotris-(triphenylphosphine)ruthenium(II)/methylaluminum bis
(2,6-di-tert-butylphenoxide) initiating system: possibility of living radical polymerization.
Macromolecules 28:1721–1723
188. Moad G, Rizzardo E, Thang SH (2008) Radical addition-fragmentation chemistry in polymer
synthesis. Polymer 49:1079–1131
189. L€ owe AB, McCormick CL (2007) Reversible addition-fragmentation chain transfer (RAFT)
radical polymerization and the synthesis of water-soluble (co)polymers under homogeneous
conditions in organic and aqueous media. Prog Polym Sci 32:283–351
190. Chiefari J, Chong YKB, Ercole F et al (1998) Living free-radical polymerization by reversible
addition-fragmentation. Chain transfer: the RAFT process. Macromolecules 31:5559–5562
191. Hawker CJ, Bosman AW, Harth E (2001) New polymer synthesis by nitroxide mediated
living radical polymerizations. Chem Rev 101:3661–3688
192. Studer A (2004) Tin-free radical chemistry using the persistent radical effect: alkoxyamine
isomerization, addition reactions and polymerizations. Chem Soc Rev 33:267–273
193. Grubbs RB (2011) Nitroxide-mediated radical polymerization: limitations and versatility.
Polym Rev 51:104–137
194. David G, Boyer C, Tonnar J, Ameduri B et al (2006) Use of iodocompounds in radical
polymerization. Chem Rev 106:3936–3962
195. Poli R (2006) Relationship between one-electron transition-metal reactivity and radical
polymerization processes. Angew Chem Int Ed 45:5058–5070
196. Yamago S (2009) Precision polymer synthesis by degenerative transfer controlled/living
radical polymerization using organotellurium, organostibine, and organobismuthine chain
transfer agents. Chem Rev 109:5051–5068
197. Yamago S (2006) The development of organotellurium-mediated and organostibinemediated living radical polymerization reactions. J Polym Sci A Polym Chem 44:1–12
198. Goto A, Kwak Y, Fukuda T et al (2003) Mechanism-based invention of high-speed living
radical polymerization using organotellurium compounds and azo-initiators. J Am Chem Soc
125:8720–8721
199. Yamago S, Iida K, Yoshida J (2002) Organotellurium compounds as novel initiators
for controlled/living radical polymerizations. Synthesis of functionalized polystyrenes and
end-group modifications. J Am Chem Soc 124:2874–2875
200. Kwak Y, Goto A, Fukuda T et al (2006) A systematic study on activation processes in
organotellurium-mediated living radical polymerizations (TERPs) of styrene, methyl
methacrylate, methyl acrylate, and vinyl acetate. Macromolecules 39:4671–4679
201. Yamago S, Iida K, Yoshida J (2002) Synthesis of poly(meth)acrylate derivatives and their diand triblock copolymers. J Am Chem Soc 124:13666–13667
Controlled Polymerization in Flow Microreactor Systems
47