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155. Pennisi RW, Fetters LJ (1988) Preparation of asymmetric three-arm polybutadiene and
polystyrene stars. Macromolecules 21:1094–1099
156. Iatrou H, Hadjichristidis N (1992) Synthesis of a model 3-miktoarm star terpolymer.
Macromolecules 25:4649–4651
157. Ro ´zga-Wijas K, Chojnowski J, Fortuniak W et al (2003) Branched functionalised polysiloxane–silica hybrids for immobilisation of catalysts. J Mater Chem 13:2301–2310
158. Iida K, Chastek TQ, Beers KL et al (2009) Living anionic polymerization using a microfluidic
reactor. Lab Chip 9:339–345
159. Zune C, Je ´ro ˆme R (1999) Anionic polymerization of methacrylic monomers: characterization
of the propagating species. Prog Polym Sci 24:631–664
160. Baskaran D (2003) Strategic developments in living anionic polymerization of alkyl (meth)
acrylates. Prog Polym Sci 28:521–581
161. Nagaki A, Tomida Y, Miyazaki A et al (2009) Microflow system controlled anionic polymerization of MMA. Macromolecules 42:4384–4387
162. Nagaki A, Miyazaki A, Tomida Y et al (2011) Anionic polymerization of alkyl methacrylates
using flow microreactor systems. Chem Eng J 167:548–555
163. Nagaki A, Miyazaki A, Yoshida J (2010) Synthesis of polystyrenes-poly(alkyl methacrylates)
block copolymers via anionic polymerization using an integrated flow microreactor system.
Macromolecules 43:8424–8429
164. Matyjaszewski K, Davis TP (2002) Handbook of radical polymerization. Wiley, New York
165. Iwasaki T, Yoshida J (2005) Free radical polymerization in microreactors. Significant
improvement in molecular weight distribution control. Macromolecules 38:1159–1163
166. Leveson P, Dunk WAE, Jachuck RJ (2004) Investigation of shear effects on styrene free
radical polymerization using a narrow channel reactor. J Appl Polym Sci 94:1365–1369
167. Iwasaki T, Kawano N, Yoshida J (2006) Radical polymerization using micro flow system.
Numbering-up of microreactors and continuous operation. Org Process Res Dev
10:1126–1131
168. Bayer T, Pysall D, Wachsen O (2000) Micro mixing effects in continuous radical polymerization. In: Ehrfeld W (ed) Proceedings 3rd international conference on microreaction technology.
Springer, Berlin, pp 165–170
169. Axiva GmbH, Pysall D, Wachsen O et al (1999) Method and device for continuous production
of polymers. Patent WO/1999/054362
170. Serra C, Sary N, Schlatter G et al (2005) Numerical simulation of polymerization in
interdigital multilamination micromixers. Lab Chip 5:966–973
171. Serra C, Schlatter G, Sary N et al (2007) Free radical polymerization in multilaminated
microreactors: 2D and 3D multiphysics CFD modelling. Microfluid Nanofluid 3:451–461
172. Rollin AL, Patterson I, Huneault R et al (1977) The effect of flow regime on the continuous
emulsion polymerization of styrene in a tubular reactor. Can J Chem Eng 55:565–571
173. Dalpe J, Bataille P (1989) Loop polymerization of vinyl acetate. J Appl Polym Sci
38:2237–2244
174. Abad C, de la Cal JC, Asua JM (1995) Start-up procedures in the emulsion copolymerization
of vinyl esters in a continuous loop reactor. Polymer 36:4293–4299
175. Ouzine K, Graillat C, McKenna T (2004) Continuous tubular reactors for latex production:
conventional emulsion and miniemulsion polymerizations. J Appl Polym Sci 91:2195–2207
176. Matyjaszewski K, Davis TP (2002) Handbook of radical polymerization. Wiley-Interscience,
New York
177. Moad G, Solomon DH (2006) The chemistry of radical polymerization. Elsevier, Amsterdam
178. Braunecke WA, Matyjaszewski K (2007) Controlled/living radical polymerization: features,
developments, and perspectives. Prog Polym Sci 32:93–146
179. Matyjaszewski K (1998) Controlled radical polymerization, vol 685. American Chemical
Society, Washington
46
A. Nagaki and J.-i. Yoshida
continuous flow. Macromolecules 43:5582–5588
155. Pennisi RW, Fetters LJ (1988) Preparation of asymmetric three-arm polybutadiene and
polystyrene stars. Macromolecules 21:1094–1099
156. Iatrou H, Hadjichristidis N (1992) Synthesis of a model 3-miktoarm star terpolymer.
Macromolecules 25:4649–4651
157. Ro ´zga-Wijas K, Chojnowski J, Fortuniak W et al (2003) Branched functionalised polysiloxane–silica hybrids for immobilisation of catalysts. J Mater Chem 13:2301–2310
158. Iida K, Chastek TQ, Beers KL et al (2009) Living anionic polymerization using a microfluidic
reactor. Lab Chip 9:339–345
159. Zune C, Je ´ro ˆme R (1999) Anionic polymerization of methacrylic monomers: characterization
of the propagating species. Prog Polym Sci 24:631–664
160. Baskaran D (2003) Strategic developments in living anionic polymerization of alkyl (meth)
acrylates. Prog Polym Sci 28:521–581
161. Nagaki A, Tomida Y, Miyazaki A et al (2009) Microflow system controlled anionic polymerization of MMA. Macromolecules 42:4384–4387
162. Nagaki A, Miyazaki A, Tomida Y et al (2011) Anionic polymerization of alkyl methacrylates
using flow microreactor systems. Chem Eng J 167:548–555
163. Nagaki A, Miyazaki A, Yoshida J (2010) Synthesis of polystyrenes-poly(alkyl methacrylates)
block copolymers via anionic polymerization using an integrated flow microreactor system.
Macromolecules 43:8424–8429
164. Matyjaszewski K, Davis TP (2002) Handbook of radical polymerization. Wiley, New York
165. Iwasaki T, Yoshida J (2005) Free radical polymerization in microreactors. Significant
improvement in molecular weight distribution control. Macromolecules 38:1159–1163
166. Leveson P, Dunk WAE, Jachuck RJ (2004) Investigation of shear effects on styrene free
radical polymerization using a narrow channel reactor. J Appl Polym Sci 94:1365–1369
167. Iwasaki T, Kawano N, Yoshida J (2006) Radical polymerization using micro flow system.
Numbering-up of microreactors and continuous operation. Org Process Res Dev
10:1126–1131
168. Bayer T, Pysall D, Wachsen O (2000) Micro mixing effects in continuous radical polymerization. In: Ehrfeld W (ed) Proceedings 3rd international conference on microreaction technology.
Springer, Berlin, pp 165–170
169. Axiva GmbH, Pysall D, Wachsen O et al (1999) Method and device for continuous production
of polymers. Patent WO/1999/054362
170. Serra C, Sary N, Schlatter G et al (2005) Numerical simulation of polymerization in
interdigital multilamination micromixers. Lab Chip 5:966–973
171. Serra C, Schlatter G, Sary N et al (2007) Free radical polymerization in multilaminated
microreactors: 2D and 3D multiphysics CFD modelling. Microfluid Nanofluid 3:451–461
172. Rollin AL, Patterson I, Huneault R et al (1977) The effect of flow regime on the continuous
emulsion polymerization of styrene in a tubular reactor. Can J Chem Eng 55:565–571
173. Dalpe J, Bataille P (1989) Loop polymerization of vinyl acetate. J Appl Polym Sci
38:2237–2244
174. Abad C, de la Cal JC, Asua JM (1995) Start-up procedures in the emulsion copolymerization
of vinyl esters in a continuous loop reactor. Polymer 36:4293–4299
175. Ouzine K, Graillat C, McKenna T (2004) Continuous tubular reactors for latex production:
conventional emulsion and miniemulsion polymerizations. J Appl Polym Sci 91:2195–2207
176. Matyjaszewski K, Davis TP (2002) Handbook of radical polymerization. Wiley-Interscience,
New York
177. Moad G, Solomon DH (2006) The chemistry of radical polymerization. Elsevier, Amsterdam
178. Braunecke WA, Matyjaszewski K (2007) Controlled/living radical polymerization: features,
developments, and perspectives. Prog Polym Sci 32:93–146
179. Matyjaszewski K (1998) Controlled radical polymerization, vol 685. American Chemical
Society, Washington
46
A. Nagaki and J.-i. Yoshida
