241. Srikanth S, Maesen M, Dominguez-Benetton X, Vanbroekhoven K, Pant D (2014)
Enzymatic electrosynthesis of formate through CO 2 sequestration/reduction in a bioelectrochemical system (BES). Bioresour Technol 165:350–354
242. Hwang H, Yeon YJ, Lee S, Choe H, Jang MG, Cho DH, Park S, Kim YH (2015)
Electro-biocatalytic production of formate from carbon dioxide using an oxygen-stable
whole cell biocatalyst. Bioresour Technol 185:35–39
243. Kim SH, Chung GY, Kim SH, Vinothkumar G, Yoon SH, Jung KD (2016) Electrochemical NADH regeneration and electroenzymatic CO 2 reduction on cu nanorods/glassy carbon
electrode prepared by cyclic deposition. Electrochim Acta 210:837–845
244. Lee SY, Lim SY, Seo D, Lee JY, Chung TD (2016) Light-driven highly selective conversion
of CO 2 to formate by electrosynthesized enzyme/cofactor thin film electrode. Adv Energy
Mater 6:1502207
245. Nam DH, Kuk SK, Choe H, Lee S, Ko JW, Son EJ, Choi EG, Kim YH, Park CB (2016)
Enzymatic photosynthesis of formate from carbon dioxide coupled with highly efficient
photoelectrochemical regeneration of nicotinamide cofactors. Green Chem 18:5989–5993
246. Schlager S, Dumitru LM, Haberbauer M, Fuchsbauer A, Neugebauer H, Hiemetsberger D,
Wagner A, Portenkirchner E, Sariciftci NS (2016) Electrochemical reduction of carbon
dioxide to methanol by direct injection of electrons into immobilized enzymes on a modified
electrode. Chemsuschem 9:631–635
247. Ikeyama S, Amao Y (2017) A Novel electron carrier molecule based on a viologen
derivative for visible light-driven CO 2 reduction to formic acid with the system of zinc
porphyrin and formate dehydrogenase. Sustain Energy Fuels 1:1730–1733
248. Noji T, Jin T, Nango M, Kamiya N, Amao Y (2017) CO 2 photoreduction by formate
dehydrogenase and a Ru-complex in a nanoporous glass reactor. ACS Appl Mater Interfaces
9:3260–3265
249. Zhang L, Liu J, Ong J, Li SFY (2016) Specific and sustainable bioelectro-reduction of
carbon dioxide to formate on a novel enzymatic cathode. Chemosphere 162:228–234
250. Yadav RK, Baeg J-O, Oh GH, Park N-J, Kong K-J, Kim J, Hwang DW, Biswas SK (2012)
A photocatalyst-enzyme coupled artificial photosynthesis system for solar energy in
production of formic acid from CO 2 . J Am Chem Soc 134:11455–11461
251. El-Zahab B, Donnelly D, Wang P (2008) Particle-tethered NADH for production of
methanol from CO 2 catalyzed by coimmobilized enzymes. Biotechnol Bioeng 99:508–514
252. Choe H, Joo JC, Cho DH, Kim MH, Lee SH, Jung KD, Kim YH (2014) Efficient CO 2 -
reducing activity of NAD-dependent formate dehydrogenase from thiobacillus sp
KNK65MA for formate production from CO 2 gas. PLoS ONE 9:e103111
253. Kuk SK, Singh RK, Nam DH, Singh R, Lee JK, Park CB (2017) Photoelectrochemical
reduction of carbon dioxide to methanol through a highly efficient enzyme cascade. Angew
Chem 56:3827–3832
254. Sakai K, Kitazumi Y, Shirai O, Kano K (2016) Bioelectrocatalytic formate oxidation and
carbon dioxide reduction at high current density and low overpotential with
tungsten-containing formate dehydrogenase and mediators. Electrochem Commun 65:31–34
255. Sakai K, Kitazumi Y, Shirai O, Takagi K, Kano K (2016) Efficient bioelectrocatalytic CO 2
reduction on gas-diffusion-type biocathode with tungsten-containing formate dehydrogenase. Electrochem Commun 73:85–88
256. Sakai K, Kitazumi Y, Shirai O, Takagi K, Kano K (2017) direct electron transfer-type
four-way bioelectrocatalysis of CO 2 / formate and NAD +/NADH redox couples by
tungsten-containing formate dehydrogenase adsorbed on gold nanoparticle-embedded
mesoporous carbon electrodes modified with 4-Mercaptopyridine. Electrochem Commun
84:75–79
257. Sakai K, Sugimoto Y, Kitazumi Y, Shirai O, Takagi K, Kano K (2017) Direct electron
transfer-type bioelectrocatalytic interconversion of carbon dioxide/formate and NAD +/
NADH redox couples with tungsten-containing formate dehydrogenase. Electrochim Acta
228:537–544
Carbon Dioxide Utilisation—The Formate Route
79
Enzymatic electrosynthesis of formate through CO 2 sequestration/reduction in a bioelectrochemical system (BES). Bioresour Technol 165:350–354
242. Hwang H, Yeon YJ, Lee S, Choe H, Jang MG, Cho DH, Park S, Kim YH (2015)
Electro-biocatalytic production of formate from carbon dioxide using an oxygen-stable
whole cell biocatalyst. Bioresour Technol 185:35–39
243. Kim SH, Chung GY, Kim SH, Vinothkumar G, Yoon SH, Jung KD (2016) Electrochemical NADH regeneration and electroenzymatic CO 2 reduction on cu nanorods/glassy carbon
electrode prepared by cyclic deposition. Electrochim Acta 210:837–845
244. Lee SY, Lim SY, Seo D, Lee JY, Chung TD (2016) Light-driven highly selective conversion
of CO 2 to formate by electrosynthesized enzyme/cofactor thin film electrode. Adv Energy
Mater 6:1502207
245. Nam DH, Kuk SK, Choe H, Lee S, Ko JW, Son EJ, Choi EG, Kim YH, Park CB (2016)
Enzymatic photosynthesis of formate from carbon dioxide coupled with highly efficient
photoelectrochemical regeneration of nicotinamide cofactors. Green Chem 18:5989–5993
246. Schlager S, Dumitru LM, Haberbauer M, Fuchsbauer A, Neugebauer H, Hiemetsberger D,
Wagner A, Portenkirchner E, Sariciftci NS (2016) Electrochemical reduction of carbon
dioxide to methanol by direct injection of electrons into immobilized enzymes on a modified
electrode. Chemsuschem 9:631–635
247. Ikeyama S, Amao Y (2017) A Novel electron carrier molecule based on a viologen
derivative for visible light-driven CO 2 reduction to formic acid with the system of zinc
porphyrin and formate dehydrogenase. Sustain Energy Fuels 1:1730–1733
248. Noji T, Jin T, Nango M, Kamiya N, Amao Y (2017) CO 2 photoreduction by formate
dehydrogenase and a Ru-complex in a nanoporous glass reactor. ACS Appl Mater Interfaces
9:3260–3265
249. Zhang L, Liu J, Ong J, Li SFY (2016) Specific and sustainable bioelectro-reduction of
carbon dioxide to formate on a novel enzymatic cathode. Chemosphere 162:228–234
250. Yadav RK, Baeg J-O, Oh GH, Park N-J, Kong K-J, Kim J, Hwang DW, Biswas SK (2012)
A photocatalyst-enzyme coupled artificial photosynthesis system for solar energy in
production of formic acid from CO 2 . J Am Chem Soc 134:11455–11461
251. El-Zahab B, Donnelly D, Wang P (2008) Particle-tethered NADH for production of
methanol from CO 2 catalyzed by coimmobilized enzymes. Biotechnol Bioeng 99:508–514
252. Choe H, Joo JC, Cho DH, Kim MH, Lee SH, Jung KD, Kim YH (2014) Efficient CO 2 -
reducing activity of NAD-dependent formate dehydrogenase from thiobacillus sp
KNK65MA for formate production from CO 2 gas. PLoS ONE 9:e103111
253. Kuk SK, Singh RK, Nam DH, Singh R, Lee JK, Park CB (2017) Photoelectrochemical
reduction of carbon dioxide to methanol through a highly efficient enzyme cascade. Angew
Chem 56:3827–3832
254. Sakai K, Kitazumi Y, Shirai O, Kano K (2016) Bioelectrocatalytic formate oxidation and
carbon dioxide reduction at high current density and low overpotential with
tungsten-containing formate dehydrogenase and mediators. Electrochem Commun 65:31–34
255. Sakai K, Kitazumi Y, Shirai O, Takagi K, Kano K (2016) Efficient bioelectrocatalytic CO 2
reduction on gas-diffusion-type biocathode with tungsten-containing formate dehydrogenase. Electrochem Commun 73:85–88
256. Sakai K, Kitazumi Y, Shirai O, Takagi K, Kano K (2017) direct electron transfer-type
four-way bioelectrocatalysis of CO 2 / formate and NAD +/NADH redox couples by
tungsten-containing formate dehydrogenase adsorbed on gold nanoparticle-embedded
mesoporous carbon electrodes modified with 4-Mercaptopyridine. Electrochem Commun
84:75–79
257. Sakai K, Sugimoto Y, Kitazumi Y, Shirai O, Takagi K, Kano K (2017) Direct electron
transfer-type bioelectrocatalytic interconversion of carbon dioxide/formate and NAD +/
NADH redox couples with tungsten-containing formate dehydrogenase. Electrochim Acta
228:537–544
Carbon Dioxide Utilisation—The Formate Route
79