258. Sakai K, Xia H, Kitazumi Y, Shirai O, Kano K (2018) Assembly of
direct-electron-transfer-type bioelectrodes with high performance. Electrochim Acta
271:305–311
259. Muller U, Willnow P, Ruschig U, Hopner T (1978) Formate dehydrogenase from
Pseudomonas oxalaticus. Eur J Biochem 83:485–498
260. Yu X, Niks D, Mulchandani A, Hille R (2017) Efficient reduction of CO 2 by the
molybdenum-containing formate dehydrogenase from Cupriavidus necator (Ralstonia
eutropha). J Biol Chem 292:16872–16879
261. Walker LM, Li V, Niks D, Hille R, Elliott SJ (2019) Deconvolution of reduction potentials
of formate dehydrogenase from Cupriavidus necator. J Biol Inorg Chem 24:889–898
262. Yu X, Niks D, Ge X, Liu H, Hille R, Mulchandani A (2019) Synthesis of formate from CO 2
gas catalyzed by an O 2 -tolerant NAD-dependent formate dehydrogenase and glucose
dehydrogenase. Biochemistry 58:1861–1868
263. Bassegoda A, Madden C, Wakerley DW, Reisner E, Hirst J (2014) Reversible interconversion of CO 2 and formate by a molybdenum-containing formate dehydrogenase. J Am
Chem Soc 136:15473–15476
264. Roger M, Brown F, Gabrielli W, Sargent F (2018) Efficient hydrogen-dependent carbon
dioxide reduction by Escherichia coli. Curr Biol 28:140–145
265. Singh S, Noori MT, Verm N (2020) Efficient bio-electroreduction of CO 2 to formate on a
iron phthalocyanine-dispersed CDC in microbial electrolysis system. ElectrochimActa
338:135887
266. Cordas CM, Campaniço M, Baptista R, Maia LB, Moura I, Moura JJG (2019) Direct
electrochemical reduction of carbon dioxide by a molybdenum-containing formate
dehydrogenase. J Inorg Biochem 196:110694
267. Mourato C, Martins M, da Silva SM, Pereira IA (2017) A continuous system for biocatalytic
hydrogenation of CO 2 to Formate. Bioresour Technol 235:149–156
268. Martins M, Mourato C, Pereira IAC (2015) Desulfovibrio vulgaris growth coupled to
formate-driven H 2 production. Environ Sci Technol 49:14655–14662
269. Martins M, Mourato C, Morais-Silva FO, Rodrigues- Pousada C, Voordouw G, Wall JD,
Pereira IAC (2016) Electron transfer pathways of formate-driven H 2 production in
Desulfovibrio. Appl Microbiol Biotechnol 100:8135–8146
270. Sokol KP, Robinson WE, Oliveira AO, Warnan J, Nowaczyk MM, Ruff A, Pereira IAC,
Reisner E (2018) Photoreduction of CO 2 with a formate dehydrogenase driven by
photosystem II using a semi-artificial Z-scheme architecture. J Am Chem Soc 140:16418–
16422
271. Miller M, Robinson WR, Oliveira AR, Heidary N, Kornienko N, Warnan J, Pereira IAC,
Reisner E (2019) Interfacing formate dehydrogenase with metal oxides for the reversible
electrocatalysis and solar-driven reduction of carbon dioxide. Angew Chem 58:4601–4605
272. Szczesny J, Ruff A, Oliveira AR, Pita M, Pereira IAC, De Lacey AL, Schuhmann W (2020)
Electroenzymatic CO 2 fixation using redox polymer/enzyme-modified gas diffusion
electrodes. ACS Energy Lett 5:321–327
273. Sokol KP, Robinson WE, Oliveira AR, Zacarias S, Lee C-Y, Madden C, Bassegoda A,
Hirst J, Pereira IAC, Reisner E (2019) Reversible and selective interconversion of hydrogen
and carbon dioxide into formate by a semiartificial formate hydrogenlyase mimic. J Chem
Am Soc 141:17498–17502
274. Berg IA, Kockelkorn D, Ramos-Vera WH, Say RF, Zarzycki J, Hügler M (2010)
Autotrophic carbon fixation in archaea. Nat Rev Microbiol 8:447–460
275. Martin WF, Thauer RK (2017) Energy in ancient metabolism. Cell 168:953–955
80
L. B. Maia et al.
direct-electron-transfer-type bioelectrodes with high performance. Electrochim Acta
271:305–311
259. Muller U, Willnow P, Ruschig U, Hopner T (1978) Formate dehydrogenase from
Pseudomonas oxalaticus. Eur J Biochem 83:485–498
260. Yu X, Niks D, Mulchandani A, Hille R (2017) Efficient reduction of CO 2 by the
molybdenum-containing formate dehydrogenase from Cupriavidus necator (Ralstonia
eutropha). J Biol Chem 292:16872–16879
261. Walker LM, Li V, Niks D, Hille R, Elliott SJ (2019) Deconvolution of reduction potentials
of formate dehydrogenase from Cupriavidus necator. J Biol Inorg Chem 24:889–898
262. Yu X, Niks D, Ge X, Liu H, Hille R, Mulchandani A (2019) Synthesis of formate from CO 2
gas catalyzed by an O 2 -tolerant NAD-dependent formate dehydrogenase and glucose
dehydrogenase. Biochemistry 58:1861–1868
263. Bassegoda A, Madden C, Wakerley DW, Reisner E, Hirst J (2014) Reversible interconversion of CO 2 and formate by a molybdenum-containing formate dehydrogenase. J Am
Chem Soc 136:15473–15476
264. Roger M, Brown F, Gabrielli W, Sargent F (2018) Efficient hydrogen-dependent carbon
dioxide reduction by Escherichia coli. Curr Biol 28:140–145
265. Singh S, Noori MT, Verm N (2020) Efficient bio-electroreduction of CO 2 to formate on a
iron phthalocyanine-dispersed CDC in microbial electrolysis system. ElectrochimActa
338:135887
266. Cordas CM, Campaniço M, Baptista R, Maia LB, Moura I, Moura JJG (2019) Direct
electrochemical reduction of carbon dioxide by a molybdenum-containing formate
dehydrogenase. J Inorg Biochem 196:110694
267. Mourato C, Martins M, da Silva SM, Pereira IA (2017) A continuous system for biocatalytic
hydrogenation of CO 2 to Formate. Bioresour Technol 235:149–156
268. Martins M, Mourato C, Pereira IAC (2015) Desulfovibrio vulgaris growth coupled to
formate-driven H 2 production. Environ Sci Technol 49:14655–14662
269. Martins M, Mourato C, Morais-Silva FO, Rodrigues- Pousada C, Voordouw G, Wall JD,
Pereira IAC (2016) Electron transfer pathways of formate-driven H 2 production in
Desulfovibrio. Appl Microbiol Biotechnol 100:8135–8146
270. Sokol KP, Robinson WE, Oliveira AO, Warnan J, Nowaczyk MM, Ruff A, Pereira IAC,
Reisner E (2018) Photoreduction of CO 2 with a formate dehydrogenase driven by
photosystem II using a semi-artificial Z-scheme architecture. J Am Chem Soc 140:16418–
16422
271. Miller M, Robinson WR, Oliveira AR, Heidary N, Kornienko N, Warnan J, Pereira IAC,
Reisner E (2019) Interfacing formate dehydrogenase with metal oxides for the reversible
electrocatalysis and solar-driven reduction of carbon dioxide. Angew Chem 58:4601–4605
272. Szczesny J, Ruff A, Oliveira AR, Pita M, Pereira IAC, De Lacey AL, Schuhmann W (2020)
Electroenzymatic CO 2 fixation using redox polymer/enzyme-modified gas diffusion
electrodes. ACS Energy Lett 5:321–327
273. Sokol KP, Robinson WE, Oliveira AR, Zacarias S, Lee C-Y, Madden C, Bassegoda A,
Hirst J, Pereira IAC, Reisner E (2019) Reversible and selective interconversion of hydrogen
and carbon dioxide into formate by a semiartificial formate hydrogenlyase mimic. J Chem
Am Soc 141:17498–17502
274. Berg IA, Kockelkorn D, Ramos-Vera WH, Say RF, Zarzycki J, Hügler M (2010)
Autotrophic carbon fixation in archaea. Nat Rev Microbiol 8:447–460
275. Martin WF, Thauer RK (2017) Energy in ancient metabolism. Cell 168:953–955
80
L. B. Maia et al.