581
212. Vinogradova OM, Keier NP, Roginskii SZ (1957) Dokl. Akad Nauk SSSR 112:1075–1078
213. Toussaint WJ, Dunn JT (1947) US 2,421,361
214. Toussaint W.J, Dunn J. T, Jackson D. R (1947) Ind Eng Chem, 39, 120–125. https://pubs.acs.
org/doi/pdf/10.1021/ie50446a010
215. Delacaillerie JBD, Gruver V, Fripiat JJ (1995) Modification of the surface properties of
natural phyllosilicate sepiolite by secondary isomorphic substitution. J Catal 151:420–430.
https://doi.org/10.1006/jcat.1995.1044
216. Gruver V, Sun A, Fripiat J. J, (1995) Catalytic properties of aluminated sepiolite in ethanol
conversion. Catal Lett 34:359–364. https://link.springer.com/article/10.1007/BF00806885
217. Chieregato A, Ochoa JV, Cavani F (2016) Olefins from biomass. In: Chemicals and fuels from
bio-based building blocks. Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, pp 1–32
218. Natta G, Rigamonti R (1947) Chim Ind 29:95
219. Corson, B. B, Jones H.E, Welling C.E, Hinckley J.A, Stahly E.E (1950) Butadiene from ethyl
alcohol, Ind Eng Chem, 42:359. https://pubs.acs.org/doi/pdf/10.1021/ie50482a039
220. Kitayama Y, Michishita A (1981) Catalytic activity of fibrous clay mineral sepiolite for
butadiene formation from ethanol. J Chem Soc Chem Commun 9:401–402. https://doi.
org/10.1039/C39810000401
221. Kitayama Y, Satoh M, Kodama, T (1996) Preparation of large surface area nickel magnesium
silicate and its catalytic activity for conversion of ethanol into buta-1,3-diene Catal Lett36:95
https://link.springer.com/article/10.1007/BF00807211
222. Ohnishi R, Akimoto T, Tanabe K (1985) Pronounced catalytic activity and selectivity of
MgO–SiO 2 –Na 2 O for synthesis of buta-1,3-diene from ethanol. J Chem Soc Chem Commun
22:1613–1614. https://doi.org/10.1039/C39850001613
223. Kvisle S, Aguero A, Sneeden RPA (1988) Transformation of ethanol into 1,3-butadiene
over magnesium oxide/silica catalysts. Appl Catal 43:117–131. https://doi.org/10.1016/
S0166- 9834(00)80905- 7
224. Makshina EV, Janssens W, Sels BF, Jacobs PA (2012) Catalytic study of the conversion of ethanol into 1,3-butadiene. Catal Today 198:338–344. https://doi.org/10.1016/j.
cattod.2012.05.031
225. Bhattacharyya, S, K, Ganguly, N. D (1962) One-step catalytic conversion of ethanol to
butadiene in the fixed bed. II binary- and ternary-oxide catalysts J Appl Chem, 12:105–110.
https://doi.org/10.1002/jctb.5010120302
226. Bhattacharyya, S. K, Avasthi, B. N (1963) One-step catalytic conversion of ethanol to
Butadiene in a fluidized bed, Ind Eng Chem Process Des Dev, 2, 45–51. https://pubs.acs.org/
doi/pdf/10.1021/i260005a010
227. Chung SH, Angelici C, Hinterding SOM, Weingarth M, Baldus M, Houben K, Weckhuysen
M, Bruijnincx PCA (2016) On the role of magnesium silicates in wet-kneaded silicamagnesia catalysts for the Lebedev ethanol-to-butadiene process. ACS Catal 6:4034–4045.
https://doi.org/10.1021/acscatal.5b02972
228. Angelici C, Velthoen MEZ, Weckhuyse BM, Bruijnincx PCA (2015) Influence of acid– base
properties on the Lebedev ethanol-to-butadiene process catalyzed by SiO 2 – MgO materials.
Cat Sci Technol 5:2869–2879. https://doi.org/10.1039/C5CY00200A
229. Patel AD, Meesters K, den Uil H, de Jong E, Blok K, Patel MK (2012) Sustainability assessment of novel chemical processes at early stage: application to biobased processes. Energy
Environ Sci 5:8430. https://doi.org/10.1039/c2ee21581k
230. Chang CD, Silvestri AJ (1977) The conversion of methanol and other o-compounds to hydrocarbons over zeolite catalysts. J Catal 47:249–259
231. Derouane EG, Nagy JB, Dejaifve P, Van hoof JHC, Ben P, Spekman BP, Vedrine JC,
Naccache C (1978) Elucidation of the mechanism of conversion of methanol and ethanol to hydrocarbons on a new type of synthetic zeolite. J Catal 53:40–55. https://doi.
org/10.1016/0021- 9517(78)90006- 4
Catalytic Conversion of Alcohols into Value-Added Products
212. Vinogradova OM, Keier NP, Roginskii SZ (1957) Dokl. Akad Nauk SSSR 112:1075–1078
213. Toussaint WJ, Dunn JT (1947) US 2,421,361
214. Toussaint W.J, Dunn J. T, Jackson D. R (1947) Ind Eng Chem, 39, 120–125. https://pubs.acs.
org/doi/pdf/10.1021/ie50446a010
215. Delacaillerie JBD, Gruver V, Fripiat JJ (1995) Modification of the surface properties of
natural phyllosilicate sepiolite by secondary isomorphic substitution. J Catal 151:420–430.
https://doi.org/10.1006/jcat.1995.1044
216. Gruver V, Sun A, Fripiat J. J, (1995) Catalytic properties of aluminated sepiolite in ethanol
conversion. Catal Lett 34:359–364. https://link.springer.com/article/10.1007/BF00806885
217. Chieregato A, Ochoa JV, Cavani F (2016) Olefins from biomass. In: Chemicals and fuels from
bio-based building blocks. Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, pp 1–32
218. Natta G, Rigamonti R (1947) Chim Ind 29:95
219. Corson, B. B, Jones H.E, Welling C.E, Hinckley J.A, Stahly E.E (1950) Butadiene from ethyl
alcohol, Ind Eng Chem, 42:359. https://pubs.acs.org/doi/pdf/10.1021/ie50482a039
220. Kitayama Y, Michishita A (1981) Catalytic activity of fibrous clay mineral sepiolite for
butadiene formation from ethanol. J Chem Soc Chem Commun 9:401–402. https://doi.
org/10.1039/C39810000401
221. Kitayama Y, Satoh M, Kodama, T (1996) Preparation of large surface area nickel magnesium
silicate and its catalytic activity for conversion of ethanol into buta-1,3-diene Catal Lett36:95
https://link.springer.com/article/10.1007/BF00807211
222. Ohnishi R, Akimoto T, Tanabe K (1985) Pronounced catalytic activity and selectivity of
MgO–SiO 2 –Na 2 O for synthesis of buta-1,3-diene from ethanol. J Chem Soc Chem Commun
22:1613–1614. https://doi.org/10.1039/C39850001613
223. Kvisle S, Aguero A, Sneeden RPA (1988) Transformation of ethanol into 1,3-butadiene
over magnesium oxide/silica catalysts. Appl Catal 43:117–131. https://doi.org/10.1016/
S0166- 9834(00)80905- 7
224. Makshina EV, Janssens W, Sels BF, Jacobs PA (2012) Catalytic study of the conversion of ethanol into 1,3-butadiene. Catal Today 198:338–344. https://doi.org/10.1016/j.
cattod.2012.05.031
225. Bhattacharyya, S, K, Ganguly, N. D (1962) One-step catalytic conversion of ethanol to
butadiene in the fixed bed. II binary- and ternary-oxide catalysts J Appl Chem, 12:105–110.
https://doi.org/10.1002/jctb.5010120302
226. Bhattacharyya, S. K, Avasthi, B. N (1963) One-step catalytic conversion of ethanol to
Butadiene in a fluidized bed, Ind Eng Chem Process Des Dev, 2, 45–51. https://pubs.acs.org/
doi/pdf/10.1021/i260005a010
227. Chung SH, Angelici C, Hinterding SOM, Weingarth M, Baldus M, Houben K, Weckhuysen
M, Bruijnincx PCA (2016) On the role of magnesium silicates in wet-kneaded silicamagnesia catalysts for the Lebedev ethanol-to-butadiene process. ACS Catal 6:4034–4045.
https://doi.org/10.1021/acscatal.5b02972
228. Angelici C, Velthoen MEZ, Weckhuyse BM, Bruijnincx PCA (2015) Influence of acid– base
properties on the Lebedev ethanol-to-butadiene process catalyzed by SiO 2 – MgO materials.
Cat Sci Technol 5:2869–2879. https://doi.org/10.1039/C5CY00200A
229. Patel AD, Meesters K, den Uil H, de Jong E, Blok K, Patel MK (2012) Sustainability assessment of novel chemical processes at early stage: application to biobased processes. Energy
Environ Sci 5:8430. https://doi.org/10.1039/c2ee21581k
230. Chang CD, Silvestri AJ (1977) The conversion of methanol and other o-compounds to hydrocarbons over zeolite catalysts. J Catal 47:249–259
231. Derouane EG, Nagy JB, Dejaifve P, Van hoof JHC, Ben P, Spekman BP, Vedrine JC,
Naccache C (1978) Elucidation of the mechanism of conversion of methanol and ethanol to hydrocarbons on a new type of synthetic zeolite. J Catal 53:40–55. https://doi.
org/10.1016/0021- 9517(78)90006- 4
Catalytic Conversion of Alcohols into Value-Added Products