156. Song LC, Xie ZJ, Wang MM, Zhao GY, Song HB (2012) Biomimetic models for the active
site of [Fe]hydrogenase featuring an acylmethyl(hydroxymethyl)pyridine ligand. Inorg Chem
51(14):7466–7468
157. Bichler B, Holzhacker C, Stoger B, Puchberger M, Veiros LF, Kirchner K (2013) Heterolytic
cleavage of dihydrogen by an iron(II) PNP pincer complex via metal-ligand cooperation.
Organometallics 32(15):4114–4121
158. Durgaprasad G, Xie ZL, Rose MJ (2016) Iron hydride detection and intramolecular hydride
transfer in a synthetic model of mono-iron hydrogenase with a CNS chelate. Inorg Chem 55
(2):386–389
159. Xie ZL, Durgaprasad G, Ali AK, Rose MJ (2017) Substitution reactions of iron(ii) carbamoylthioether complexes related to mono-iron hydrogenase. Dalton Trans 46(33):10814–10829
160. Hirotsu M, Santo K, Hashimoto H, Kinoshita I (2012) Carbon- and sulfur-bridged diiron
carbonyl complexes containing N,C,S-tridentate ligands derived from functionalized
dibenzothiophenes: mimics of the [FeFe]-hydrogenase active site. Organometallics 31
(21):7548–7557
161. Hirotsu M, Tsuboi C, Nishioka T, Kinoshita I (2011) Carbon-sulfur bond cleavage reactions of
dibenzothiophene derivatives mediated by iron and ruthenium carbonyls. Dalton Trans 40
(4):785–787
162. Nakae T, Hirotsu M, Kinoshita I (2015) Di- and mononuclear iron complexes of N,C,Stridentate ligands containing an Aminopyridyl group: effect of the pendant amine site on
catalytic properties for proton reduction. Organometallics 34(16):3988–3997
163. Hirotsu M, Santo K, Tsuboi C, Kinoshita I (2014) Diiron carbonyl complexes bearing an N,C,
S-pincer ligand: reactivity toward phosphines, heterolytic Fe–Fe cleavage, and electrocatalytic
proton reduction. Organometallics 33(16):4260–4268
164. Ott S, Kritikos M, Akermark B, Sun L (2003) Synthesis and structure of a biomimetic model of
the iron hydrogenase active site covalently linked to a ruthenium photosensitizer. Angew
Chem Int Ed Engl 42(28):3285–3288
165. Hammarström L, Barigelletti F, Flamigni L, Indelli MT, Armaroli N, Calogero G,
Guardigli M, Sour A, Collin J-P, Sauvage J-P (1997) A study on delocalization of MLCT
excited states by rigid bridging ligands in homometallic dinuclear complexes of ruthenium(II).
Chem A Eur J 101(48):9061–9069
166. Ott S, Borgstrom M, Kritikos M, Lomoth R, Bergquist J, Akermark B, Hammarstrom L, Sun L
(2004) Model of the iron hydrogenase active site covalently linked to a ruthenium photosensitizer: synthesis and photophysical properties. Inorg Chem 43(15):4683–4692
167. Hawecker JL, Lehn JM, Ziessel R (1983) Efficient homogeneous photochemical hydrogen
generation and water reduction mediated by cobaloxime or macrocyclic cobalt complexes.
New J Chem 7:271–277
168. Mulfort KL, Tiede DM (2010) Supramolecular cobaloxime assemblies for H2 photocatalysis:
an initial solution state structure-function analysis. J Phys Chem B 114(45):14572–14581
169. Gersten SW, Samuels GJ, Meyer TJ (1982) Catalytic oxidation of water by an oxo-bridged
ruthenium dimer. J Am Chem Soc 104(14):4029–4030
170. Gilbert JA, Eggleston DS, Murphy WR, Geselowitz DA, Gersten SW, Hodgson DJ, Meyer TJ
(1985) Structure and redox properties of the water-oxidation catalyst [(bpy)2(OH2)RuORu
(OH2)(bpy)2]4+. J Am Chem Soc 107(13):3855–3864
171. Collin JP, Sauvage JP (1986) Synthesis and study of mononuclear ruthenium(II) complexes of
sterically hindering diimine chelates. Implications for the catalytic oxidation of water to
molecular oxygen. Inorg Chem 25(2):135–141
172. Wada T, Tsuge K, Tanaka K (2000) Electrochemical oxidation of water to dioxygen catalyzed
by the oxidized form of the bis(ruthenium – hydroxo) complex in H2O. Angew Chem Int Ed
39(8):1479–1482
173. Wada T, Tsuge K, Tanaka K (2001) Syntheses and redox properties of bis(hydroxoruthenium)
complexes with quinone and bipyridine ligands. Water-oxidation catalysis. Inorg Chem 40
(2):329–337
444
H.-T. Zhang and M.-T. Zhang
site of [Fe]hydrogenase featuring an acylmethyl(hydroxymethyl)pyridine ligand. Inorg Chem
51(14):7466–7468
157. Bichler B, Holzhacker C, Stoger B, Puchberger M, Veiros LF, Kirchner K (2013) Heterolytic
cleavage of dihydrogen by an iron(II) PNP pincer complex via metal-ligand cooperation.
Organometallics 32(15):4114–4121
158. Durgaprasad G, Xie ZL, Rose MJ (2016) Iron hydride detection and intramolecular hydride
transfer in a synthetic model of mono-iron hydrogenase with a CNS chelate. Inorg Chem 55
(2):386–389
159. Xie ZL, Durgaprasad G, Ali AK, Rose MJ (2017) Substitution reactions of iron(ii) carbamoylthioether complexes related to mono-iron hydrogenase. Dalton Trans 46(33):10814–10829
160. Hirotsu M, Santo K, Hashimoto H, Kinoshita I (2012) Carbon- and sulfur-bridged diiron
carbonyl complexes containing N,C,S-tridentate ligands derived from functionalized
dibenzothiophenes: mimics of the [FeFe]-hydrogenase active site. Organometallics 31
(21):7548–7557
161. Hirotsu M, Tsuboi C, Nishioka T, Kinoshita I (2011) Carbon-sulfur bond cleavage reactions of
dibenzothiophene derivatives mediated by iron and ruthenium carbonyls. Dalton Trans 40
(4):785–787
162. Nakae T, Hirotsu M, Kinoshita I (2015) Di- and mononuclear iron complexes of N,C,Stridentate ligands containing an Aminopyridyl group: effect of the pendant amine site on
catalytic properties for proton reduction. Organometallics 34(16):3988–3997
163. Hirotsu M, Santo K, Tsuboi C, Kinoshita I (2014) Diiron carbonyl complexes bearing an N,C,
S-pincer ligand: reactivity toward phosphines, heterolytic Fe–Fe cleavage, and electrocatalytic
proton reduction. Organometallics 33(16):4260–4268
164. Ott S, Kritikos M, Akermark B, Sun L (2003) Synthesis and structure of a biomimetic model of
the iron hydrogenase active site covalently linked to a ruthenium photosensitizer. Angew
Chem Int Ed Engl 42(28):3285–3288
165. Hammarström L, Barigelletti F, Flamigni L, Indelli MT, Armaroli N, Calogero G,
Guardigli M, Sour A, Collin J-P, Sauvage J-P (1997) A study on delocalization of MLCT
excited states by rigid bridging ligands in homometallic dinuclear complexes of ruthenium(II).
Chem A Eur J 101(48):9061–9069
166. Ott S, Borgstrom M, Kritikos M, Lomoth R, Bergquist J, Akermark B, Hammarstrom L, Sun L
(2004) Model of the iron hydrogenase active site covalently linked to a ruthenium photosensitizer: synthesis and photophysical properties. Inorg Chem 43(15):4683–4692
167. Hawecker JL, Lehn JM, Ziessel R (1983) Efficient homogeneous photochemical hydrogen
generation and water reduction mediated by cobaloxime or macrocyclic cobalt complexes.
New J Chem 7:271–277
168. Mulfort KL, Tiede DM (2010) Supramolecular cobaloxime assemblies for H2 photocatalysis:
an initial solution state structure-function analysis. J Phys Chem B 114(45):14572–14581
169. Gersten SW, Samuels GJ, Meyer TJ (1982) Catalytic oxidation of water by an oxo-bridged
ruthenium dimer. J Am Chem Soc 104(14):4029–4030
170. Gilbert JA, Eggleston DS, Murphy WR, Geselowitz DA, Gersten SW, Hodgson DJ, Meyer TJ
(1985) Structure and redox properties of the water-oxidation catalyst [(bpy)2(OH2)RuORu
(OH2)(bpy)2]4+. J Am Chem Soc 107(13):3855–3864
171. Collin JP, Sauvage JP (1986) Synthesis and study of mononuclear ruthenium(II) complexes of
sterically hindering diimine chelates. Implications for the catalytic oxidation of water to
molecular oxygen. Inorg Chem 25(2):135–141
172. Wada T, Tsuge K, Tanaka K (2000) Electrochemical oxidation of water to dioxygen catalyzed
by the oxidized form of the bis(ruthenium – hydroxo) complex in H2O. Angew Chem Int Ed
39(8):1479–1482
173. Wada T, Tsuge K, Tanaka K (2001) Syntheses and redox properties of bis(hydroxoruthenium)
complexes with quinone and bipyridine ligands. Water-oxidation catalysis. Inorg Chem 40
(2):329–337
444
H.-T. Zhang and M.-T. Zhang