90
3 Theoretical Study of Rh-Catalyzed …
88. Ryu J, Cho SH, Chang S (2012) A versatile Rhodium(I) catalyst system for the addition of
heteroarenes to both alkenes and alkynes by a C–H bond activation. Angew Chem Int Ed
51:3677–3681
89. Schipper DJ, Hutchinson M, Fagnou K (2010) Rhodium(III)-catalyzed intermolecular
hydroarylation of alkynes. J Am Chem Soc 132:6910–6911
90. Shi L, Zhong X, She H, Lei Z, Li F (2015) Manganese catalyzed C–H functionalization of
indoles with alkynes to synthesize bis/trisubstituted indolylalkenes and carbazoles: the acid
is the key to control selectivity. Chem Commun 51:7136–7139
91. Shibata K, Natsui S, Chatani N (2017) Rhodium-catalyzed alkenylation of C–H bonds in
aromatic amides with alkynes. Org Lett 19:2234–2237
92 Tan YX, Liu XY, Zhang SQ, Xie PP, Wang X, Feng KR, Yang SQ, He ZT, Hong X, Tian P, Lin
GQ (2020) An unconventional trans-exo-selective cyclization of alkyne-tethered cyclohexadienones initiated by Rhodium(III)-catalyzed C–H activation via insertion relay. CCS Chem
2:1582–1595
93. Unoh Y, Yokoyama Y, Satoh T, Hirano K, Miura M (2016) Regioselective synthesis of
benzo[b]phosphole derivatives via direct ortho-alkenylation and cyclization of arylthiophosphinamides. Org Lett 18:5436–5439
94. Xu HJ, Kang YS, Shi H, Zhang P, Chen YK, Zhang B, Liu ZQ, Zhao J, Sun WY, Yu JQ, Lu Y
(2019) Rh(III)-Catalyzed meta-C–H alkenylation with alkynes. J Am Chem Soc 141:76–79
95. Zhao H, Xu X, Luo Z, Cao L, Li B, Li H, Xu L, Fan Q, Walsh PJ (2019) Rhodium(I)-catalyzed
C6-selective C–H alkenylation and polyenylation of 2-pyridones with alkenyl and conjugated
polyenyl carboxylic acids. Chem Sci 10:10089–10096
96. Liu B, Zhou T, Li B, Xu S, Song H, Wang B (2014) Rhodium(III)-catalyzed alkenylation
reactions of 8-methylquinolines with alkynes by C(sp3)-H activation. Angew Chem Int Ed
53:4191–4195
97. Jiang J, Ramozzi R, Morokuma K (2015) RhIII-catalyzed C(sp3) -H bond activation by an
external base metalation/deprotonation mechanism: a theoretical study. Chem Eur J 21:11158–
11164
98. Fukui Y, Liu P, Liu Q, He ZT, Wu NY, Tian P, Lin G-Q (2014) Tunable arylative cyclization of
1,6-Enynes triggered by Rhodium(III)-catalyzed C–H activation. J Am Chem Soc 136:15607–
15614
99. Du L, Xu Y, Yang S, Li J, Fu X (2016) Computational insights into the Rhodium(III)-catalyzed
coupling of benzamides and 1,6-enynes via a tunable arylative cyclization. J Org Chem
81:1921–1929
100. Yang YF, Houk KN, Wu YD (2016) Computational exploration of RhIII/RhV and RhIII/RhI
catalysis in Rhodium(III)-catalyzed C-H activation reactions of N-phenoxyacetamides with
alkynes. J Am Chem Soc 138:6861–6868
101. Han SH, Choi M, Jeong T, Sharma S, Mishra NK, Park J, Oh JS, Kim WJ, Lee JS, Kim IS
(2015) Rhodium-catalyzed C–H alkylation of indolines with allylic alcohols: direct access to
beta-aryl carbonyl compounds. J Org Chem 80:11092–11099
102. Liu B, Fan Y, Gao Y, Sun C, Xu C, Zhu J (2012) Rhodium(III)-catalyzed nitroso directed
C–H olefination of arenes high-yield, versatile coupling under mild conditions. J Am Chem
Soc 135:468–473
103. Liu B, Hu P, Zhou X, Bai D, Chang J, Li X (2017) Cp*Rh(III)-catalyzed mild addition of
C(sp3)-H bonds to α, β-unsaturated aldehydes and ketones. Org Lett 19:2086–2089
104. Patureau FW, Besset T, Kuhl N, Glorius F (2011) Diverse strategies toward indenol and
fulvene derivatives: Rh-catalyzed C–H activation of aryl ketones followed by coupling with
internal alkynes. J Am Chem Soc 133:2154–2156
105. Takahashi H, Inagaki S, Yoshii N, Gao F, Nishihara Y, Takagi K (2009) Rh-catalyzed negishi
alkyl-aryl cross-coupling leading to α- or β-phosphoryl-substituted alkylarenes. J Org Chem
74:2794–2797
106. Wang H, Yu S, Qi Z, Li X (2015) Rh(III)-catalyzed C–H alkylation of arenes using alkylboron
reagents. Org Lett 17:2812–2815
3 Theoretical Study of Rh-Catalyzed …
88. Ryu J, Cho SH, Chang S (2012) A versatile Rhodium(I) catalyst system for the addition of
heteroarenes to both alkenes and alkynes by a C–H bond activation. Angew Chem Int Ed
51:3677–3681
89. Schipper DJ, Hutchinson M, Fagnou K (2010) Rhodium(III)-catalyzed intermolecular
hydroarylation of alkynes. J Am Chem Soc 132:6910–6911
90. Shi L, Zhong X, She H, Lei Z, Li F (2015) Manganese catalyzed C–H functionalization of
indoles with alkynes to synthesize bis/trisubstituted indolylalkenes and carbazoles: the acid
is the key to control selectivity. Chem Commun 51:7136–7139
91. Shibata K, Natsui S, Chatani N (2017) Rhodium-catalyzed alkenylation of C–H bonds in
aromatic amides with alkynes. Org Lett 19:2234–2237
92 Tan YX, Liu XY, Zhang SQ, Xie PP, Wang X, Feng KR, Yang SQ, He ZT, Hong X, Tian P, Lin
GQ (2020) An unconventional trans-exo-selective cyclization of alkyne-tethered cyclohexadienones initiated by Rhodium(III)-catalyzed C–H activation via insertion relay. CCS Chem
2:1582–1595
93. Unoh Y, Yokoyama Y, Satoh T, Hirano K, Miura M (2016) Regioselective synthesis of
benzo[b]phosphole derivatives via direct ortho-alkenylation and cyclization of arylthiophosphinamides. Org Lett 18:5436–5439
94. Xu HJ, Kang YS, Shi H, Zhang P, Chen YK, Zhang B, Liu ZQ, Zhao J, Sun WY, Yu JQ, Lu Y
(2019) Rh(III)-Catalyzed meta-C–H alkenylation with alkynes. J Am Chem Soc 141:76–79
95. Zhao H, Xu X, Luo Z, Cao L, Li B, Li H, Xu L, Fan Q, Walsh PJ (2019) Rhodium(I)-catalyzed
C6-selective C–H alkenylation and polyenylation of 2-pyridones with alkenyl and conjugated
polyenyl carboxylic acids. Chem Sci 10:10089–10096
96. Liu B, Zhou T, Li B, Xu S, Song H, Wang B (2014) Rhodium(III)-catalyzed alkenylation
reactions of 8-methylquinolines with alkynes by C(sp3)-H activation. Angew Chem Int Ed
53:4191–4195
97. Jiang J, Ramozzi R, Morokuma K (2015) RhIII-catalyzed C(sp3) -H bond activation by an
external base metalation/deprotonation mechanism: a theoretical study. Chem Eur J 21:11158–
11164
98. Fukui Y, Liu P, Liu Q, He ZT, Wu NY, Tian P, Lin G-Q (2014) Tunable arylative cyclization of
1,6-Enynes triggered by Rhodium(III)-catalyzed C–H activation. J Am Chem Soc 136:15607–
15614
99. Du L, Xu Y, Yang S, Li J, Fu X (2016) Computational insights into the Rhodium(III)-catalyzed
coupling of benzamides and 1,6-enynes via a tunable arylative cyclization. J Org Chem
81:1921–1929
100. Yang YF, Houk KN, Wu YD (2016) Computational exploration of RhIII/RhV and RhIII/RhI
catalysis in Rhodium(III)-catalyzed C-H activation reactions of N-phenoxyacetamides with
alkynes. J Am Chem Soc 138:6861–6868
101. Han SH, Choi M, Jeong T, Sharma S, Mishra NK, Park J, Oh JS, Kim WJ, Lee JS, Kim IS
(2015) Rhodium-catalyzed C–H alkylation of indolines with allylic alcohols: direct access to
beta-aryl carbonyl compounds. J Org Chem 80:11092–11099
102. Liu B, Fan Y, Gao Y, Sun C, Xu C, Zhu J (2012) Rhodium(III)-catalyzed nitroso directed
C–H olefination of arenes high-yield, versatile coupling under mild conditions. J Am Chem
Soc 135:468–473
103. Liu B, Hu P, Zhou X, Bai D, Chang J, Li X (2017) Cp*Rh(III)-catalyzed mild addition of
C(sp3)-H bonds to α, β-unsaturated aldehydes and ketones. Org Lett 19:2086–2089
104. Patureau FW, Besset T, Kuhl N, Glorius F (2011) Diverse strategies toward indenol and
fulvene derivatives: Rh-catalyzed C–H activation of aryl ketones followed by coupling with
internal alkynes. J Am Chem Soc 133:2154–2156
105. Takahashi H, Inagaki S, Yoshii N, Gao F, Nishihara Y, Takagi K (2009) Rh-catalyzed negishi
alkyl-aryl cross-coupling leading to α- or β-phosphoryl-substituted alkylarenes. J Org Chem
74:2794–2797
106. Wang H, Yu S, Qi Z, Li X (2015) Rh(III)-catalyzed C–H alkylation of arenes using alkylboron
reagents. Org Lett 17:2812–2815