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Org Lett 15:112–115
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113. Li Y, Xie F, Li X (2016) Formal gold- and rhodium-catalyzed regiodivergent C–H alkynylation
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115. Xie F, Qi Z, Yu S, Li X (2014) Rh(III)- and Ir(III)-catalyzed C–H alkynylation of arenes under
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119. Collins KD, Lied F, Glorius F (2014) Preparation of conjugated 1,3-enynes by Rh(III)catalysed alkynylation of alkenes via C-H activation. Chem Commun 50:4459–4461
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121. Zhao F, Xu B, Ren D, Han L, Yu Z, Liu T (2018) C–H Alkynylation of N-methylisoquinolone
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122. Asaumi T, Matsuo T, Fukuyama T, Ie Y, Kakiuchi F, Chatani N (2004) Ruthenium-and
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123. Guan ZH, Ren ZH, Spinella SM, Yu S, Liang Y-M, Zhang X (2009) Rhodium catalyzed
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124. Lang R, Wu J, Shi L, Xia C, Li F (2011) Regioselective Rh-catalyzed direct carbonylation of
indoles to synthesize indole-3-carboxylates. Chem Commun 47:12553–12555
125. Li X, Li X, Jiao N (2015) Rh-catalyzed construction of quinolin-2(1H)-ones via C–H bond
activation of simple anilines with CO and alkynes. J Am Chem Soc 137:9246–9249
126. Wang GW, Bower JF (2018) Modular access to azepines by directed carbonylative C–C bond
activation of aminocyclopropanes. J Am Chem Soc 140:2743–2747
127. Yutaka Ishii NC, Kakiuchi Fumitoshi, Murai Shinji (1997) Rhodium catalyzed reaction of
N-(2-Pyridinyl)piperazines with CO and ethylene. a novel carbonylation at a C–H bond in
the piperazine ring. Organometallics 16:3615–3622
128. Gao B, Liu S, Lan Y, Huang H (2016) Rhodium-catalyzed cyclocarbonylation of ketimines
via C–H bond activation. Organometallics 35:1480–1487
129. Cho SH, Kim JY, Kwak J, Chang S (2011) Recent advances in the transition metal-catalyzed
twofold oxidative C–H bond activation strategy for C–C and C–N bond formation. Chem Soc
Rev 40:5068–5083
130. Park S, Seo B, Shin S, Son JY, Lee PH (2013) Rhodium-catalyzed oxidative coupling through
C–H activation and annulation directed by phosphonamide and phosphinamide groups. Chem
Commun (Camb) 49:8671–8673
91
107. Zhang C, Wang M, Fan Z, Sun LP, Zhang A (2014) Substituent-enabled oxidative dehydrogenative cross-coupling of 1,4-naphthoquinones with alkenes. J Org Chem 79:7626–7632
108. Brand JP, Charpentier J, Waser J (2009) Direct alkynylation of indole and pyrrole heterocycles.
Angew Chem Int Ed 48:9346–9349
109. Brand JP, Chevalley C, Scopelliti R, Waser J (2012) Ethynyl benziodoxolones for the direct
alkynylation of heterocycles: structural requirement, improved procedure for pyrroles, and
insights into the mechanism. Chem Eur J 18:5655–5666
110. Brand JP, Chevalley C, Waser J (2011) One-pot gold-catalyzed synthesis of 3-silylethynyl
indoles from unprotected o-alkynylanilines Beilstein. J Org Chem 7:565–569
111. Tolnai GL, Ganss S, Brand JP, Waser J (2013) C2-selective direct alkynylation of indoles.
Org Lett 15:112–115
112. Waser J, Brand J (2012) Synthesis of 1-[(Triisopropylsilyl)ethynyl]-1λ3,2-benziodoxol3(1H)-one and Alkynylation of Indoles, Thiophenes, and Anilines. Synthesis 44:1155–1158
113. Li Y, Xie F, Li X (2016) Formal gold- and rhodium-catalyzed regiodivergent C–H alkynylation
of 2-pyridones. J Org Chem 81:715–722
114. Wang H, Xie F, Qi Z, Li X (2015) Iridium- and rhodium-catalyzed C–H activation and formyl
alkynylation of benzaldehydes under chelation-assistance. Org Lett 17:920–923
115. Xie F, Qi Z, Yu S, Li X (2014) Rh(III)- and Ir(III)-catalyzed C–H alkynylation of arenes under
chelation assistance. J Am Chem Soc 136:4780–4787
116. Feng C, Feng D, Luo Y, Loh T-P (2014) Rhodium(III)-catalyzed olefinic C-H alkynylation
of enamides at room temperature. Chem Commun 50:9865–9868
117. Feng C, Feng D, Luo Y, Loh T-P (2014) Rhodium(III)-catalyzed olefinic C–H alkynylation
of acrylamides using tosyl-imide as directing group. Org Lett 16:5956–5959
118. Feng C, Loh TP (2014) Rhodium-catalyzed C–H alkynylation of arenes at room temperature.
Angew Chem 126:2760–2764
119. Collins KD, Lied F, Glorius F (2014) Preparation of conjugated 1,3-enynes by Rh(III)catalysed alkynylation of alkenes via C-H activation. Chem Commun 50:4459–4461
120. Shaikh AC, Shinde DR, Patil NT (2016) Gold vs rhodium catalysis: tuning reactivity through
catalyst control in the C–H alkynylation of isoquinolones. Org Lett 18:1056–1059
121. Zhao F, Xu B, Ren D, Han L, Yu Z, Liu T (2018) C–H Alkynylation of N-methylisoquinolone
by rhodium or gold catalysis: theoretical studies on the mechanism, regioselectivity, and role
of TIPS-EBX. Organometallics 37:1026–1033
122. Asaumi T, Matsuo T, Fukuyama T, Ie Y, Kakiuchi F, Chatani N (2004) Ruthenium-and
rhodium-catalyzed direct carbonylation of the ortho C–H bond in the benzene ring of
N-arylpyrazoles. J Org Chem 69:4433–4440
123. Guan ZH, Ren ZH, Spinella SM, Yu S, Liang Y-M, Zhang X (2009) Rhodium catalyzed
direct oxidative carbonylation of aromatic C–H bond with CO and alcohols. J Am Chem Soc
131:729–733
124. Lang R, Wu J, Shi L, Xia C, Li F (2011) Regioselective Rh-catalyzed direct carbonylation of
indoles to synthesize indole-3-carboxylates. Chem Commun 47:12553–12555
125. Li X, Li X, Jiao N (2015) Rh-catalyzed construction of quinolin-2(1H)-ones via C–H bond
activation of simple anilines with CO and alkynes. J Am Chem Soc 137:9246–9249
126. Wang GW, Bower JF (2018) Modular access to azepines by directed carbonylative C–C bond
activation of aminocyclopropanes. J Am Chem Soc 140:2743–2747
127. Yutaka Ishii NC, Kakiuchi Fumitoshi, Murai Shinji (1997) Rhodium catalyzed reaction of
N-(2-Pyridinyl)piperazines with CO and ethylene. a novel carbonylation at a C–H bond in
the piperazine ring. Organometallics 16:3615–3622
128. Gao B, Liu S, Lan Y, Huang H (2016) Rhodium-catalyzed cyclocarbonylation of ketimines
via C–H bond activation. Organometallics 35:1480–1487
129. Cho SH, Kim JY, Kwak J, Chang S (2011) Recent advances in the transition metal-catalyzed
twofold oxidative C–H bond activation strategy for C–C and C–N bond formation. Chem Soc
Rev 40:5068–5083
130. Park S, Seo B, Shin S, Son JY, Lee PH (2013) Rhodium-catalyzed oxidative coupling through
C–H activation and annulation directed by phosphonamide and phosphinamide groups. Chem
Commun (Camb) 49:8671–8673