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85. Nobushige K, Hirano K, Satoh T, Miura M (2014) Rhodium(III)-catalyzed ortho-alkenylation
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66. Satoh T, Miura M (2010) Oxidative coupling of aromatic substrates with alkynes and alkenes
under rhodium catalysis. Chem Eur J 16:11212–11222
67. Takahama Y, Shibata Y, Tanaka K (2015) Oxidative olefination of anilides with unactivated
alkenes catalyzed by an (electron-deficient η5-cyclopentadienyl)Rhodium(iii) complex under
ambient conditions. Chem -Eur J 21:9053–9056
68. Tsai AS, Brasse M, Bergman RG, Ellman JA (2011) Rh(III)-catalyzed oxidative coupling of
unactivated alkenes via C–H activation. Org Lett 13:540–542
69. Xue X, Xu J, Zhang L, Xu C, Pan Y, Xu L, Li H, Zhang W (2016) Rhodium(III)-catalyzed
direct C–H olefination of arenes with aliphatic olefins. Adv Synth Catal 358:573–583
70. Zhao P, Wang F, Han K, Li X (2012) Rhodium(III)-catalyzed cyclization-olefination of nacetoxyl ketoimine-alkynes. Org Lett 14:3400–3403
71. Zheng J, Cui W-J, Zheng C, You S-L (2016) Synthesis and application of chiral spiro cp ligands
in rhodium-catalyzed asymmetric oxidative coupling of biaryl compounds with alkenes. J Am
Chem Soc 138:5242–5245
72. Zheng J, You S-L (2014) Construction of axial chirality by rhodium-catalyzed asymmetric
dehydrogenative heck coupling of biaryl compounds with alkenes. Angew Chem Int Ed
53:13244–13247
73. Zheng L, Wang J (2012) Direct oxidative coupling of arenes with olefins by Rh-Catalyzed -H
activation in air: observation of a strong cooperation of the acid. Chem Eur J 18:9699–9704
74. Zhu W, Gunnoe TB (2020) Advances in rhodium-catalyzed oxidative arene alkenylation. Acc
Chem Res 53:920–936
75. Zhu W, Gunnoe TB (2020) Rhodium-catalyzed arene alkenylation using only dioxygen as the
oxidant. ACS Catal 10:11519–11531
76. Gong TJ, Xiao B, Liu ZJ, Wan J, Xu J, Luo DF, Fu Y, Liu L (2011) Rhodium-catalyzed
selective C–H activation/olefination of phenol carbamates. Org Lett 13:3235–3237
77. Zhang Q, Yu H-Z, Li Y-T, Liu L, Huang Y, Fu Y (2013) Computational study on mechanism
of Rh(III)-catalyzed oxidative heck coupling of phenol carbamates with alkenes. Dalton Trans
42:4175–4184
78. Xu L, Zhang C, He Y, Tan L, Ma D (2015) Rhodium-catalyzed regioselective C7functionalization of N-pivaloylindoles. Angew Chem Int Ed 55:321–325
79. Han L, Ma X, Liu Y, Yu Z, Liu T (2018) Mechanistic insight into the C7-selective C–H
functionalization of N-acyl indole catalyzed by a rhodium complex: a theoretical study. Org
Chem Front 5:725–733
80. Azpíroz R, Di Giuseppe A, Urriolabeitia A, Passarelli V, Polo V, Pérez-Torrente JJ, Oro
LA, Castarlenas R (2019) Hydride-rhodium(iii)-n-heterocyclic carbene catalyst for tandem
alkylation/alkenylation via C–H activation. ACS Catal 9:9372–9386
81. Boyarskiy VP, Ryabukhin DS, Bokach NA, Vasilyev AV (2016) Alkenylation of arenes and
heteroarenes with alkynes. Chem Rev 116:5894–5986
82. Chatupheeraphat A, Rueping M, Magre M (2019) Chemo- and regioselective magnesiumcatalyzed ortho-alkenylation of anilines. Org Lett 21:9153–9157
83. Luo J, Zhang C, Su F, Zhang B, Jia F (2020) Mechanism and origins of regio- and mono/diselectivity in Rh(III)-Catalyzed meta-C–H alkenylation with alkynes. Eur J Org Chem
2020:3294–3302
84. Martinez AM, Echavarren J, Alonso I, Rodriguez N, Gomez Arrayas R, Carretero JC (2015)
Rh(I)/Rh(III) catalyst-controlled divergent aryl/heteroaryl C–H bond functionalization of
picolinamides with alkynes. Chem Sci 6:5802–5814
85. Nobushige K, Hirano K, Satoh T, Miura M (2014) Rhodium(III)-catalyzed ortho-alkenylation
through C–H bond cleavage directed by sulfoxide groups. Org Lett 16:1188–1191
86. Qiu Y, Scheremetjew A, Ackermann L (2019) Electro-Oxidative C–C alkenylation by
RHODIUM(III) catalysis. J Am Chem Soc 141:2731–2738
87. Qiu Z, Deng J, Zhang Z, Wu C, Li J, Liao X (2016) Mechanism of the Rhodium(III)catalyzed alkenylation reaction of N-phenoxyacetamide with styrene or N-tosylhydrazone: a
computational study. Dalton Trans 45:8118–8126