120
4 Theoretical View of Rh-Catalyzed C–H Functionalization …
27. Wang H, Tang G, Li X (2015) Rhodium(III)-catalyzed amidation of unactivated C(sp(3))-H
bonds. Angew Chem Int Ed 54:13049–13052
28. Dateer RB, Chang S (2015) Selective cyclization of arylnitrones to indolines under external
oxidant-free conditions: Dual role of Rh(III) catalyst in the C–H activation and oxygen atom
transfer. J Am Chem Soc 137:4908–4911
29. Lerchen A, Knecht T, Daniliuc CG, Glorius F (2016) Unnatural amino acid synthesis enabled
by the regioselective cobalt(III)-catalyzed intermolecular carboamination of alkenes. Angew
Chem Int Ed 55:15166–15170
30. Yu S, Li Y, Zhou X, Wang H, Kong L, Li X (2016) Access to structurally diverse quinolinefused heterocycles via rhodium(III)-catalyzed C–C/C–N coupling of bifunctional substrates.
Org Lett 18:2812–2815
31. Yu S, Tang G, Li Y, Zhou X, Lan Y, Li X (2016) Anthranil: an aminating reagent leading
to bifunctionality for both C(sp(3))-H and C(sp(2))-H under rhodium(III) catalysis. Angew
Chem Int Ed 55:8696–8700
32. Liu G, Shen Y, Zhou Z, Lu X (2013) Rhodium(III)-catalyzed redox-neutral coupling of Nphenoxyacetamides and alkynes with tunable selectivity. Angew Chem Int Ed 52:6033–6037
33. Piou T, Rovis T (2015) Rhodium-catalysed syn-carboamination of alkenes via a transient
directing group. Nature 527:86–90
34. Kim JY, Park SH, Ryu J, Cho SH, Kim SH, Chang S (2012) Rhodium-catalyzed intermolecular
amidation of arenes with sulfonyl azides via chelation-assisted C–H bond activation. J Am
Chem Soc 134:9110–9113
35. Shin K, Baek Y, Chang S (2013) Direct C–H amination of arenes with alkyl azides under
rhodium catalysis. Angew Chem Int Ed 52:8031–8036
36. Park SH, Kwak J, Shin K, Ryu J, Park Y, Chang S (2014) Mechanistic studies of the rhodiumcatalyzed direct C–H amination reaction using azides as the nitrogen source. J Am Chem Soc
136:2492–2502
37. Wang X, Gensch T, Lerchen A, Daniliuc CG, Glorius F (2017) Cp*Rh(III)/Bicyclic olefin
cocatalyzed C–H bond amidation by intramolecular amide transfer. J Am Chem Soc
139:6506–6512
38. Xie F, Qi Z, Li X (2013) Rhodium(III)-catalyzed azidation and nitration of arenes by C–H
activation. Angew Chem Int Ed 52:11862–11866
39. Wang W, Pan C, Chen F, Cheng J (2011) Copper(II)-catalyzed ortho-functionalization of
2-arylpyridines with acyl chlorides. Chem Commun 47:3978–3980
40. Chen X, Hao X-S, Goodhue CE, Yu J-Q (2006) Cu(II)-catalyzed functionalizations of aryl
C–H bonds using O 2 as an oxidant. J Am Chem Soc 128:6790–6791
41. Du Z, Gao L, Lin Y (2015) Cu-catalyzed aryl C–H halogenation using N-halosuccinimides
via assistance of benzoic acid. Chem Res Chin Univ 31:167–170
42. Dick AR, Hull KL, Sanford MS (2004) A highly selective catalytic method for the oxidative
functionalization of C–H bonds. J Am Chem Soc 126:2300–2301
43. Bedford RB, Haddow MF, Mitchell CJ, Webster RL (2011) Mild C–H halogenation of anilides
and the isolation of an unusual palladium(I)-palladium(II) species. Angew Chem Int Ed
50:5524–5527
44. Zhan B-B, Liu Y-H, Hu F, Shi B-F (2016) Nickel-catalyzed ortho-halogenation of unactivated
(hetero)aryl C–H bonds with lithium halides using a removable auxiliary. Chem Commun
52:4934–4937
45. Li J-J, Mei T-S, Yu J-Q (2008) Synthesis of indolines and tetrahydroisoquinolines from
arylethylamines by Pd(II)-catalyzed C–H activation reactions. Angew Chem Int Ed 47:6452–
6455
46. Lied F, Lerchen A, Knecht T, Mück-Lichtenfeld C, Glorius F (2016) Versatile Cp*Rh(III)catalyzed selective ortho-chlorination of arenes and heteroarenes. ACS Catal 6:7839–7843
47. Schroder N, Wencel-Delord J, Glorius F (2012) High-yielding, versatile, and practical
[Rh(III)Cp*]-catalyzed ortho bromination and iodination of arenes. J Am Chem Soc
134:8298–8301
4 Theoretical View of Rh-Catalyzed C–H Functionalization …
27. Wang H, Tang G, Li X (2015) Rhodium(III)-catalyzed amidation of unactivated C(sp(3))-H
bonds. Angew Chem Int Ed 54:13049–13052
28. Dateer RB, Chang S (2015) Selective cyclization of arylnitrones to indolines under external
oxidant-free conditions: Dual role of Rh(III) catalyst in the C–H activation and oxygen atom
transfer. J Am Chem Soc 137:4908–4911
29. Lerchen A, Knecht T, Daniliuc CG, Glorius F (2016) Unnatural amino acid synthesis enabled
by the regioselective cobalt(III)-catalyzed intermolecular carboamination of alkenes. Angew
Chem Int Ed 55:15166–15170
30. Yu S, Li Y, Zhou X, Wang H, Kong L, Li X (2016) Access to structurally diverse quinolinefused heterocycles via rhodium(III)-catalyzed C–C/C–N coupling of bifunctional substrates.
Org Lett 18:2812–2815
31. Yu S, Tang G, Li Y, Zhou X, Lan Y, Li X (2016) Anthranil: an aminating reagent leading
to bifunctionality for both C(sp(3))-H and C(sp(2))-H under rhodium(III) catalysis. Angew
Chem Int Ed 55:8696–8700
32. Liu G, Shen Y, Zhou Z, Lu X (2013) Rhodium(III)-catalyzed redox-neutral coupling of Nphenoxyacetamides and alkynes with tunable selectivity. Angew Chem Int Ed 52:6033–6037
33. Piou T, Rovis T (2015) Rhodium-catalysed syn-carboamination of alkenes via a transient
directing group. Nature 527:86–90
34. Kim JY, Park SH, Ryu J, Cho SH, Kim SH, Chang S (2012) Rhodium-catalyzed intermolecular
amidation of arenes with sulfonyl azides via chelation-assisted C–H bond activation. J Am
Chem Soc 134:9110–9113
35. Shin K, Baek Y, Chang S (2013) Direct C–H amination of arenes with alkyl azides under
rhodium catalysis. Angew Chem Int Ed 52:8031–8036
36. Park SH, Kwak J, Shin K, Ryu J, Park Y, Chang S (2014) Mechanistic studies of the rhodiumcatalyzed direct C–H amination reaction using azides as the nitrogen source. J Am Chem Soc
136:2492–2502
37. Wang X, Gensch T, Lerchen A, Daniliuc CG, Glorius F (2017) Cp*Rh(III)/Bicyclic olefin
cocatalyzed C–H bond amidation by intramolecular amide transfer. J Am Chem Soc
139:6506–6512
38. Xie F, Qi Z, Li X (2013) Rhodium(III)-catalyzed azidation and nitration of arenes by C–H
activation. Angew Chem Int Ed 52:11862–11866
39. Wang W, Pan C, Chen F, Cheng J (2011) Copper(II)-catalyzed ortho-functionalization of
2-arylpyridines with acyl chlorides. Chem Commun 47:3978–3980
40. Chen X, Hao X-S, Goodhue CE, Yu J-Q (2006) Cu(II)-catalyzed functionalizations of aryl
C–H bonds using O 2 as an oxidant. J Am Chem Soc 128:6790–6791
41. Du Z, Gao L, Lin Y (2015) Cu-catalyzed aryl C–H halogenation using N-halosuccinimides
via assistance of benzoic acid. Chem Res Chin Univ 31:167–170
42. Dick AR, Hull KL, Sanford MS (2004) A highly selective catalytic method for the oxidative
functionalization of C–H bonds. J Am Chem Soc 126:2300–2301
43. Bedford RB, Haddow MF, Mitchell CJ, Webster RL (2011) Mild C–H halogenation of anilides
and the isolation of an unusual palladium(I)-palladium(II) species. Angew Chem Int Ed
50:5524–5527
44. Zhan B-B, Liu Y-H, Hu F, Shi B-F (2016) Nickel-catalyzed ortho-halogenation of unactivated
(hetero)aryl C–H bonds with lithium halides using a removable auxiliary. Chem Commun
52:4934–4937
45. Li J-J, Mei T-S, Yu J-Q (2008) Synthesis of indolines and tetrahydroisoquinolines from
arylethylamines by Pd(II)-catalyzed C–H activation reactions. Angew Chem Int Ed 47:6452–
6455
46. Lied F, Lerchen A, Knecht T, Mück-Lichtenfeld C, Glorius F (2016) Versatile Cp*Rh(III)catalyzed selective ortho-chlorination of arenes and heteroarenes. ACS Catal 6:7839–7843
47. Schroder N, Wencel-Delord J, Glorius F (2012) High-yielding, versatile, and practical
[Rh(III)Cp*]-catalyzed ortho bromination and iodination of arenes. J Am Chem Soc
134:8298–8301