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49. Zhang P, Hong L, Li G, Wang R (2015) Sodium halides as halogenating reagents: rhodium(III)catalyzed versatile and practical halogenation of aryl compounds. Adv Synth Catal 357:345–
349
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54. Chen H, Hartwig JF (1999) Catalytic, regiospecific end-functionalization of alkanes: rheniumcatalyzed borylation under photochemical conditions. Angew Chem Int Ed 38:3391–3393
55. Kleeberg C, Dang L, Lin Z, Marder TB (2009) A facile route to aryl boronates: roomtemperature, copper-catalyzed borylation of aryl halides with alkoxy diboron reagents. Angew
Chem Int Ed 48:5350–5354
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pinacolborane with aryl iodides at room temperature. Org Lett 8:261–263
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58. Liskey CW, Hartwig JF (2013) Iridium-catalyzed C–H borylation of cyclopropanes. J Am
Chem Soc 135:3375–3378
59. Molander GA, Cavalcanti LN, Garcia-Garcia C (2013) Nickel-catalyzed borylation of halides
and pseudohalides with tetrahydroxydiboron [B2(OH)4]. J Org Chem 78:6427–6439
60. Chen H, Schlecht S, Semple TC, Hartwig JF (2000) Thermal, catalytic, regiospecific
functionalization of alkanes. Science 287:1995–1997
61. Mkhalid IA, Barnard JH, Marder TB, Murphy JM, Hartwig JF (2010) C–H activation for the
construction of C–B bonds. Chem Rev 110:890–931
62. Tobisu M, Kinuta H, Kita Y, Remond E, Chatani N (2012) Rhodium(I)-catalyzed borylation
of nitriles through the cleavage of carbon-cyano bonds. J Am Chem Soc 134:115–118
63. Murphy JM, Lawrence JD, Kawamura K, Incarvito C, Hartwig JF (2006) Rutheniumcatalyzed regiospecific borylation of methyl C–H bonds. J Am Chem Soc 128:13684–13685
64. Shimada S, Batsanov AS, Howard JAK, Marder TB (2001) Formation of Aryl- and Benzylboronate Esters by Rhodium-Catalyzed C − H Bond Functionalization with Pinacolborane.
Angew Chem Int Ed 40:2168–2171
65. Lam WH, Lam KC, Lin Z, Shimada S, Perutz RN, Marder TB (2004) Theoretical study
of reaction pathways for the rhodium phosphine-catalysed borylation of C–H bonds with
pinacolborane. Dalton Trans:1556–1562
66. Hartwig JF, Cook KS, Hapke M, Incarvito CD, Fan Y, Webster CE, Hall MB (2005) Rhodium
boryl complexes in the catalytic, terminal functionalization of alkanes. J Am Chem Soc
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67. Wei CS, Jimenez-Hoyos CA, Videa MF, Hartwig JF, Hall MB (2010) Origins of the selectivity
for borylation of primary over secondary C–H bonds catalyzed by Cp*-rhodium complexes.
J Am Chem Soc 132:3078–3091
68. Chang WTT, Smith RC, Regens CS, Bailey AD, Werner NS, Denmark SE, Denmark SE, Liu
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69. Denmark SE, Ambrosi A (2015) Why You Really Should Consider Using PalladiumCatalyzed Cross-Coupling of Silanols and Silanolates. Org Process Res Dev 19:982–994
70. Furuta S, Mori T, Yoshigoe Y, Sekine K, Kuninobu Y (2020) Synthesis, structures and photophysical properties of hexacoordinated organosilicon compounds with 2-(2-pyridyl)phenyl
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121
48. Qian G, Hong X, Liu B, Mao H, Xu B (2014) Rhodium-catalyzed regioselective C–H
chlorination of 7-azaindoles using 1,2-dichloroethane. Org Lett 16:5294–5297
49. Zhang P, Hong L, Li G, Wang R (2015) Sodium halides as halogenating reagents: rhodium(III)catalyzed versatile and practical halogenation of aryl compounds. Adv Synth Catal 357:345–
349
50. Zhang T, Qi X, Liu S, Bai R, Liu C, Lan Y (2017) Computational investigation of the role
played by rhodium(V) in the rhodium(III)-Catalyzed ortho-Bromination of Arenes. Chemistry
23:2690–2699
51. Matteson DS (1989) Boronic esters in stereodirected synthesis. Tetrahedron Lett 45:1859–
1885
52. Suzuki A (1994) New synthetic transformations via organoboron compounds. Pure Appl
Chem 66:213–222
53. Suzuki A (1991) Synthetic studies via the cross-coupling reaction of organoboron derivatives
with organic halides. Pure Appl Chem 63:419–422
54. Chen H, Hartwig JF (1999) Catalytic, regiospecific end-functionalization of alkanes: rheniumcatalyzed borylation under photochemical conditions. Angew Chem Int Ed 38:3391–3393
55. Kleeberg C, Dang L, Lin Z, Marder TB (2009) A facile route to aryl boronates: roomtemperature, copper-catalyzed borylation of aryl halides with alkoxy diboron reagents. Angew
Chem Int Ed 48:5350–5354
56. Zhu W, Ma D (2006) Formation of arylboronates by a CuI-catalyzed coupling reaction of
pinacolborane with aryl iodides at room temperature. Org Lett 8:261–263
57. Billingsley KL, Buchwald SL (2008) An improved system for the palladium-catalyzed
borylation of aryl halides with pinacol borane. J Org Chem 73:5589–5591
58. Liskey CW, Hartwig JF (2013) Iridium-catalyzed C–H borylation of cyclopropanes. J Am
Chem Soc 135:3375–3378
59. Molander GA, Cavalcanti LN, Garcia-Garcia C (2013) Nickel-catalyzed borylation of halides
and pseudohalides with tetrahydroxydiboron [B2(OH)4]. J Org Chem 78:6427–6439
60. Chen H, Schlecht S, Semple TC, Hartwig JF (2000) Thermal, catalytic, regiospecific
functionalization of alkanes. Science 287:1995–1997
61. Mkhalid IA, Barnard JH, Marder TB, Murphy JM, Hartwig JF (2010) C–H activation for the
construction of C–B bonds. Chem Rev 110:890–931
62. Tobisu M, Kinuta H, Kita Y, Remond E, Chatani N (2012) Rhodium(I)-catalyzed borylation
of nitriles through the cleavage of carbon-cyano bonds. J Am Chem Soc 134:115–118
63. Murphy JM, Lawrence JD, Kawamura K, Incarvito C, Hartwig JF (2006) Rutheniumcatalyzed regiospecific borylation of methyl C–H bonds. J Am Chem Soc 128:13684–13685
64. Shimada S, Batsanov AS, Howard JAK, Marder TB (2001) Formation of Aryl- and Benzylboronate Esters by Rhodium-Catalyzed C − H Bond Functionalization with Pinacolborane.
Angew Chem Int Ed 40:2168–2171
65. Lam WH, Lam KC, Lin Z, Shimada S, Perutz RN, Marder TB (2004) Theoretical study
of reaction pathways for the rhodium phosphine-catalysed borylation of C–H bonds with
pinacolborane. Dalton Trans:1556–1562
66. Hartwig JF, Cook KS, Hapke M, Incarvito CD, Fan Y, Webster CE, Hall MB (2005) Rhodium
boryl complexes in the catalytic, terminal functionalization of alkanes. J Am Chem Soc
127:2538–2552
67. Wei CS, Jimenez-Hoyos CA, Videa MF, Hartwig JF, Hall MB (2010) Origins of the selectivity
for borylation of primary over secondary C–H bonds catalyzed by Cp*-rhodium complexes.
J Am Chem Soc 132:3078–3091
68. Chang WTT, Smith RC, Regens CS, Bailey AD, Werner NS, Denmark SE, Denmark SE, Liu
JHC (2011) Cross-coupling with organosilicon compounds silicon-based coupling reactions
in the total synthesis of natural products. Organ React 49:213–746
69. Denmark SE, Ambrosi A (2015) Why You Really Should Consider Using PalladiumCatalyzed Cross-Coupling of Silanols and Silanolates. Org Process Res Dev 19:982–994
70. Furuta S, Mori T, Yoshigoe Y, Sekine K, Kuninobu Y (2020) Synthesis, structures and photophysical properties of hexacoordinated organosilicon compounds with 2-(2-pyridyl)phenyl
groups. Org Biomol Chem 18:3239–3242