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4. Gensch T, Hopkinson MN, Glorius F, Wencel-Delord J (2016) Mild metal-catalyzed C–H
activation: examples and concepts. Chem Soc Rev 45:2900–2936
5. Lin C, Gao F, Shen L (2019) Advances in transition metal-catalyzed selective functionalization
of inert C–O bonds assisted by directing groups. Adv Synth Catal 361:3915–3924
6. Liu CX, Gu Q, You S-L (2020) Asymmetric C–H bond functionalization of ferrocenes: new
opportunities and challenges. Trends Chem 2:737–749
7. Lyons TW, Sanford MS (2010) Palladium-catalyzed ligand-directed C–H functionalization
reactions. Chem Rev 110:1147–1169
8. Park Y, Kim Y, Chang S (2017) Transition metal-catalyzed C–H amination: scope, mechanism,
and applications. Chem Rev 117:9247–9301
9. Song G, Li X (2015) Substrate activation strategies in rhodium(III)-catalyzed selective
functionalization of arenes. Acc Chem Res 48:1007–1020
10. Song G, Wang F, Li X (2012) C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed
oxidative C–H activation. Chem Soc Rev 41:3651–3678
11. Sperger T, Sanhueza IA, Kalvet I, Schoenebeck F (2015) Computational studies of synthetically relevant homogeneous organometallic catalysis involving Ni, Pd, Ir, and Rh: an overview
of commonly employed DFT methods and mechanistic insights. Chem Rev 115:9532–9586
12. Tauchert ME, Incarvito CD, Rheingold AL, Bergman RG, Ellman JA (2012) Mechanism of
the rhodium(III)-catalyzed arylation of imines via C–H bond functionalization: inhibition by
substrate. J Am Chem Soc 134:1482–1485
13. Tsai AS, Tauchert ME, Bergman RG, Ellman JA (2011) Rhodium(III)-catalyzed arylation of
Boc-imines via C–H bond functionalization. J Am Chem Soc 133:1248–1250
14. Wang K, Hu F, Zhang Y, Wang J (2015) Directing group-assisted transition-metal-catalyzed
vinylic C–H bond functionalization. Sci China Chem 58:1252–1265
15. Jin C, Wang G, Yang X, Zhu W, Yang Y (2018) Experimental and theoretical studies on
rhodium-catalyzed direct CH benzoxylation reaction. Tetrahedron Lett 59:2042–2045
16. Hartwig JF (1998) Transition metal catalyzed synthesis of arylamines and aryl ethers from
aryl halides and triflates: scope and mechanism. Angew Chem Int Ed 37:2046–2067
17. Hartwig JF (2008) Evolution of a fourth generation catalyst for the amination and thioetherification of aryl halides. Acc Chem Res 41:1534–1544
18. Surry DS, Buchwald SL (2008) Biaryl phosphane ligands in palladium-catalyzed amination.
Angew Chem Int Ed 47:6338–6361
19. Figg TM, Park S, Park J, Chang S, Musaev DG (2014) Comparative investigations of
Cp*-based group 9 metal-catalyzed direct C–H amination of benzamides. Organometallics
33:4076–4085
20. Ng K-H, Zhou Z, Yu W-Y (2012) Rhodium(III)-catalyzed intermolecular direct amination of
aromatic C–H bonds with N-chloroamines. Org Lett 14:272–275
21. Ryu J, Shin K, Park SH, Kim JY, Chang S (2012) Rhodium-catalyzed direct C–H amination of
benzamides with aryl azides: a synthetic route to diarylamines. Angew Chem Int Ed 51:9904–
9908
22. Zhou B, Du J, Yang Y, Li Y (2013) Rhodium(III)-catalyzed intermolecular direct amidation
of aldehyde C–H bonds with N-chloroamines at room temperature. Org Lett 15:2934–2937
23. Wang F, Yu S, Li X (2016) Transition metal-catalysed couplings between arenes and strained or
reactive rings: combination of C–H activation and ring scission. Chem Soc Rev 45:6462–6477
24. Shin K, Kim H, Chang S (2015) Transition-metal-catalyzed C–N bond forming reactions using
organic azides as the nitrogen source: a journey for the mild and versatile C–H amination.
Acc Chem Res 48:1040–1052
25. Park J, Chang S (2015) Comparative catalytic activity of group 9 [Cp*M(III)] complexes:
cobalt-catalyzed C–H amidation of arenes with dioxazolones as amidating reagents. Angew
Chem Int Ed 54:14103–14107
26. Park Y, Park KT, Kim JG, Chang S (2015) Mechanistic studies on the Rh(III)-mediated amido
transfer process leading to robust C–H amination with a new type of amidating reagent. J Am
Chem Soc 137:4534–4542
119
4. Gensch T, Hopkinson MN, Glorius F, Wencel-Delord J (2016) Mild metal-catalyzed C–H
activation: examples and concepts. Chem Soc Rev 45:2900–2936
5. Lin C, Gao F, Shen L (2019) Advances in transition metal-catalyzed selective functionalization
of inert C–O bonds assisted by directing groups. Adv Synth Catal 361:3915–3924
6. Liu CX, Gu Q, You S-L (2020) Asymmetric C–H bond functionalization of ferrocenes: new
opportunities and challenges. Trends Chem 2:737–749
7. Lyons TW, Sanford MS (2010) Palladium-catalyzed ligand-directed C–H functionalization
reactions. Chem Rev 110:1147–1169
8. Park Y, Kim Y, Chang S (2017) Transition metal-catalyzed C–H amination: scope, mechanism,
and applications. Chem Rev 117:9247–9301
9. Song G, Li X (2015) Substrate activation strategies in rhodium(III)-catalyzed selective
functionalization of arenes. Acc Chem Res 48:1007–1020
10. Song G, Wang F, Li X (2012) C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed
oxidative C–H activation. Chem Soc Rev 41:3651–3678
11. Sperger T, Sanhueza IA, Kalvet I, Schoenebeck F (2015) Computational studies of synthetically relevant homogeneous organometallic catalysis involving Ni, Pd, Ir, and Rh: an overview
of commonly employed DFT methods and mechanistic insights. Chem Rev 115:9532–9586
12. Tauchert ME, Incarvito CD, Rheingold AL, Bergman RG, Ellman JA (2012) Mechanism of
the rhodium(III)-catalyzed arylation of imines via C–H bond functionalization: inhibition by
substrate. J Am Chem Soc 134:1482–1485
13. Tsai AS, Tauchert ME, Bergman RG, Ellman JA (2011) Rhodium(III)-catalyzed arylation of
Boc-imines via C–H bond functionalization. J Am Chem Soc 133:1248–1250
14. Wang K, Hu F, Zhang Y, Wang J (2015) Directing group-assisted transition-metal-catalyzed
vinylic C–H bond functionalization. Sci China Chem 58:1252–1265
15. Jin C, Wang G, Yang X, Zhu W, Yang Y (2018) Experimental and theoretical studies on
rhodium-catalyzed direct CH benzoxylation reaction. Tetrahedron Lett 59:2042–2045
16. Hartwig JF (1998) Transition metal catalyzed synthesis of arylamines and aryl ethers from
aryl halides and triflates: scope and mechanism. Angew Chem Int Ed 37:2046–2067
17. Hartwig JF (2008) Evolution of a fourth generation catalyst for the amination and thioetherification of aryl halides. Acc Chem Res 41:1534–1544
18. Surry DS, Buchwald SL (2008) Biaryl phosphane ligands in palladium-catalyzed amination.
Angew Chem Int Ed 47:6338–6361
19. Figg TM, Park S, Park J, Chang S, Musaev DG (2014) Comparative investigations of
Cp*-based group 9 metal-catalyzed direct C–H amination of benzamides. Organometallics
33:4076–4085
20. Ng K-H, Zhou Z, Yu W-Y (2012) Rhodium(III)-catalyzed intermolecular direct amination of
aromatic C–H bonds with N-chloroamines. Org Lett 14:272–275
21. Ryu J, Shin K, Park SH, Kim JY, Chang S (2012) Rhodium-catalyzed direct C–H amination of
benzamides with aryl azides: a synthetic route to diarylamines. Angew Chem Int Ed 51:9904–
9908
22. Zhou B, Du J, Yang Y, Li Y (2013) Rhodium(III)-catalyzed intermolecular direct amidation
of aldehyde C–H bonds with N-chloroamines at room temperature. Org Lett 15:2934–2937
23. Wang F, Yu S, Li X (2016) Transition metal-catalysed couplings between arenes and strained or
reactive rings: combination of C–H activation and ring scission. Chem Soc Rev 45:6462–6477
24. Shin K, Kim H, Chang S (2015) Transition-metal-catalyzed C–N bond forming reactions using
organic azides as the nitrogen source: a journey for the mild and versatile C–H amination.
Acc Chem Res 48:1040–1052
25. Park J, Chang S (2015) Comparative catalytic activity of group 9 [Cp*M(III)] complexes:
cobalt-catalyzed C–H amidation of arenes with dioxazolones as amidating reagents. Angew
Chem Int Ed 54:14103–14107
26. Park Y, Park KT, Kim JG, Chang S (2015) Mechanistic studies on the Rh(III)-mediated amido
transfer process leading to robust C–H amination with a new type of amidating reagent. J Am
Chem Soc 137:4534–4542