Index
403
222, 237, 239–241, 245–250, 252–
259, 262, 263, 268, 270, 272–274,
283–285, 322, 323, 335, 336, 339,
347, 362–364, 366–368, 370, 373,
374, 376–382, 390, 392, 393
Lewis acidity, 4, 8, 10, 13, 45, 135, 147,
156, 171, 174, 178, 183–187, 211,
212, 214, 216–219, 221, 222, 224–
227, 229, 259, 285, 289, 300, 312,
330, 390
Lewis base, 32, 45, 47, 62, 69, 87, 98, 100,
101, 113, 116, 118, 119, 122, 124–
126, 131, 134, 135, 141, 148, 160,
167, 169, 170, 174, 178, 179, 184–
186, 188, 189, 191, 193, 196, 198,
202, 210, 216, 219, 220, 222, 223,
225, 237, 239–248, 250, 252, 253,
256, 259, 260, 262, 268, 270, 271,
273, 283–285, 330, 333, 337, 338,
362–364, 366, 374, 377, 378, 380,
382, 392
M
Macrocyclic oligomers, 87, 96
Metadynamics, 167, 179, 190, 192–194,
199, 202
Metal-ligand cooperation, 321
Metal-metal bond
Metal organic framework (MOF), 2, 11, 167,
170, 196–200, 202, 254, 256–259,
273
Metal oxide, 237, 240, 250, 262–264, 268,
273
Molecular dynamics simulations, 188, 190
Molecular sieve, 7, 225, 238, 244
Monomer, 17, 18, 245, 250, 251, 283, 285,
287–300, 302, 304, 305, 307, 308,
310–312
Mulliken theory, 378
N
Nanoparticle, 238, 248, 260, 271, 272, 321
N-heterocyclic carbene, 2, 9, 10, 17, 35, 335,
338, 361, 377
O
Olefin, 2, 3, 6–8, 10, 12, 15, 32, 35, 100,
218, 227–229, 238, 245, 246, 284,
287, 326, 380
P
Pedagogy, 383
Phosphine, 2, 3, 8, 10, 15, 17, 18, 57,
122, 158, 174, 177, 185, 188, 190,
193, 217, 227, 240, 242, 243, 248,
252, 259, 287, 288, 295, 320, 322,
323, 328, 329, 335–337, 339–341,
362–365, 375–377, 379
Photochemistry
Photoinduced, 374, 378, 380, 381
Polar vinyl monomer, 283, 285–288, 296,
297, 312
Polymerization, 1, 17, 100, 152, 216, 245,
283, 285–309, 311, 312, 337, 338,
365
Polyoxometalate cluster, 237, 250, 261, 273
Q
Quinone, 372
R
Radical, 17, 90, 91, 95, 104, 158–160, 250,
251, 270, 326, 361–368, 370–372,
375–378, 380–382
Radical anion, 158, 367, 368, 372, 374, 377,
380–382
Radical cation, 363–365, 374, 376, 377
Radical ion pair, 363–365, 374, 377–380,
382
Rare-earth element, 319, 323, 336, 337
Ring-opening polymerization, 283, 302
S
Semi-immobilised, 237, 241, 243, 247, 249,
250, 273
Silica, 3, 237, 241, 245, 246, 248–250, 259,
260, 273
Silylation, 131–136, 330
Single-electron Transfer (SET), 158, 361–
364, 366–368, 370, 372–382
Solid state, 102, 148, 149, 174, 186, 242, 252
Surface, 10, 18, 175, 192, 193, 199, 202, 240,
245–250, 253, 254, 256, 258, 259,
262–264, 266–273, 293
T
Thermodynamic, 35, 57, 120, 122, 130, 140,
154, 155, 173, 178, 180, 184, 186,
196, 197, 211, 227, 248, 267, 295,
322, 365, 375, 379, 387, 389–397
403
222, 237, 239–241, 245–250, 252–
259, 262, 263, 268, 270, 272–274,
283–285, 322, 323, 335, 336, 339,
347, 362–364, 366–368, 370, 373,
374, 376–382, 390, 392, 393
Lewis acidity, 4, 8, 10, 13, 45, 135, 147,
156, 171, 174, 178, 183–187, 211,
212, 214, 216–219, 221, 222, 224–
227, 229, 259, 285, 289, 300, 312,
330, 390
Lewis base, 32, 45, 47, 62, 69, 87, 98, 100,
101, 113, 116, 118, 119, 122, 124–
126, 131, 134, 135, 141, 148, 160,
167, 169, 170, 174, 178, 179, 184–
186, 188, 189, 191, 193, 196, 198,
202, 210, 216, 219, 220, 222, 223,
225, 237, 239–248, 250, 252, 253,
256, 259, 260, 262, 268, 270, 271,
273, 283–285, 330, 333, 337, 338,
362–364, 366, 374, 377, 378, 380,
382, 392
M
Macrocyclic oligomers, 87, 96
Metadynamics, 167, 179, 190, 192–194,
199, 202
Metal-ligand cooperation, 321
Metal-metal bond
Metal organic framework (MOF), 2, 11, 167,
170, 196–200, 202, 254, 256–259,
273
Metal oxide, 237, 240, 250, 262–264, 268,
273
Molecular dynamics simulations, 188, 190
Molecular sieve, 7, 225, 238, 244
Monomer, 17, 18, 245, 250, 251, 283, 285,
287–300, 302, 304, 305, 307, 308,
310–312
Mulliken theory, 378
N
Nanoparticle, 238, 248, 260, 271, 272, 321
N-heterocyclic carbene, 2, 9, 10, 17, 35, 335,
338, 361, 377
O
Olefin, 2, 3, 6–8, 10, 12, 15, 32, 35, 100,
218, 227–229, 238, 245, 246, 284,
287, 326, 380
P
Pedagogy, 383
Phosphine, 2, 3, 8, 10, 15, 17, 18, 57,
122, 158, 174, 177, 185, 188, 190,
193, 217, 227, 240, 242, 243, 248,
252, 259, 287, 288, 295, 320, 322,
323, 328, 329, 335–337, 339–341,
362–365, 375–377, 379
Photochemistry
Photoinduced, 374, 378, 380, 381
Polar vinyl monomer, 283, 285–288, 296,
297, 312
Polymerization, 1, 17, 100, 152, 216, 245,
283, 285–309, 311, 312, 337, 338,
365
Polyoxometalate cluster, 237, 250, 261, 273
Q
Quinone, 372
R
Radical, 17, 90, 91, 95, 104, 158–160, 250,
251, 270, 326, 361–368, 370–372,
375–378, 380–382
Radical anion, 158, 367, 368, 372, 374, 377,
380–382
Radical cation, 363–365, 374, 376, 377
Radical ion pair, 363–365, 374, 377–380,
382
Rare-earth element, 319, 323, 336, 337
Ring-opening polymerization, 283, 302
S
Semi-immobilised, 237, 241, 243, 247, 249,
250, 273
Silica, 3, 237, 241, 245, 246, 248–250, 259,
260, 273
Silylation, 131–136, 330
Single-electron Transfer (SET), 158, 361–
364, 366–368, 370, 372–382
Solid state, 102, 148, 149, 174, 186, 242, 252
Surface, 10, 18, 175, 192, 193, 199, 202, 240,
245–250, 253, 254, 256, 258, 259,
262–264, 266–273, 293
T
Thermodynamic, 35, 57, 120, 122, 130, 140,
154, 155, 173, 178, 180, 184, 186,
196, 197, 211, 227, 248, 267, 295,
322, 365, 375, 379, 387, 389–397