402
Index
167, 170–175, 180, 190, 192, 193,
197, 199, 202, 225, 254, 264, 266,
267, 272
d 0 -Metallocene cations, 100
Donor-acceptor complex, 361
E
Electrophilic addition, 113, 116, 119, 124–
126, 133, 144
Encounter complex, 176, 177, 193, 195, 201,
202, 346, 379, 388
Epoxide, 143, 222, 267, 283, 287, 288, 302,
305, 307–309, 311, 312, 336
Ether, 7, 174, 175, 188, 189, 209, 220, 224,
283, 284, 305, 307–310
F
Frustrated Lewis pair (FLP), 1–20, 29, 31–
33, 35, 37, 38, 45, 47, 57, 61, 62, 68,
69, 72, 73, 75, 81, 83, 87–95, 98–105,
113, 114, 116, 118, 119, 123, 129,
132, 134–138, 140, 141, 144–146,
148, 150, 152, 154, 156, 158–160,
167, 169–172, 174–180, 184, 186–
194, 196, 199–202, 209–212, 216–
221, 224, 226–229, 237–255, 257–
274, 283–292, 294, 299–301, 312,
319–332, 334–344, 346–348, 361–
367, 372, 374–376, 378–382, 387–
397
Functional-group tolerance, 7, 19, 45
G
Gold, 10, 245, 247–249, 272, 321, 322, 335,
340, 341
Graft, 241, 242, 245, 246, 256, 259, 260
Graphene, 123, 237, 250, 262, 268–270, 272,
273
H
Heterobimetallic, 319, 323, 339–345
Heterogeneous catalysis, 2, 240, 245, 248,
250, 252–254, 273, 388
Heteroleptic, 214–216, 218
Heterolytic cleavage, 2, 239, 247, 254, 260,
266, 272, 329, 362, 375, 376
Hexagonal boron nitride, 237, 238, 272
Homogeneous catalysis, 273
Homoleptic, 212, 217, 338
Homolytic cleavage, 362, 370, 375
Hydroarylation, 1, 15, 16
Hydroboration, 1, 6, 14, 18, 31, 32, 35, 40,
43, 45, 57, 91, 96, 98, 126, 150, 152,
156, 226–229, 242, 257, 334
Hydrogenation, 1, 6, 3–11, 15, 19, 29, 31,
33, 35, 38–40, 42–46, 48–50, 52, 54,
75, 81, 118, 132, 139, 168, 172, 175,
176, 178, 184–191, 196–202, 216–
225, 228, 229, 239–244, 248, 254,
255, 257, 258, 265, 266, 268–272,
320–322, 326–328, 333, 338, 348,
362, 388
Hydrosilylation, 1, 12, 18, 29, 31, 57, 59, 61,
62, 64, 66–68, 81, 131, 228, 333, 336
I
Imine, 3–5, 8, 10, 11, 31–33, 35, 40, 89, 93,
174, 178, 179, 198, 221, 239, 248,
253, 257, 329, 332
Immobilised, 249, 250, 273
Interacting Lewis pair, 283, 285, 286
Intermolecular, 9, 31, 35, 47, 98, 100, 103,
104, 123, 137, 171, 172, 174, 175,
177, 178, 188, 201, 211, 239, 240,
295, 326, 328, 331, 337, 338
Intramolecular, 2, 6, 8, 9, 15, 16, 31, 87, 91,
98, 101, 104, 120, 124–126, 132, 137,
141, 142, 167, 171, 172, 174, 177,
178, 193, 194, 199, 201, 211, 220,
226–228, 239, 240, 250, 251, 254,
255, 295, 297, 321, 323, 326, 327,
329, 332, 334, 335, 337
K
Ketone, 3, 5, 7, 8, 12, 15, 45, 47, 50, 59, 61,
62, 64, 67, 69, 78, 152, 169, 174, 175,
178, 186–188, 192, 202, 216, 218,
220, 244, 245, 266, 272, 327, 331,
333, 334, 336, 362
Kinetic, 8, 18, 118–120, 122, 123, 147, 148,
154, 155, 177, 178, 184, 194, 196,
227, 248, 295, 296, 329, 340, 344
L
Lewis acid, 4, 6–8, 10, 12, 13, 15, 16, 18,
31, 35, 47, 50, 68, 69, 75, 78, 80,
81, 87, 89, 92, 97, 98, 100–102, 105,
113, 116, 118–120, 123, 124, 130,
132, 134, 135, 138, 148, 160, 167,
169–176, 178–181, 186–188, 191,
193, 194, 196, 201, 210, 211, 218,
Index
167, 170–175, 180, 190, 192, 193,
197, 199, 202, 225, 254, 264, 266,
267, 272
d 0 -Metallocene cations, 100
Donor-acceptor complex, 361
E
Electrophilic addition, 113, 116, 119, 124–
126, 133, 144
Encounter complex, 176, 177, 193, 195, 201,
202, 346, 379, 388
Epoxide, 143, 222, 267, 283, 287, 288, 302,
305, 307–309, 311, 312, 336
Ether, 7, 174, 175, 188, 189, 209, 220, 224,
283, 284, 305, 307–310
F
Frustrated Lewis pair (FLP), 1–20, 29, 31–
33, 35, 37, 38, 45, 47, 57, 61, 62, 68,
69, 72, 73, 75, 81, 83, 87–95, 98–105,
113, 114, 116, 118, 119, 123, 129,
132, 134–138, 140, 141, 144–146,
148, 150, 152, 154, 156, 158–160,
167, 169–172, 174–180, 184, 186–
194, 196, 199–202, 209–212, 216–
221, 224, 226–229, 237–255, 257–
274, 283–292, 294, 299–301, 312,
319–332, 334–344, 346–348, 361–
367, 372, 374–376, 378–382, 387–
397
Functional-group tolerance, 7, 19, 45
G
Gold, 10, 245, 247–249, 272, 321, 322, 335,
340, 341
Graft, 241, 242, 245, 246, 256, 259, 260
Graphene, 123, 237, 250, 262, 268–270, 272,
273
H
Heterobimetallic, 319, 323, 339–345
Heterogeneous catalysis, 2, 240, 245, 248,
250, 252–254, 273, 388
Heteroleptic, 214–216, 218
Heterolytic cleavage, 2, 239, 247, 254, 260,
266, 272, 329, 362, 375, 376
Hexagonal boron nitride, 237, 238, 272
Homogeneous catalysis, 273
Homoleptic, 212, 217, 338
Homolytic cleavage, 362, 370, 375
Hydroarylation, 1, 15, 16
Hydroboration, 1, 6, 14, 18, 31, 32, 35, 40,
43, 45, 57, 91, 96, 98, 126, 150, 152,
156, 226–229, 242, 257, 334
Hydrogenation, 1, 6, 3–11, 15, 19, 29, 31,
33, 35, 38–40, 42–46, 48–50, 52, 54,
75, 81, 118, 132, 139, 168, 172, 175,
176, 178, 184–191, 196–202, 216–
225, 228, 229, 239–244, 248, 254,
255, 257, 258, 265, 266, 268–272,
320–322, 326–328, 333, 338, 348,
362, 388
Hydrosilylation, 1, 12, 18, 29, 31, 57, 59, 61,
62, 64, 66–68, 81, 131, 228, 333, 336
I
Imine, 3–5, 8, 10, 11, 31–33, 35, 40, 89, 93,
174, 178, 179, 198, 221, 239, 248,
253, 257, 329, 332
Immobilised, 249, 250, 273
Interacting Lewis pair, 283, 285, 286
Intermolecular, 9, 31, 35, 47, 98, 100, 103,
104, 123, 137, 171, 172, 174, 175,
177, 178, 188, 201, 211, 239, 240,
295, 326, 328, 331, 337, 338
Intramolecular, 2, 6, 8, 9, 15, 16, 31, 87, 91,
98, 101, 104, 120, 124–126, 132, 137,
141, 142, 167, 171, 172, 174, 177,
178, 193, 194, 199, 201, 211, 220,
226–228, 239, 240, 250, 251, 254,
255, 295, 297, 321, 323, 326, 327,
329, 332, 334, 335, 337
K
Ketone, 3, 5, 7, 8, 12, 15, 45, 47, 50, 59, 61,
62, 64, 67, 69, 78, 152, 169, 174, 175,
178, 186–188, 192, 202, 216, 218,
220, 244, 245, 266, 272, 327, 331,
333, 334, 336, 362
Kinetic, 8, 18, 118–120, 122, 123, 147, 148,
154, 155, 177, 178, 184, 194, 196,
227, 248, 295, 296, 329, 340, 344
L
Lewis acid, 4, 6–8, 10, 12, 13, 15, 16, 18,
31, 35, 47, 50, 68, 69, 75, 78, 80,
81, 87, 89, 92, 97, 98, 100–102, 105,
113, 116, 118–120, 123, 124, 130,
132, 134, 135, 138, 148, 160, 167,
169–176, 178–181, 186–188, 191,
193, 194, 196, 201, 210, 211, 218,