9 Frustrated Lewis Pairs Based on Transition Metals
357
156. Hanna TA, Baranger AM, Bergman RG (1995) Reaction of Carbon Dioxide and Heterocumulenes with an Unsymmetrical Metal-Metal bond. Direct Addition of Carbon Dioxide Across
a Zirconium-Iridium Bond and Stoichiometric Reduction of Carbon Dioxide to Formate. J
Am Chem Soc 117:11363–11364. https://doi.org/10.1021/ja00150a044
157. Baranger AM, Bergman RG (1994) Cooperative Reactivity in the Interactions of X-H bonds
with a Zirconium-Iridium Bridging Imido Complex. J Am Chem Soc 116:3822–3835. https://
doi.org/10.1021/ja00088a019
158. Memmler H, Kauper U, Gade LH, Scowen IJ, McPartlin M (1996) Insertion of X=C=Y
Heteroallenes into Unsupported Zr–M Bonds (M = Fe, Ru). Chem Commun 1751–1752.
https://doi.org/10.1039/CC9960001751
159. Schneider A, Gade LH, Breuning M, Bringmann G, Scowen IJ, McPartlin M (1998) Cooperative Reactivity of Unsupported Early−Late Heterobimetallics: Ring Opening and Subsequent
Decarbonylation of Biaryllactones. Organometallics 17:1643–1645. https://doi.org/10.1021/
om980007d
160. Gade LH, Memmler H, Kauper U, Schneider A, Fabre S, Bezougli I, Lutz M, Galka C, Scowen
IJ, McPartlin M (2000) Cooperative Reactivity of Early-Late Heterodinuclear Transition Metal
Complexes with Polar Organic Substrates. Chem Eur J 6:692–708. https://doi.org/10.1002/
(SICI)1521-3765(20000218)6:4%3c692::AID-CHEM692%3e3.0.CO;2-2
161. Findeis B, Schubart M, Platzek C, Gade LH, Scowen I, McPartlin M (1996) A ‘Passe-Partout’
for the Stabilization of Highly Polar Unsupported M–M Bonds (M = Ti, Zr, Hf; M = Fe, Ru)
and α-Addition of the Metal Nucleophile–Electrophile Pairs to an Isocyanide. Chem Commun
219–220. https://doi.org/10.1039/CC9960000219
162. Pinkes JR, Tetrick SM, Landrum BE, Cutler AR (1998) Characterization of the μ-(η 1 -C:
η 2 -S, S )Dithiocarboxylate Complexes Cp(CO) 2 Fe–CS 2 –Zr(X)Cp 2 (X=Cl, OCMe 3 ); CS 2
Insertion into the FeZr Bond of the Heterobimetallic Complex Cp(CO) 2 Fe–Zr(OCMe 3 )Cp 2 .
J Organomet Chem 556:1–7. https://doi.org/10.1016/S0022-328X(98)00752-9
163. Sisak A, Halmos E (2007) Reactions of Early–Late Heterobimetallics with Oxiranes: New
Examples for Cooperative Reactivity. J Organomet Chem 92:1817–1824. https://doi.org/10.
1016/j.jorganchem.2006.10.009
164. Uehara K, Hikichi S, Inagaki A, Akita M (2005) Xenophilic Complexes Bearing a Tp R
Ligand, [Tp R M–M’L n ] [Tp R =Tp iPr2 , T p # (T pMe2,4-B r); M=Ni Co, Fe, Mn; M’L n =Co(CO) 4 ,
Co(CO) 3 (PPh 3 ), RuCp(CO) 2 ]: The Two Metal Centers are Held Together not by Covalent
Interaction but by Electrostatic Attraction. Chem Eur J 11:2788–2809. https://doi.org/10.
1002/chem.200401016
165. Schmidt JAR, Lobkovsky EB, Coates GW (2005) Chromium(III) Octaethylporphyrinato
Tetracarbonylcobaltate: a Highly Active, Selective, and Versatile Catalyst for Epoxide
Carbonylation. J Am Chem Soc 127:11426–11435. https://doi.org/10.1021/ja051874u
166. Krogman JP, Foxman BM, Thomas CM (2011) Activation of CO 2 by a Heterobimetallic
Zr/Co Complex. J Am Chem Soc 133:14582–14585. https://doi.org/10.1021/ja2071847
167. Cooper BG, Fafard CM, Foxman BM, Thomas CM (2010) Electronic Factors Affecting
Metal−Metal Interactions in Early/Late Heterobimetallics: Substituent Effects in Zirconium/Platinum Bis(phosphinoamide) Complexes. Organometallics 29:5179–5186. https://
doi.org/10.1021/om100356a
168. Riddlestone IM, Rajabi NA, Lowe JP, Mahon MF, Macgregor SA, Whittlesey MK (2016)
Activation of H 2 over the Ru−Zn Bond in the Transition Metal−Lewis Acid Heterobimetallic
Species [Ru(IPr) 2 (CO)ZnEt] + . J Am Chem Soc 35:11081–11084. https://doi.org/10.1021/
jacs.6b05243
169. Jamali S, Abedanzadeh S, Khaledi NK, Samouei H, Hendi Z, Zacchini S, Kia R, Shahsavari
HR (2016) A Cooperative Pathway for Water Activation Using a Bimetallic Pt 0 –Cu I System.
Dalton Trans 45:17644–17651. https://doi.org/10.1039/c6dt03305a
357
156. Hanna TA, Baranger AM, Bergman RG (1995) Reaction of Carbon Dioxide and Heterocumulenes with an Unsymmetrical Metal-Metal bond. Direct Addition of Carbon Dioxide Across
a Zirconium-Iridium Bond and Stoichiometric Reduction of Carbon Dioxide to Formate. J
Am Chem Soc 117:11363–11364. https://doi.org/10.1021/ja00150a044
157. Baranger AM, Bergman RG (1994) Cooperative Reactivity in the Interactions of X-H bonds
with a Zirconium-Iridium Bridging Imido Complex. J Am Chem Soc 116:3822–3835. https://
doi.org/10.1021/ja00088a019
158. Memmler H, Kauper U, Gade LH, Scowen IJ, McPartlin M (1996) Insertion of X=C=Y
Heteroallenes into Unsupported Zr–M Bonds (M = Fe, Ru). Chem Commun 1751–1752.
https://doi.org/10.1039/CC9960001751
159. Schneider A, Gade LH, Breuning M, Bringmann G, Scowen IJ, McPartlin M (1998) Cooperative Reactivity of Unsupported Early−Late Heterobimetallics: Ring Opening and Subsequent
Decarbonylation of Biaryllactones. Organometallics 17:1643–1645. https://doi.org/10.1021/
om980007d
160. Gade LH, Memmler H, Kauper U, Schneider A, Fabre S, Bezougli I, Lutz M, Galka C, Scowen
IJ, McPartlin M (2000) Cooperative Reactivity of Early-Late Heterodinuclear Transition Metal
Complexes with Polar Organic Substrates. Chem Eur J 6:692–708. https://doi.org/10.1002/
(SICI)1521-3765(20000218)6:4%3c692::AID-CHEM692%3e3.0.CO;2-2
161. Findeis B, Schubart M, Platzek C, Gade LH, Scowen I, McPartlin M (1996) A ‘Passe-Partout’
for the Stabilization of Highly Polar Unsupported M–M Bonds (M = Ti, Zr, Hf; M = Fe, Ru)
and α-Addition of the Metal Nucleophile–Electrophile Pairs to an Isocyanide. Chem Commun
219–220. https://doi.org/10.1039/CC9960000219
162. Pinkes JR, Tetrick SM, Landrum BE, Cutler AR (1998) Characterization of the μ-(η 1 -C:
η 2 -S, S )Dithiocarboxylate Complexes Cp(CO) 2 Fe–CS 2 –Zr(X)Cp 2 (X=Cl, OCMe 3 ); CS 2
Insertion into the FeZr Bond of the Heterobimetallic Complex Cp(CO) 2 Fe–Zr(OCMe 3 )Cp 2 .
J Organomet Chem 556:1–7. https://doi.org/10.1016/S0022-328X(98)00752-9
163. Sisak A, Halmos E (2007) Reactions of Early–Late Heterobimetallics with Oxiranes: New
Examples for Cooperative Reactivity. J Organomet Chem 92:1817–1824. https://doi.org/10.
1016/j.jorganchem.2006.10.009
164. Uehara K, Hikichi S, Inagaki A, Akita M (2005) Xenophilic Complexes Bearing a Tp R
Ligand, [Tp R M–M’L n ] [Tp R =Tp iPr2 , T p # (T pMe2,4-B r); M=Ni Co, Fe, Mn; M’L n =Co(CO) 4 ,
Co(CO) 3 (PPh 3 ), RuCp(CO) 2 ]: The Two Metal Centers are Held Together not by Covalent
Interaction but by Electrostatic Attraction. Chem Eur J 11:2788–2809. https://doi.org/10.
1002/chem.200401016
165. Schmidt JAR, Lobkovsky EB, Coates GW (2005) Chromium(III) Octaethylporphyrinato
Tetracarbonylcobaltate: a Highly Active, Selective, and Versatile Catalyst for Epoxide
Carbonylation. J Am Chem Soc 127:11426–11435. https://doi.org/10.1021/ja051874u
166. Krogman JP, Foxman BM, Thomas CM (2011) Activation of CO 2 by a Heterobimetallic
Zr/Co Complex. J Am Chem Soc 133:14582–14585. https://doi.org/10.1021/ja2071847
167. Cooper BG, Fafard CM, Foxman BM, Thomas CM (2010) Electronic Factors Affecting
Metal−Metal Interactions in Early/Late Heterobimetallics: Substituent Effects in Zirconium/Platinum Bis(phosphinoamide) Complexes. Organometallics 29:5179–5186. https://
doi.org/10.1021/om100356a
168. Riddlestone IM, Rajabi NA, Lowe JP, Mahon MF, Macgregor SA, Whittlesey MK (2016)
Activation of H 2 over the Ru−Zn Bond in the Transition Metal−Lewis Acid Heterobimetallic
Species [Ru(IPr) 2 (CO)ZnEt] + . J Am Chem Soc 35:11081–11084. https://doi.org/10.1021/
jacs.6b05243
169. Jamali S, Abedanzadeh S, Khaledi NK, Samouei H, Hendi Z, Zacchini S, Kia R, Shahsavari
HR (2016) A Cooperative Pathway for Water Activation Using a Bimetallic Pt 0 –Cu I System.
Dalton Trans 45:17644–17651. https://doi.org/10.1039/c6dt03305a