356
N. Hidalgo et al.
137. Arnold PL, Marr IA, Zlatogorsky S, Bellabarbac R, Toozec RP (2014) Activation of Carbon
Dioxide and Carbon Disulphide by a Scandium N-Heterocyclic Carbene Complex. Dalton
Trans 43:34–37. https://doi.org/10.1039/c3dt52762j
138. Turner ZR, Bellabarba R, Tooze RP, Arnold PL (2010) Addition-Elimination Reactions Across
the M−C Bond of Metal N-Heterocyclic Carbenes. J Am Chem Soc 132:4050–4051. https://
doi.org/10.1021/ja910673q
139. Arnold PL, Turner ZR, Germeroth AI, Casely IJ, Nichol GS, Bellabarba R, Tooze RP
(2013) Carbon Monoxide and Carbon Dioxide Insertion Chemistry of f-Block N-Heterocyclic
Carbene Complexes. Dalton Trans 42:1333–1337. https://doi.org/10.1039/C2DT31698F
140. Arnold PL, Kerr RWF, Weetman C, Docherty SR, Rieb J, Cruickshank FL, Wang K, Jandl C,
McMullon MW, Pöthig A, Kühn FE, Smith AD (2018) Selective and Catalytic Carbon Dioxide
and Heteroallene Activation Mediated by Cerium N-Heterocyclic Carbene Complexes. Chem
Sci 9:8035–8045. https://doi.org/10.1039/C8SC03312A
141. Sun X, Su W, Shi K, Xie Z, Zhu C (2020) Triple Frustrated Lewis Pair-Type Reactivity on a
Single Rare Earth Metal Center. Chem Eur J Accepted Manuscript. https://doi.org/10.1002/
chem.201905629
142. Stephan DW (1989) Early-Late Heterobimetallics. Coord Chem Rev 95:41–107. https://doi.
org/10.1016/0010-8545(89)80002-5
143. Wheatley N, Kalck P (1999) Structure and Reactivity of Early−Late Heterobimetallic
Complexes. Chem Rev 99:3379–3420. https://doi.org/10.1021/cr980325m
144. Gade LH (2000) Highly Polar Metal-Metal Bonds in “Early-Late” Heterodimetallic
Complexes. Angew Chem Int Ed 39:2658–2678. https://doi.org/10.1002/1521-3773(200008
04)39:15%3c2658::AID-ANIE2658%3e3.0.CO;2-C
145. Cooper BG, Napoline JW, Thomas CM (2012) Catalytic Applications of Early/Late
Heterobimetallic Complexes. Catal Rev 54:1–40. https://doi.org/10.1080/01614940.2012.
619931
146. Herberhold M, Jin G-X (1994) Heterodimetallic Complexes with an Unbridged, Polar MetalMetal Bond. Angew Chem Int Ed 33:964–966. https://doi.org/10.1002/anie.199409641
147. Chapman AM, Flynn SR, Wass DF (2016) Unexpected Formation of Early Late Heterobimetallic Complexes from Transition Metal Frustrated Lewis Pairs. Inorg Chem 55:1017–
1021. https://doi.org/10.1021/acs.inorgchem.5b01424
148. Campos C (2017) Dihydrogen and Acetylene Activation by a Gold(I)/Platinum(0) Transition
Metal Only Frustrated Lewis Pair. J Am Chem Soc 139:2944–2947. https://doi.org/10.1021/
jacs.7b00491
149. Bauer J, Braunschweig H, Dewhurst RD (2012) Metal-Only Lewis Pairs with Transition Metal
Lewis Bases. Chem Rev 112:4329–4346. https://doi.org/10.1021/cr3000048
150. Hidalgo N, Moreno JJ, Pérez-Jiménez M, Maya C, López-Serrano J, Campos J (2020a)
Evidence for Genuine Bimetallic Frustrated Lewis Pair Activation of Dihydrogen with
Gold(I)/Platinum(0) Systems. Chem Eur J 26:5982–5993
151. Dang LX, Schenter GK, Chang T-M, Kathmann SM, Autrey T (2012) Role of Solvents on
the Thermodynamics and Kinetics of Forming Frustrated Lewis Pairs. J Phys Chem Lett
3:3312–3319. https://doi.org/10.1021/jz301533a
152. Hidalgo N, Bajo S, Moreno JJ, Navarro-Gilabert C, Mercado BQ, Campos J (2019) Reactivity
of a Gold(I)/Platinum(0) Frustrated Lewis Pair with Germanium and Tin Dihalides. Dalton
Trans 48:9127–9138. https://doi.org/10.1039/c9dt00702d
153. Hidalgo N, Moreno JJ, Pérez-Jiménez M, Maya C, López-Serrano J, Campos J (2020) Tuning
Activity and Selectivity During Alkyne Activation by Gold(I)/Platinum(0) Frustrated Lewis
Pairs. Organometallics 39:2534–2544. https://doi.org/10.1021/acs.organomet.0c00330
154. Dureen MA, Stephan DW (2009) Terminal Alkyne Activation by Frustrated and cC Classical
Lewis Acid/Phosphine Pairs. J Am Chem Soc 131:8396–8397. https://doi.org/10.1021/ja9
03650w
155. Pinkes JR, Steffey BD, Vites JC, Cutler AR (1994) Carbon Dioxide Insertion into the Fe-Zr and
Ru-Zr Bonds of the Heterobimetallic Complexes Cp(CO) 2 M-Zr(Cl)Cp 2 : Direct Production
of the μ-η 1 (C):η 2 (O, O’)-CO 2 Compounds Cp(CO) 2 M-CO 2 -Zr(Cl)Cp 2 . Organometallics
13:21–23. https://doi.org/10.1021/om00013a009
N. Hidalgo et al.
137. Arnold PL, Marr IA, Zlatogorsky S, Bellabarbac R, Toozec RP (2014) Activation of Carbon
Dioxide and Carbon Disulphide by a Scandium N-Heterocyclic Carbene Complex. Dalton
Trans 43:34–37. https://doi.org/10.1039/c3dt52762j
138. Turner ZR, Bellabarba R, Tooze RP, Arnold PL (2010) Addition-Elimination Reactions Across
the M−C Bond of Metal N-Heterocyclic Carbenes. J Am Chem Soc 132:4050–4051. https://
doi.org/10.1021/ja910673q
139. Arnold PL, Turner ZR, Germeroth AI, Casely IJ, Nichol GS, Bellabarba R, Tooze RP
(2013) Carbon Monoxide and Carbon Dioxide Insertion Chemistry of f-Block N-Heterocyclic
Carbene Complexes. Dalton Trans 42:1333–1337. https://doi.org/10.1039/C2DT31698F
140. Arnold PL, Kerr RWF, Weetman C, Docherty SR, Rieb J, Cruickshank FL, Wang K, Jandl C,
McMullon MW, Pöthig A, Kühn FE, Smith AD (2018) Selective and Catalytic Carbon Dioxide
and Heteroallene Activation Mediated by Cerium N-Heterocyclic Carbene Complexes. Chem
Sci 9:8035–8045. https://doi.org/10.1039/C8SC03312A
141. Sun X, Su W, Shi K, Xie Z, Zhu C (2020) Triple Frustrated Lewis Pair-Type Reactivity on a
Single Rare Earth Metal Center. Chem Eur J Accepted Manuscript. https://doi.org/10.1002/
chem.201905629
142. Stephan DW (1989) Early-Late Heterobimetallics. Coord Chem Rev 95:41–107. https://doi.
org/10.1016/0010-8545(89)80002-5
143. Wheatley N, Kalck P (1999) Structure and Reactivity of Early−Late Heterobimetallic
Complexes. Chem Rev 99:3379–3420. https://doi.org/10.1021/cr980325m
144. Gade LH (2000) Highly Polar Metal-Metal Bonds in “Early-Late” Heterodimetallic
Complexes. Angew Chem Int Ed 39:2658–2678. https://doi.org/10.1002/1521-3773(200008
04)39:15%3c2658::AID-ANIE2658%3e3.0.CO;2-C
145. Cooper BG, Napoline JW, Thomas CM (2012) Catalytic Applications of Early/Late
Heterobimetallic Complexes. Catal Rev 54:1–40. https://doi.org/10.1080/01614940.2012.
619931
146. Herberhold M, Jin G-X (1994) Heterodimetallic Complexes with an Unbridged, Polar MetalMetal Bond. Angew Chem Int Ed 33:964–966. https://doi.org/10.1002/anie.199409641
147. Chapman AM, Flynn SR, Wass DF (2016) Unexpected Formation of Early Late Heterobimetallic Complexes from Transition Metal Frustrated Lewis Pairs. Inorg Chem 55:1017–
1021. https://doi.org/10.1021/acs.inorgchem.5b01424
148. Campos C (2017) Dihydrogen and Acetylene Activation by a Gold(I)/Platinum(0) Transition
Metal Only Frustrated Lewis Pair. J Am Chem Soc 139:2944–2947. https://doi.org/10.1021/
jacs.7b00491
149. Bauer J, Braunschweig H, Dewhurst RD (2012) Metal-Only Lewis Pairs with Transition Metal
Lewis Bases. Chem Rev 112:4329–4346. https://doi.org/10.1021/cr3000048
150. Hidalgo N, Moreno JJ, Pérez-Jiménez M, Maya C, López-Serrano J, Campos J (2020a)
Evidence for Genuine Bimetallic Frustrated Lewis Pair Activation of Dihydrogen with
Gold(I)/Platinum(0) Systems. Chem Eur J 26:5982–5993
151. Dang LX, Schenter GK, Chang T-M, Kathmann SM, Autrey T (2012) Role of Solvents on
the Thermodynamics and Kinetics of Forming Frustrated Lewis Pairs. J Phys Chem Lett
3:3312–3319. https://doi.org/10.1021/jz301533a
152. Hidalgo N, Bajo S, Moreno JJ, Navarro-Gilabert C, Mercado BQ, Campos J (2019) Reactivity
of a Gold(I)/Platinum(0) Frustrated Lewis Pair with Germanium and Tin Dihalides. Dalton
Trans 48:9127–9138. https://doi.org/10.1039/c9dt00702d
153. Hidalgo N, Moreno JJ, Pérez-Jiménez M, Maya C, López-Serrano J, Campos J (2020) Tuning
Activity and Selectivity During Alkyne Activation by Gold(I)/Platinum(0) Frustrated Lewis
Pairs. Organometallics 39:2534–2544. https://doi.org/10.1021/acs.organomet.0c00330
154. Dureen MA, Stephan DW (2009) Terminal Alkyne Activation by Frustrated and cC Classical
Lewis Acid/Phosphine Pairs. J Am Chem Soc 131:8396–8397. https://doi.org/10.1021/ja9
03650w
155. Pinkes JR, Steffey BD, Vites JC, Cutler AR (1994) Carbon Dioxide Insertion into the Fe-Zr and
Ru-Zr Bonds of the Heterobimetallic Complexes Cp(CO) 2 M-Zr(Cl)Cp 2 : Direct Production
of the μ-η 1 (C):η 2 (O, O’)-CO 2 Compounds Cp(CO) 2 M-CO 2 -Zr(Cl)Cp 2 . Organometallics
13:21–23. https://doi.org/10.1021/om00013a009