9 Frustrated Lewis Pairs Based on Transition Metals
355
120. Arndt S, Hansmann MM, Motloch P, Rudolph M, Rominger F, Hashmi ASK (2017)
Intramolecular Anti-Phosphinoauration of Alkynes: An FLP-M otivated Approach to Stable
Aurated Phosphindolium Complexes. Chem Eur J 23:2542–2547. https://doi.org/10.1002/
chem.201605914
121. Wang Z, Wang Y, Zhang L (2014) Soft Propargylic Deprotonation: Designed Ligand Enables
Au-Catalyzed Isomerization of Alkynes to 1,3-Dienes. J Am Chem Soc 136:8887–8890.
https://doi.org/10.1021/ja503909c
122. Wang Z, Ying A, Fan Z, Hervieu C, Zhang L (2017) Tertiary Amino Group in Cationic Gold
Catalyst: Tethered Frustrated Lewis Pairs that Enable Ligand-Controlled Regiodivergent and
Stereoselective Isomerizations of Propargylic Esters. ACS Catal 5:3676–3680. https://doi.
org/10.1021/acscatal.7b00626
123. Li X, Ma X, Wang Z, Liu P-N, Zhang L (2019) Bifunctional Phosphine Ligand Enabled
Gold-Catalyzed Alkynamide Cycloisomerization: Access to Electron-Rich 2-Aminofurans
and their Diels–Alder Adducts. Angew Chem Int Ed 58:17180–17184. https://doi.org/10.
1002/anie.201908598
124. Cheng X, Wang Z, Quintanilla CD, Zhang L (2019) Chiral Bifunctional Phosphine Ligand
Enabling Gold-Catalyzed Asymmetric Isomerization of Alkyne to Allene and Asymmetric
Synthesis of 2,5-Dihydrofuran. J Am Chem Soc 141:3787–3791. https://doi.org/10.1021/jacs.
8b12833
125. Anwander R, Kobayashi S (1999). Kobayashi S (Eds), Lanthanides: Chemistry and Use in
Organic Synthesis, Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-69801-9
126. Berkefeld A, Piers WE, Parvez M, Castro L, Maron L, Eisenstein O (2012) Carbon Monoxide
Activation via O-Bound CO Using Decamethylscandocinium−Hydridoborate Ion Pairs. J
Am Chem Soc 134:10843–10851. https://doi.org/10.1021/ja300591v
127. Berkefeld A, Piers WE, Parvez M, Castro L, Maron L, Eisenstein O (2013)
Decamethylscandocinium-Hydrido-(Perfluorophenyl)-Borate: Fixation and Tandem
Tris(Perfluorophenyl)-Borane Catalysed Deoxygenative Hydrosilation of Carbon Dioxide.
Chem Sci 4:2152–2162. https://doi.org/10.1039/C3SC50145K
128. Chang K, Xu X (2017) Frustrated Lewis Pair Behaviour of a Neutral Scandium Complex.
Dalton Trans 46:4514–4517. https://doi.org/10.1039/c7dt00676d
129. Chang K, Wang X, Fan Z, Xu X (2018) Reactions of Neutral Scandium/Phosphorus Lewis
Pairs with Small Molecules. Inorg Chem 57:8568–8580. https://doi.org/10.1021/acs.inorgc
hem.8b01292
130. Xu P, Yao Y, Xu X (2017) Frustrated Lewis Pair-Like Reactivity of Rare-Earth Metal
Complexes: 1,4-Addition Reactions and Polymerizations of Conjugated Polar Alkenes. Chem
Eur J 23:1263–1267. https://doi.org/10.1002/chem.201605622
131. Yao T, Xu P, Xu X (2019) Scandium Complexes Containing β-Diketiminato Ligands with
Pendant Phosphanyl Groups: Competition Between Sc/γ-C [4 + 2] Cycloaddition and Sc/P
Frustrated Lewis Pair Reactions. Dalton Trans 48:7743–7754. https://doi.org/10.1039/c9dt01
035a
132. Yasuda H (2002) Organo-Rare-Earth-Metal Initiated Living Polymerizations of Polar and
Nonpolar Monomers. J Organomet Chem 647:128–138. https://doi.org/10.1016/S0022-328
X(01)01357-2
133. Yasuda H (2001) Rare-Earth-Metal-Initiated Polymerizations of (Meth)Acrylates and Block
Copolymerizations of Olefins with Polar Monomers. J Polym Sci Part a Polym Chem 39:1955–
1959. https://doi.org/10.1002/pola.1172
134. Xu P, Xu X (2018) Homoleptic Rare-Earth Aryloxide Based Lewis Pairs for Polymerization of
Conjugated Polar Alkenes. ACS Catal 8:198–202. https://doi.org/10.1021/acscatal.7b02875
135. Xu P, Wu L, Dong L, Xu X (2018) Chemoselective Polymerization of Polar Divinyl Monomers
with Rare-Earth/Phosphine Lewis Pairs. Molecules 2:360–369. https://doi.org/10.3390/mol
ecules23020360
136. Chang K, Dong Y, Xu X (2019) Dihydrogen Activation by Intermolecular Rare-Earth
Aryloxide/N-Heterocyclic Carbene Lewis Pairs. Chem Commun 55:12777–12780. https://
doi.org/10.1039/C9CC06676D
355
120. Arndt S, Hansmann MM, Motloch P, Rudolph M, Rominger F, Hashmi ASK (2017)
Intramolecular Anti-Phosphinoauration of Alkynes: An FLP-M otivated Approach to Stable
Aurated Phosphindolium Complexes. Chem Eur J 23:2542–2547. https://doi.org/10.1002/
chem.201605914
121. Wang Z, Wang Y, Zhang L (2014) Soft Propargylic Deprotonation: Designed Ligand Enables
Au-Catalyzed Isomerization of Alkynes to 1,3-Dienes. J Am Chem Soc 136:8887–8890.
https://doi.org/10.1021/ja503909c
122. Wang Z, Ying A, Fan Z, Hervieu C, Zhang L (2017) Tertiary Amino Group in Cationic Gold
Catalyst: Tethered Frustrated Lewis Pairs that Enable Ligand-Controlled Regiodivergent and
Stereoselective Isomerizations of Propargylic Esters. ACS Catal 5:3676–3680. https://doi.
org/10.1021/acscatal.7b00626
123. Li X, Ma X, Wang Z, Liu P-N, Zhang L (2019) Bifunctional Phosphine Ligand Enabled
Gold-Catalyzed Alkynamide Cycloisomerization: Access to Electron-Rich 2-Aminofurans
and their Diels–Alder Adducts. Angew Chem Int Ed 58:17180–17184. https://doi.org/10.
1002/anie.201908598
124. Cheng X, Wang Z, Quintanilla CD, Zhang L (2019) Chiral Bifunctional Phosphine Ligand
Enabling Gold-Catalyzed Asymmetric Isomerization of Alkyne to Allene and Asymmetric
Synthesis of 2,5-Dihydrofuran. J Am Chem Soc 141:3787–3791. https://doi.org/10.1021/jacs.
8b12833
125. Anwander R, Kobayashi S (1999). Kobayashi S (Eds), Lanthanides: Chemistry and Use in
Organic Synthesis, Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-69801-9
126. Berkefeld A, Piers WE, Parvez M, Castro L, Maron L, Eisenstein O (2012) Carbon Monoxide
Activation via O-Bound CO Using Decamethylscandocinium−Hydridoborate Ion Pairs. J
Am Chem Soc 134:10843–10851. https://doi.org/10.1021/ja300591v
127. Berkefeld A, Piers WE, Parvez M, Castro L, Maron L, Eisenstein O (2013)
Decamethylscandocinium-Hydrido-(Perfluorophenyl)-Borate: Fixation and Tandem
Tris(Perfluorophenyl)-Borane Catalysed Deoxygenative Hydrosilation of Carbon Dioxide.
Chem Sci 4:2152–2162. https://doi.org/10.1039/C3SC50145K
128. Chang K, Xu X (2017) Frustrated Lewis Pair Behaviour of a Neutral Scandium Complex.
Dalton Trans 46:4514–4517. https://doi.org/10.1039/c7dt00676d
129. Chang K, Wang X, Fan Z, Xu X (2018) Reactions of Neutral Scandium/Phosphorus Lewis
Pairs with Small Molecules. Inorg Chem 57:8568–8580. https://doi.org/10.1021/acs.inorgc
hem.8b01292
130. Xu P, Yao Y, Xu X (2017) Frustrated Lewis Pair-Like Reactivity of Rare-Earth Metal
Complexes: 1,4-Addition Reactions and Polymerizations of Conjugated Polar Alkenes. Chem
Eur J 23:1263–1267. https://doi.org/10.1002/chem.201605622
131. Yao T, Xu P, Xu X (2019) Scandium Complexes Containing β-Diketiminato Ligands with
Pendant Phosphanyl Groups: Competition Between Sc/γ-C [4 + 2] Cycloaddition and Sc/P
Frustrated Lewis Pair Reactions. Dalton Trans 48:7743–7754. https://doi.org/10.1039/c9dt01
035a
132. Yasuda H (2002) Organo-Rare-Earth-Metal Initiated Living Polymerizations of Polar and
Nonpolar Monomers. J Organomet Chem 647:128–138. https://doi.org/10.1016/S0022-328
X(01)01357-2
133. Yasuda H (2001) Rare-Earth-Metal-Initiated Polymerizations of (Meth)Acrylates and Block
Copolymerizations of Olefins with Polar Monomers. J Polym Sci Part a Polym Chem 39:1955–
1959. https://doi.org/10.1002/pola.1172
134. Xu P, Xu X (2018) Homoleptic Rare-Earth Aryloxide Based Lewis Pairs for Polymerization of
Conjugated Polar Alkenes. ACS Catal 8:198–202. https://doi.org/10.1021/acscatal.7b02875
135. Xu P, Wu L, Dong L, Xu X (2018) Chemoselective Polymerization of Polar Divinyl Monomers
with Rare-Earth/Phosphine Lewis Pairs. Molecules 2:360–369. https://doi.org/10.3390/mol
ecules23020360
136. Chang K, Dong Y, Xu X (2019) Dihydrogen Activation by Intermolecular Rare-Earth
Aryloxide/N-Heterocyclic Carbene Lewis Pairs. Chem Commun 55:12777–12780. https://
doi.org/10.1039/C9CC06676D