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101. Rokob TA, Hamza A, Stirling A, Pápai I (2009) On the Mechanism of B(C 6 F 5 ) 3 -Catalyzed
Direct Hydrogenation of Imines: Inherent and Thermally Induced Frustration. J Am Chem
Soc 131:2029–2036. https://doi.org/10.1021/ja809125r
102. Owen GR (2012) Hydrogen Atom Storage Upon Z-class Borane Ligand Functions: An Alternative Approach to Ligand Cooperation. Chem Soc Rev 41:3535–3546. https://doi.org/10.
1039/C2CS15346G
103. Harman WH, Peters JC (2012) Reversible H 2 Addition Across a Nickel–Borane Unit as a
Promising Strategy for Catalysis. J Am Chem Soc 134:5080–5082. https://doi.org/10.1021/
ja211419t
104. Fong H, Moret M-E, Lee Y, Peters JC (2013) Heterolytic H 2 Cleavage and Catalytic Hydrogenation by an Iron Metallaboratrane. Organometallics 32:3053–3062. https://doi.org/10.
1021/om400281v
105. MacMillan SN, Hill Harman W, Peters JC (2014) Facile Si–H Bond Activation and Hydrosilylation Catalysis Mediated by a Nickel–Borane Complex. Chem Sci 5:590–597. https://doi.
org/10.1039/C3SC52626G
106. Harman WH, Lin T-P, Peters JC (2014) A d 10 Ni–(H 2 ) Adduct as an Intermediate in H-H
Oxidative Addition Across a NiB Bond. Angew Chem Int Ed 53:1081–1086. https://doi.org/
10.1002/anie.201308175
107. Nesbit MA, Suess DLM, Peters JC (2015) E−H Bond Activations and Hydrosilylation Catalysis with Iron and Cobalt Metalloboranes. Organometallics 34:4741–4752. https://doi.org/
10.1021/acs.organomet.5b00530
108. Forrest SJK, Clifton J, Fey N, Pringle PG, Sparkes HA, Wass DF (2015) Cooperative Lewis
Pairs Based on Late Transition Metals: Activation of Small Molecules by Platinum(0) and
B(C 6 F 5 ) 3 . Angew Chem Int Ed 54:2223–2227. https://doi.org/10.1002/anie.201409872
109. Mistry K, Pringle PG, Sparkes HA, Wass DF (2020) Transition Metal Cooperative Lewis Pairs
Using Platinum(0) Diphosphine Monocarbonyl Complexes as Lewis Bases. Organometallics
39:468–477. https://doi.org/10.1021/acs.organomet.9b00568
110. Barnett BR, Moore CE, Rheingold AL, Figueroa JS (2014) Cooperative Transition
Metal/Lewis Acid Bond-Activation Reactions by a Bidentate (Boryl)Iminomethane Complex:
A Significant Metal-Borane Interaction Promoted by a Small Bite-Angle LZ Chelate. J Am
Chem Soc 136:10262–10265. https://doi.org/10.1021/ja505843g
111. Barnett BR, Neville ML, Moore CE, Rheingold AL, Figueroa JS (2017) Oxidative-Insertion
Reactivity Across a Geometrically Constrained Metal→Borane interaction. Angew Chem Int
Ed 56:7195–7199. https://doi.org/10.1002/anie.201702151
112. Friend CM, Hashmi ASK (2014) Gold Catalysis. Acc Chem Res 47:729–730. https://doi.org/
10.1021/ar5000506
113. Braun I, Asiri AM, Hashmi ASK (2013) Gold Catalysis 2.0. ACS Catal 3:1902–1907. https://
doi.org/10.1021/cs400437s
114. Rudolph M, Hashmi AS (2012) Gold Catalysis in Total Synthesis—an Update. Chem Soc
Rev 41:2448–2462. https://doi.org/10.1039/C1CS15279C
115. Krause N, Winter C (2011) Gold-Catalyzed Nucleophilic Cy clization of functionalized
allenes: A powerful access to carbo- and heterocycles. Chem Rev 111:1994–2009. https://
doi.org/10.1021/cr1004088
116. Corma A, Leyva-Pérez A, Sabater MJ (2011) Gold-Catalyzed Carbon−Heteroatom BondForming Reactions. Chem Rev 111:1657–1712. https://doi.org/10.1021/cr100414u
117. Fîrstner A (2009) Gold and Platinum Catalysis—a Convenient Tool for Generating Molecular
Complexity. Chem Soc Rev 38:3208–3221. https://doi.org/10.1039/B816696J
118. Obradors C, Echavarren AM (2014) Intriguing Mechanistic Labyrinths in Gold (I) Catalysis.
Chem Commun 50:16–28. https://doi.org/10.1039/C3CC45518A
119. Weber SG, Loos C, Rominger F, Straub BF (2012) Synthesis of an Extremely Sterically
Shielding N-Heterocyclic Carbene Ligand. ARKIVOC (Gainesville, FL, U.S.) 3:226–242.
https://doi.org/10.3998/ark.5550190.0013.317
N. Hidalgo et al.
101. Rokob TA, Hamza A, Stirling A, Pápai I (2009) On the Mechanism of B(C 6 F 5 ) 3 -Catalyzed
Direct Hydrogenation of Imines: Inherent and Thermally Induced Frustration. J Am Chem
Soc 131:2029–2036. https://doi.org/10.1021/ja809125r
102. Owen GR (2012) Hydrogen Atom Storage Upon Z-class Borane Ligand Functions: An Alternative Approach to Ligand Cooperation. Chem Soc Rev 41:3535–3546. https://doi.org/10.
1039/C2CS15346G
103. Harman WH, Peters JC (2012) Reversible H 2 Addition Across a Nickel–Borane Unit as a
Promising Strategy for Catalysis. J Am Chem Soc 134:5080–5082. https://doi.org/10.1021/
ja211419t
104. Fong H, Moret M-E, Lee Y, Peters JC (2013) Heterolytic H 2 Cleavage and Catalytic Hydrogenation by an Iron Metallaboratrane. Organometallics 32:3053–3062. https://doi.org/10.
1021/om400281v
105. MacMillan SN, Hill Harman W, Peters JC (2014) Facile Si–H Bond Activation and Hydrosilylation Catalysis Mediated by a Nickel–Borane Complex. Chem Sci 5:590–597. https://doi.
org/10.1039/C3SC52626G
106. Harman WH, Lin T-P, Peters JC (2014) A d 10 Ni–(H 2 ) Adduct as an Intermediate in H-H
Oxidative Addition Across a NiB Bond. Angew Chem Int Ed 53:1081–1086. https://doi.org/
10.1002/anie.201308175
107. Nesbit MA, Suess DLM, Peters JC (2015) E−H Bond Activations and Hydrosilylation Catalysis with Iron and Cobalt Metalloboranes. Organometallics 34:4741–4752. https://doi.org/
10.1021/acs.organomet.5b00530
108. Forrest SJK, Clifton J, Fey N, Pringle PG, Sparkes HA, Wass DF (2015) Cooperative Lewis
Pairs Based on Late Transition Metals: Activation of Small Molecules by Platinum(0) and
B(C 6 F 5 ) 3 . Angew Chem Int Ed 54:2223–2227. https://doi.org/10.1002/anie.201409872
109. Mistry K, Pringle PG, Sparkes HA, Wass DF (2020) Transition Metal Cooperative Lewis Pairs
Using Platinum(0) Diphosphine Monocarbonyl Complexes as Lewis Bases. Organometallics
39:468–477. https://doi.org/10.1021/acs.organomet.9b00568
110. Barnett BR, Moore CE, Rheingold AL, Figueroa JS (2014) Cooperative Transition
Metal/Lewis Acid Bond-Activation Reactions by a Bidentate (Boryl)Iminomethane Complex:
A Significant Metal-Borane Interaction Promoted by a Small Bite-Angle LZ Chelate. J Am
Chem Soc 136:10262–10265. https://doi.org/10.1021/ja505843g
111. Barnett BR, Neville ML, Moore CE, Rheingold AL, Figueroa JS (2017) Oxidative-Insertion
Reactivity Across a Geometrically Constrained Metal→Borane interaction. Angew Chem Int
Ed 56:7195–7199. https://doi.org/10.1002/anie.201702151
112. Friend CM, Hashmi ASK (2014) Gold Catalysis. Acc Chem Res 47:729–730. https://doi.org/
10.1021/ar5000506
113. Braun I, Asiri AM, Hashmi ASK (2013) Gold Catalysis 2.0. ACS Catal 3:1902–1907. https://
doi.org/10.1021/cs400437s
114. Rudolph M, Hashmi AS (2012) Gold Catalysis in Total Synthesis—an Update. Chem Soc
Rev 41:2448–2462. https://doi.org/10.1039/C1CS15279C
115. Krause N, Winter C (2011) Gold-Catalyzed Nucleophilic Cy clization of functionalized
allenes: A powerful access to carbo- and heterocycles. Chem Rev 111:1994–2009. https://
doi.org/10.1021/cr1004088
116. Corma A, Leyva-Pérez A, Sabater MJ (2011) Gold-Catalyzed Carbon−Heteroatom BondForming Reactions. Chem Rev 111:1657–1712. https://doi.org/10.1021/cr100414u
117. Fîrstner A (2009) Gold and Platinum Catalysis—a Convenient Tool for Generating Molecular
Complexity. Chem Soc Rev 38:3208–3221. https://doi.org/10.1039/B816696J
118. Obradors C, Echavarren AM (2014) Intriguing Mechanistic Labyrinths in Gold (I) Catalysis.
Chem Commun 50:16–28. https://doi.org/10.1039/C3CC45518A
119. Weber SG, Loos C, Rominger F, Straub BF (2012) Synthesis of an Extremely Sterically
Shielding N-Heterocyclic Carbene Ligand. ARKIVOC (Gainesville, FL, U.S.) 3:226–242.
https://doi.org/10.3998/ark.5550190.0013.317