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170. Hidalgo N, Maya C, Campos J (2019) Cooperative Activation of X–H (X = H, C, O, N)
Bonds by a Pt(0)/Ag(I) Metal-Only Lewis Pair. Chem commun. 55:8812–8815. https://doi.
org/10.1039/C9CC03008E
171. Zhao J, Goldman AS, Hartwig JF (2005) Oxidative Addition of Ammonia to Form a Stable
Monomeric Amido Hydride Complex. Science 307:1080–1082. https://doi.org/10.1126/sci
ence.1109389
172. Fafard CM, Adhikari D, Foxman BM, Mindiola J, Ozerov OV (2007) Addition of Ammonia,
Water, and Dihydrogen Across a Single Pd−Pd Bond. J Am Chem Soc 129:10318–10319.
https://doi.org/10.1021/ja0731571
173. Jayarathne U, Mazzacano T J, Bagherzadeh S, Mankad N P (2013) Heterobimetallic
Complexes with Polar, Unsupported Cu−Fe and Zn−Fe Bonds Stabilized by N-Heterocyclic
Carbenes. Organometallic. 32:3986–3992. https://doi.org/10.1021/om400471u
174. Banerjee S, Karunananda M K, Bagherzadeh S, Jayarathne U, Parmelee S R, Waldhart G
W, Mankad N P (2014) Synthesis and Characterization of Heterobimetallic Complexes with
Direct Cu–M Bonds (M = Cr, Mn, Co, Mo, Ru, W) Supported by N-Heterocyclic Carbene
Ligands: A Toolkit for Catalytic Reaction Discovery. Inorg. Chem. 53:11307–11315. https://
doi.org/10.1021/ic5019778
175. Karunananda MK, Vázquez FX, Alp EE, Bi W, Chattopadhyay S, Shibatade T, Mankad
NP (2014) Experimental Determination of Redox Cooperativity and Electronic Structures in
Catalytically Active Cu–Fe and Zn–Fe Heterobimetallic Complexes. Dalton Trans 43:13661–
13671. https://doi.org/10.1039/C4DT01841A
176. Jayarathne U, Parmelee SR, Mankad NP (2014) Small Molecule Activation Chemistry of Cu–
Fe Heterobimetallic Complexes Toward CS 2 and N 2 O. Inorg Chem 53:7730–7737. https://
doi.org/10.1021/ic501054z
177. Karunananda MK, Parmelee SR, Waldhart GW, Mankad NP (2015) Experimental and Computational Characterization of the Transition State for C-X Bimetallic Oxidative Addition at a
Cu–Fe Reaction Center. Organometallics 34:3857–3864. https://doi.org/10.1021/acs.organo
met.5b00476
178. Karunananda MK, Mankad NP (2017) Heterobimetallic H 2 Addition and Alkene/Alkane
Elimination Reactions Related to the Mechanism of E-Selective Alkyne Semihydrogenation.
Organometallics 36:220–227. https://doi.org/10.1021/acs.organomet.6b00356
179. Mankad NP (2018) Diverse Bimetallic Mechanisms Emerging from Transition Metal Lewis
Acid/Base Pairs: Development of Co-Catalysis with Metal Carbenes and Metal Carbonyl
Anions. Chem Commun 54:1291–1302. https://doi.org/10.1039/C7CC09675E
180. Zhang Y, Karunananda MK, Yu HC, Clark KJ, Williams W, Mankad NP, Ess DH (2019)
Dynamically Bifurcating Hydride Transfer Mechanism and Origin of Inverse Isotope Effect
for Heterodinuclear AgRu-Catalyzed Alkyne Semihydrogenation. ACS Catal 9:2657–2663.
https://doi.org/10.1021/acscatal.8b04130
181. Karunananda MK, Mankad NP (2015) E-Selective Semi-Hydrogenation of Alkynes by Heterobimetallic Catalysis. J Am Chem Soc 137:14598–14601. https://doi.org/10.1021/jacs.5b1
0357
182. Mazzacano TJ, Mankad NP (2013) Base Metal Catalysts for Photochemical C-H Borylation
that Utilize Metal–Metal Cooperativity. J Am Chem Soc 135:17258–17261. https://doi.org/
10.1021/ja408861p
183. Parmelee SR, Mazzacano TJ, Zhu Y, Mankad NP, Keith JA (2015) A Heterobimetallic Mechanism for C-H Borylation Elucidated from Experimental and Computational Data. ACS Catal
5:3689–3699. https://doi.org/10.1021/acscatal.5b00275
184. Cheng LJ, Mankad NP (2019) Heterobimetallic Control of Regioselectivity in Alkyne
Hydrostannylation: Divergent Syntheses of α- and (E)-β-Vinylstannanes via Cooperative
Sn–H Bond Activation. J Am Chem Soc 141:3710–3716. https://doi.org/10.1021/jacs.9b0
0068
N. Hidalgo et al.
170. Hidalgo N, Maya C, Campos J (2019) Cooperative Activation of X–H (X = H, C, O, N)
Bonds by a Pt(0)/Ag(I) Metal-Only Lewis Pair. Chem commun. 55:8812–8815. https://doi.
org/10.1039/C9CC03008E
171. Zhao J, Goldman AS, Hartwig JF (2005) Oxidative Addition of Ammonia to Form a Stable
Monomeric Amido Hydride Complex. Science 307:1080–1082. https://doi.org/10.1126/sci
ence.1109389
172. Fafard CM, Adhikari D, Foxman BM, Mindiola J, Ozerov OV (2007) Addition of Ammonia,
Water, and Dihydrogen Across a Single Pd−Pd Bond. J Am Chem Soc 129:10318–10319.
https://doi.org/10.1021/ja0731571
173. Jayarathne U, Mazzacano T J, Bagherzadeh S, Mankad N P (2013) Heterobimetallic
Complexes with Polar, Unsupported Cu−Fe and Zn−Fe Bonds Stabilized by N-Heterocyclic
Carbenes. Organometallic. 32:3986–3992. https://doi.org/10.1021/om400471u
174. Banerjee S, Karunananda M K, Bagherzadeh S, Jayarathne U, Parmelee S R, Waldhart G
W, Mankad N P (2014) Synthesis and Characterization of Heterobimetallic Complexes with
Direct Cu–M Bonds (M = Cr, Mn, Co, Mo, Ru, W) Supported by N-Heterocyclic Carbene
Ligands: A Toolkit for Catalytic Reaction Discovery. Inorg. Chem. 53:11307–11315. https://
doi.org/10.1021/ic5019778
175. Karunananda MK, Vázquez FX, Alp EE, Bi W, Chattopadhyay S, Shibatade T, Mankad
NP (2014) Experimental Determination of Redox Cooperativity and Electronic Structures in
Catalytically Active Cu–Fe and Zn–Fe Heterobimetallic Complexes. Dalton Trans 43:13661–
13671. https://doi.org/10.1039/C4DT01841A
176. Jayarathne U, Parmelee SR, Mankad NP (2014) Small Molecule Activation Chemistry of Cu–
Fe Heterobimetallic Complexes Toward CS 2 and N 2 O. Inorg Chem 53:7730–7737. https://
doi.org/10.1021/ic501054z
177. Karunananda MK, Parmelee SR, Waldhart GW, Mankad NP (2015) Experimental and Computational Characterization of the Transition State for C-X Bimetallic Oxidative Addition at a
Cu–Fe Reaction Center. Organometallics 34:3857–3864. https://doi.org/10.1021/acs.organo
met.5b00476
178. Karunananda MK, Mankad NP (2017) Heterobimetallic H 2 Addition and Alkene/Alkane
Elimination Reactions Related to the Mechanism of E-Selective Alkyne Semihydrogenation.
Organometallics 36:220–227. https://doi.org/10.1021/acs.organomet.6b00356
179. Mankad NP (2018) Diverse Bimetallic Mechanisms Emerging from Transition Metal Lewis
Acid/Base Pairs: Development of Co-Catalysis with Metal Carbenes and Metal Carbonyl
Anions. Chem Commun 54:1291–1302. https://doi.org/10.1039/C7CC09675E
180. Zhang Y, Karunananda MK, Yu HC, Clark KJ, Williams W, Mankad NP, Ess DH (2019)
Dynamically Bifurcating Hydride Transfer Mechanism and Origin of Inverse Isotope Effect
for Heterodinuclear AgRu-Catalyzed Alkyne Semihydrogenation. ACS Catal 9:2657–2663.
https://doi.org/10.1021/acscatal.8b04130
181. Karunananda MK, Mankad NP (2015) E-Selective Semi-Hydrogenation of Alkynes by Heterobimetallic Catalysis. J Am Chem Soc 137:14598–14601. https://doi.org/10.1021/jacs.5b1
0357
182. Mazzacano TJ, Mankad NP (2013) Base Metal Catalysts for Photochemical C-H Borylation
that Utilize Metal–Metal Cooperativity. J Am Chem Soc 135:17258–17261. https://doi.org/
10.1021/ja408861p
183. Parmelee SR, Mazzacano TJ, Zhu Y, Mankad NP, Keith JA (2015) A Heterobimetallic Mechanism for C-H Borylation Elucidated from Experimental and Computational Data. ACS Catal
5:3689–3699. https://doi.org/10.1021/acscatal.5b00275
184. Cheng LJ, Mankad NP (2019) Heterobimetallic Control of Regioselectivity in Alkyne
Hydrostannylation: Divergent Syntheses of α- and (E)-β-Vinylstannanes via Cooperative
Sn–H Bond Activation. J Am Chem Soc 141:3710–3716. https://doi.org/10.1021/jacs.9b0
0068