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33. Higashi T, Kusumoto S, Nozaki K (2019) Cleavage of Si-H, B-H, and C-H Bonds by MetalLigand Cooperation. Chem Rev 119:10393–10402. https://doi.org/10.1021/acs.chemrev.9b0
0262
34. Verhoeven DGA, Moret M-E (2016) Metal–Ligand Cooperation at Tethered π-Ligands.
Dalton Trans 45:15762–15778. https://doi.org/10.1039/C6DT02184K
35. Khusnutdinova JR, Milstein D (2015) Metal-Ligand Cooperation. Angew Chem Int Ed
54:12236–12273. https://doi.org/10.1002/anie.201503873
36. Li C, Agarwal J, Schaefer HF (2014) The Remarkable [ReH 9 ] 2 −Dianion: Molecular Structure
and Vibrational Frequencies. J Phys Chem B 118:6482–6490. https://doi.org/10.1021/jp4
12003s
37. Lu Z, Ye H, Wang H (2012) New Organoboranes in “Frustrated Lewis Pair” Chemistry. In:
Erker G, Stephan D (eds) Frustrated Lewis Pairs II. Topics in Current Chemistry. Springer,
Berlin, Heidelberg, p 59−80. https://doi.org/10.1007/128_2012_382
38. Keep KP (2016) A Quantitative Scale of Oxophilicity and Thiophilicity. Inorg Chem 55:9461–
9470. https://doi.org/10.1021/acs.inorgchem.6b01702
39. Weiss M, Peters R (2015) Bimetallic Catalysis: Cooperation of Carbophilic Metal Centers. In:
Peters R (ed) Cooperative Catalysis: Designing Efficient Catalysts for Synthesis. Wiley-VCH,
Weinheim, pp 227–262. https://doi.org/10.1002/9783527681020.ch8
40. Tsipis AC (2017) DFT Challenge of Intermetallic Interactions: From Metallophilicity and
Metallaromaticity to Sextuple Bonding. Coord Chem Rev 345:229–262. https://doi.org/10.
1016/j.ccr.2016.08.005
41. Belkova NV, Epstein LM, Shubina ES (2008) On Peculiarities of Hydrogen Bonding and
Proton Transfer Equilibria of Organic Versus Organometallic Bases. ARKIVOC 4:120–138.
https://doi.org/10.3998/ark.5550190.0009.413
42. Rivas JCM (2007) Cooperation of Metals and Hydrogen Bonding Groups in Metal-Promoted
Reactions. Curr Org Chem 11:1434–1449. https://doi.org/10.2174/138527207782418726
43. Yamamoto H (ed) (2000) Lewis Acids in Organic Synthesis. Wiley-VCH, Weinheim. https://
doi.org/10.1002/aoc.201
44. McCahill JSJ, Welch GC, Stephan DW (2007) Reactivity of ‘Frustrated Lewis Pairs’: ThreeComponent Reactions of Phosphines, a Borane and Olefins. Angew Chem Int Ed 46:4968–
4971. https://doi.org/10.1002/anie.200701215
45. Chapman AM, Wass DF (2012) Cationic Ti(IV) and Neutral Ti(III) Titanocene–Phosphinoaryloxide Frustrated Lewis Pairs: Hydrogen Activation and Catalytic Amine-Borane
Dehydrogenation. Dalton Trans 41:9067–9072. https://doi.org/10.1039/c2dt30168g
46. Normand AT, Richard P, Balan C, Daniliuc CG, Kehr G, Erker G, Gendre PL (2015) Synthetic
Endeavors Toward Titanium Based Frustrated Lewis Pairs with Controlled Electronic and
Steric Properties. Organometallics 34:2000–2011. https://doi.org/10.1021/acs.organomet.5b0
0250
47. Normand AT, Bonnin Q, Brandès S, Richard P, Fleurat-Lessard P, Devillers CH, Balan C,
Gendre PL, Kehr G, Erker G (2019) The Taming of Redox-Labile Phosphidotitanocene
Cations. Chem Eur J 25:2803–2815. https://doi.org/10.1002/chem.201805430
48. Fischer M, Barbul D, Schmidtmann M, Beckhaus R (2018) Convenient Synthesis of Cationic
Titanium Complexes with Tridentate Cp, N, P-Ligand Framework: FLP-Like Reactivity at
the Ti−N Bond and Unexpected Ligand Hydrogenation Reaction. Organometallics 37:1979–
1991. https://doi.org/10.1021/acs.organomet.8b00283
49. Fischer M, Schwitalla K, Baues S, Schmidtmann M, Beckhaus R (2019) FLP Behaviour of
Cationic Titanium Complexes with Tridentate Cp, O, N-Ligands: Highly Efficient Syntheses
and Activation Reactions of C-X Bonds (X = Cl, F). Dalton Trans 48:1516–1523. https://doi.
org/10.1039/c8dt04707c
N. Hidalgo et al.
33. Higashi T, Kusumoto S, Nozaki K (2019) Cleavage of Si-H, B-H, and C-H Bonds by MetalLigand Cooperation. Chem Rev 119:10393–10402. https://doi.org/10.1021/acs.chemrev.9b0
0262
34. Verhoeven DGA, Moret M-E (2016) Metal–Ligand Cooperation at Tethered π-Ligands.
Dalton Trans 45:15762–15778. https://doi.org/10.1039/C6DT02184K
35. Khusnutdinova JR, Milstein D (2015) Metal-Ligand Cooperation. Angew Chem Int Ed
54:12236–12273. https://doi.org/10.1002/anie.201503873
36. Li C, Agarwal J, Schaefer HF (2014) The Remarkable [ReH 9 ] 2 −Dianion: Molecular Structure
and Vibrational Frequencies. J Phys Chem B 118:6482–6490. https://doi.org/10.1021/jp4
12003s
37. Lu Z, Ye H, Wang H (2012) New Organoboranes in “Frustrated Lewis Pair” Chemistry. In:
Erker G, Stephan D (eds) Frustrated Lewis Pairs II. Topics in Current Chemistry. Springer,
Berlin, Heidelberg, p 59−80. https://doi.org/10.1007/128_2012_382
38. Keep KP (2016) A Quantitative Scale of Oxophilicity and Thiophilicity. Inorg Chem 55:9461–
9470. https://doi.org/10.1021/acs.inorgchem.6b01702
39. Weiss M, Peters R (2015) Bimetallic Catalysis: Cooperation of Carbophilic Metal Centers. In:
Peters R (ed) Cooperative Catalysis: Designing Efficient Catalysts for Synthesis. Wiley-VCH,
Weinheim, pp 227–262. https://doi.org/10.1002/9783527681020.ch8
40. Tsipis AC (2017) DFT Challenge of Intermetallic Interactions: From Metallophilicity and
Metallaromaticity to Sextuple Bonding. Coord Chem Rev 345:229–262. https://doi.org/10.
1016/j.ccr.2016.08.005
41. Belkova NV, Epstein LM, Shubina ES (2008) On Peculiarities of Hydrogen Bonding and
Proton Transfer Equilibria of Organic Versus Organometallic Bases. ARKIVOC 4:120–138.
https://doi.org/10.3998/ark.5550190.0009.413
42. Rivas JCM (2007) Cooperation of Metals and Hydrogen Bonding Groups in Metal-Promoted
Reactions. Curr Org Chem 11:1434–1449. https://doi.org/10.2174/138527207782418726
43. Yamamoto H (ed) (2000) Lewis Acids in Organic Synthesis. Wiley-VCH, Weinheim. https://
doi.org/10.1002/aoc.201
44. McCahill JSJ, Welch GC, Stephan DW (2007) Reactivity of ‘Frustrated Lewis Pairs’: ThreeComponent Reactions of Phosphines, a Borane and Olefins. Angew Chem Int Ed 46:4968–
4971. https://doi.org/10.1002/anie.200701215
45. Chapman AM, Wass DF (2012) Cationic Ti(IV) and Neutral Ti(III) Titanocene–Phosphinoaryloxide Frustrated Lewis Pairs: Hydrogen Activation and Catalytic Amine-Borane
Dehydrogenation. Dalton Trans 41:9067–9072. https://doi.org/10.1039/c2dt30168g
46. Normand AT, Richard P, Balan C, Daniliuc CG, Kehr G, Erker G, Gendre PL (2015) Synthetic
Endeavors Toward Titanium Based Frustrated Lewis Pairs with Controlled Electronic and
Steric Properties. Organometallics 34:2000–2011. https://doi.org/10.1021/acs.organomet.5b0
0250
47. Normand AT, Bonnin Q, Brandès S, Richard P, Fleurat-Lessard P, Devillers CH, Balan C,
Gendre PL, Kehr G, Erker G (2019) The Taming of Redox-Labile Phosphidotitanocene
Cations. Chem Eur J 25:2803–2815. https://doi.org/10.1002/chem.201805430
48. Fischer M, Barbul D, Schmidtmann M, Beckhaus R (2018) Convenient Synthesis of Cationic
Titanium Complexes with Tridentate Cp, N, P-Ligand Framework: FLP-Like Reactivity at
the Ti−N Bond and Unexpected Ligand Hydrogenation Reaction. Organometallics 37:1979–
1991. https://doi.org/10.1021/acs.organomet.8b00283
49. Fischer M, Schwitalla K, Baues S, Schmidtmann M, Beckhaus R (2019) FLP Behaviour of
Cationic Titanium Complexes with Tridentate Cp, O, N-Ligands: Highly Efficient Syntheses
and Activation Reactions of C-X Bonds (X = Cl, F). Dalton Trans 48:1516–1523. https://doi.
org/10.1039/c8dt04707c