9 Frustrated Lewis Pairs Based on Transition Metals
349
18. Erker G (2011) Organometallic Frustrated Lewis Pair Chemistry. Dalton Trans 40:7475–7483.
https://doi.org/10.1039/C1DT10152H
19. Bouhadir G, Bourissou D (2016) Complexes of Ambiphilic Ligands: Reactivity and Catalytic
Applications. Chem Soc Rev 45:1065–1079. https://doi.org/10.1039/C5CS00697J
20. Bullock RM, Chambers GM (2017) Frustration Across the Periodic Table: Heterolytic
Cleavage of Dihydrogen by Metal Complexes. Phil Trans R Soc a 375:20170002. https://
doi.org/10.1098/rsta.2017.0002
21. Whited MT (2012) Metal–Ligand Multiple Bonds as Frustrated Lewis Pairs for C-H
Functionalization. Beilstein J Org Chem 8:1554–1563. https://doi.org/10.3762/bjoc.8.177
22. Arndt S, Rudolph M, Hashmi ASK (2017) Gold-Based Frustrated Lewis Acid/Base Pairs
(FLPs). Gold Bull 50:267–282. https://doi.org/10.1007/s13404-017-0219-7
23. Lu G, Zhang P, Sun D, Wang L, Zhou K, Wang Z-X, Guo G-C (2014) Gold Catalyzed
Hydrogenations of Small Imines and Nitriles: Enhanced Reactivity of Au Surface Toward H 2
via Collaboration with a Lewis Base. Chem Sci 5:1082–1090. https://doi.org/10.1039/C3S
C52851K
24. Zhao X, Wang J, Yang M, Lei N, Li L, Hou B, Miao S, Pan X, Wang A, Zhang T (2017)
Selective Hydrogenolysis of Glycerol to 1,3-propanediol: Manipulating the Frustrated Lewis
Pairs by Introducing Gold to Pt/WOx. Chemsuschem 10:819–824. https://doi.org/10.1002/
cssc.201601503
25. Fiorio JL, López N, Rossi LM (2017) Gold−Ligand-Catalyzed Selective Hydrogenation of
Alkynes into cis-Alkenes via H 2 Heterolytic Activation by Frustrated Lewis Pairs. ACS Catal
7:2973–2980. https://doi.org/10.1021/acscatal.6b03441
26. Bachmeier A, Esselborn J, Hexter SV, Krämer T, Klein K, Happe T, McGrady JE, Myers
WK, Armstrong FA (2015) How Formaldehyde Inhibits Hydrogen Evolution by [FeFe]Hydrogenases: Determination by 13 C ENDOR of Direct Fe–C Coordination and Order of
Electron and Proton Transfers. J Am Chem Soc 137:5381–5389. https://doi.org/10.1021/ja5
13074m
27. Brooke EJ, Evans RM, Islam STA, Roberts GM, Wehlin SAM, Carr SB, Phillips SEV,
Armstrong FA (2017) Importance of the Active Site Canopy. Residues in an O 2 -Tolerant
[NiFe]-Hydrogenase. Biochemistry 56:132–142. https://doi.org/10.1021/acs.biochem.6b0
0868
28. Kalz KF, Brinkmeier A, Dechert S, Mata RA, Meyer F (2014) Functional Model for the [Fe]
Hydrogenase Inspired by the Frustrated Lewis Pair Concept. J Am Chem Soc 136:16626–
16634. https://doi.org/10.1021/ja509186d
29. Schindler T, Lux M, Peters M, Scharf LT, Osseili H, Maron L, Tauchert ME (2015)
Synthesis and Reactivity of Palladium Complexes Featuring a Diphosphinoborane Ligand.
Organometallics 34:1978–1984. https://doi.org/10.1021/acs.organomet.5b00217
30. Cowie BE, Emslie DJH (2014) Platinum Complexes of a Borane-Appended Analogue of
1,1’- Bis(diphenylphosphino)ferrocene: Flexible Borane Coordination Modes and in situ
Vinylborane Formation. Chem Eur J 20:16899–16912. https://doi.org/10.1002/chem.201
404846
31. Frank N, Hanau K, Langer R (2014) Metal−Ligand Cooperation in H 2 Activation with
Iron Complexes Bearing Hemilabile Bis(diphenylphosphino)amine Ligands. Inorg Chem
53:11335–11343. https://doi.org/10.1021/ic5022164
32. Devillard M, Bouhadir G, Bourissou D (2015) Cooperation Between Transition Metals and
Lewis Acids: A Way to Activate H 2 and H-E Bonds. Angew Chem Int Ed 54:730–732. https://
doi.org/10.1002/anie.201410781
349
18. Erker G (2011) Organometallic Frustrated Lewis Pair Chemistry. Dalton Trans 40:7475–7483.
https://doi.org/10.1039/C1DT10152H
19. Bouhadir G, Bourissou D (2016) Complexes of Ambiphilic Ligands: Reactivity and Catalytic
Applications. Chem Soc Rev 45:1065–1079. https://doi.org/10.1039/C5CS00697J
20. Bullock RM, Chambers GM (2017) Frustration Across the Periodic Table: Heterolytic
Cleavage of Dihydrogen by Metal Complexes. Phil Trans R Soc a 375:20170002. https://
doi.org/10.1098/rsta.2017.0002
21. Whited MT (2012) Metal–Ligand Multiple Bonds as Frustrated Lewis Pairs for C-H
Functionalization. Beilstein J Org Chem 8:1554–1563. https://doi.org/10.3762/bjoc.8.177
22. Arndt S, Rudolph M, Hashmi ASK (2017) Gold-Based Frustrated Lewis Acid/Base Pairs
(FLPs). Gold Bull 50:267–282. https://doi.org/10.1007/s13404-017-0219-7
23. Lu G, Zhang P, Sun D, Wang L, Zhou K, Wang Z-X, Guo G-C (2014) Gold Catalyzed
Hydrogenations of Small Imines and Nitriles: Enhanced Reactivity of Au Surface Toward H 2
via Collaboration with a Lewis Base. Chem Sci 5:1082–1090. https://doi.org/10.1039/C3S
C52851K
24. Zhao X, Wang J, Yang M, Lei N, Li L, Hou B, Miao S, Pan X, Wang A, Zhang T (2017)
Selective Hydrogenolysis of Glycerol to 1,3-propanediol: Manipulating the Frustrated Lewis
Pairs by Introducing Gold to Pt/WOx. Chemsuschem 10:819–824. https://doi.org/10.1002/
cssc.201601503
25. Fiorio JL, López N, Rossi LM (2017) Gold−Ligand-Catalyzed Selective Hydrogenation of
Alkynes into cis-Alkenes via H 2 Heterolytic Activation by Frustrated Lewis Pairs. ACS Catal
7:2973–2980. https://doi.org/10.1021/acscatal.6b03441
26. Bachmeier A, Esselborn J, Hexter SV, Krämer T, Klein K, Happe T, McGrady JE, Myers
WK, Armstrong FA (2015) How Formaldehyde Inhibits Hydrogen Evolution by [FeFe]Hydrogenases: Determination by 13 C ENDOR of Direct Fe–C Coordination and Order of
Electron and Proton Transfers. J Am Chem Soc 137:5381–5389. https://doi.org/10.1021/ja5
13074m
27. Brooke EJ, Evans RM, Islam STA, Roberts GM, Wehlin SAM, Carr SB, Phillips SEV,
Armstrong FA (2017) Importance of the Active Site Canopy. Residues in an O 2 -Tolerant
[NiFe]-Hydrogenase. Biochemistry 56:132–142. https://doi.org/10.1021/acs.biochem.6b0
0868
28. Kalz KF, Brinkmeier A, Dechert S, Mata RA, Meyer F (2014) Functional Model for the [Fe]
Hydrogenase Inspired by the Frustrated Lewis Pair Concept. J Am Chem Soc 136:16626–
16634. https://doi.org/10.1021/ja509186d
29. Schindler T, Lux M, Peters M, Scharf LT, Osseili H, Maron L, Tauchert ME (2015)
Synthesis and Reactivity of Palladium Complexes Featuring a Diphosphinoborane Ligand.
Organometallics 34:1978–1984. https://doi.org/10.1021/acs.organomet.5b00217
30. Cowie BE, Emslie DJH (2014) Platinum Complexes of a Borane-Appended Analogue of
1,1’- Bis(diphenylphosphino)ferrocene: Flexible Borane Coordination Modes and in situ
Vinylborane Formation. Chem Eur J 20:16899–16912. https://doi.org/10.1002/chem.201
404846
31. Frank N, Hanau K, Langer R (2014) Metal−Ligand Cooperation in H 2 Activation with
Iron Complexes Bearing Hemilabile Bis(diphenylphosphino)amine Ligands. Inorg Chem
53:11335–11343. https://doi.org/10.1021/ic5022164
32. Devillard M, Bouhadir G, Bourissou D (2015) Cooperation Between Transition Metals and
Lewis Acids: A Way to Activate H 2 and H-E Bonds. Angew Chem Int Ed 54:730–732. https://
doi.org/10.1002/anie.201410781