348
N. Hidalgo et al.
References
1. Welch GC, San Juan RR, Masuda JD, Stephan DW (2006) Reversible Metal-Free Hydrogen
Activation. Science 314:1124–1128. https://doi.org/10.1126/science.1134230
2. Spikes GH, Fettinger JC, Power PP (2005) Facile Activation of Dihydrogen by an Unsaturated
Heavier Main Group Compound. J Am Chem Soc 127:12232–12233. https://doi.org/10.1021/
ja053247a
3. Frey GD, Lavallo B, Donnadieu B, Schoeller WW, Bertrand G (2007) Facile Splitting of
Hydrogen and Ammonia by Nucleophilic Activation at a Single Carbon Center. Science
316:439–441. https://doi.org/10.1126/science.1141474
4. Power PP (2010) Main-Group Elements as Transition Metals. Nature 463:171–177. https://
doi.org/10.1038/nature08634
5. Chatt J, Duncanson LA (1953) Olefin Coordination Compounds. Part III. Infrared Spectra and
Structure: Attempted Preparation of Acetylene Complexes. J Chem Soc 2939–2947. https://
doi.org/10.1039/jr9530002939
6. Peng Y, Brynda M, Ellis BD, Fettinger JC, Rivarda E, Power PP (2008) Addition to H 2
to Distannynes Under Ambient Conditions. Chem Commun 6042–6044. https://doi.org/10.
1039/B813442A
7. Stephan DW (2012) "Frustrated Lewis Pair" Hydrogenations. Org Biomol Chem 10:5740–
5746. https://doi.org/10.1039/c2ob25339a
8. Scott DJ, Fuchter MJ, Ashley AE (2017) Designing Effective ‘Frustrated Lewis Pair’
Hydrogenation Catalysts. Chem Soc Rev 46:5689–5700. https://doi.org/10.1039/C7CS00
154A
9. Chapman AM, Haddow MF, Wass DF (2011) Frustrated Lewis pairs Beyond the Main Group:
Cationic Zirconocene-Phosphinoaryloxide Complexes and Their Application in Catalytic
Dehydrogenation of Amine Boranes. J Am Chem Soc 133:8826–8829. https://doi.org/10.
1021/ja201989c
10. Chapman AM, Haddow MF, Wass DF (2011) Frustrated Lewis Pairs Beyond the Main
Group: Synthesis, Reactivity, and Small Molecule Activation with Cationic Zirconocene–
Phosphinoaryloxide Complexes. J Am Chem Soc 133:18463–18478. https://doi.org/10.1021/
ja207936p
11. Chapman AM, Haddow MF and Wass DF (2012) Cationic Group 4 Metallocene–(OPhosphanylaryl)oxido Complexes: Synthetic Routes to Transition-Metal Frustrated Lewis
Pairs. Eur J Inorg Chem 1546−1554. https://doi.org/10.1002/ejic.201100968
12. Xu X, Fr˝ ohlich R, Daniliuc CG, Kehr G, Erker G (2012) Reactions of a Methylzirconocene
Cation with Phosphinoalkynes: An Alternative Pathway for Generating Cp 2 Zr(II) Systems.
Chem Commun 48:6109−6111. https://doi.org/10.1039/C2CC31883K
13. Xu X, Kehr G, Daniliuc CG, Kehr G, Erker G (2013) Reactions of a Cationic Geminal
Zr + /P Pair with Small Molecules. J Am Chem Soc 135:6465–6476. https://doi.org/10.1021/
ja3110076
14. Wass DF, Chapman AM (2013) Frustrated Lewis Pairs Beyond the Main Group: Transition
Metal-Containing Systems. In: Erker G, Stephan D (eds) Frustrated Lewis Pairs II. Topics
in Current Chemistry. Springer, Berlin, Heidelberg, p 261−280. https://doi.org/10.1007/128_
2012_395
15. Flynn SR, Wass DF (2013) Transition Metal Frustrated Lewis Pairs. ACS Catal 3:2574–2581.
https://doi.org/10.1021/cs400754w
16. Lambic NS, Sommer RD, Ison EA (2016) Transition-Metal Oxos as the Lewis Basic Component of Frustrated Lewis Pairs. J Am Chem Soc 138:4832–4842. https://doi.org/10.1021/jacs.
6b00705
17. Zwettler N, Walg SP, Belaj F, Mösch-Zanetti NC (2018) Heterolytic Si-H Bond Cleavage at a
Molybdenum-Oxido-Based Lewis Pair. Chem Eur J 24:7149–7160. https://doi.org/10.1002/
chem.201800226
N. Hidalgo et al.
References
1. Welch GC, San Juan RR, Masuda JD, Stephan DW (2006) Reversible Metal-Free Hydrogen
Activation. Science 314:1124–1128. https://doi.org/10.1126/science.1134230
2. Spikes GH, Fettinger JC, Power PP (2005) Facile Activation of Dihydrogen by an Unsaturated
Heavier Main Group Compound. J Am Chem Soc 127:12232–12233. https://doi.org/10.1021/
ja053247a
3. Frey GD, Lavallo B, Donnadieu B, Schoeller WW, Bertrand G (2007) Facile Splitting of
Hydrogen and Ammonia by Nucleophilic Activation at a Single Carbon Center. Science
316:439–441. https://doi.org/10.1126/science.1141474
4. Power PP (2010) Main-Group Elements as Transition Metals. Nature 463:171–177. https://
doi.org/10.1038/nature08634
5. Chatt J, Duncanson LA (1953) Olefin Coordination Compounds. Part III. Infrared Spectra and
Structure: Attempted Preparation of Acetylene Complexes. J Chem Soc 2939–2947. https://
doi.org/10.1039/jr9530002939
6. Peng Y, Brynda M, Ellis BD, Fettinger JC, Rivarda E, Power PP (2008) Addition to H 2
to Distannynes Under Ambient Conditions. Chem Commun 6042–6044. https://doi.org/10.
1039/B813442A
7. Stephan DW (2012) "Frustrated Lewis Pair" Hydrogenations. Org Biomol Chem 10:5740–
5746. https://doi.org/10.1039/c2ob25339a
8. Scott DJ, Fuchter MJ, Ashley AE (2017) Designing Effective ‘Frustrated Lewis Pair’
Hydrogenation Catalysts. Chem Soc Rev 46:5689–5700. https://doi.org/10.1039/C7CS00
154A
9. Chapman AM, Haddow MF, Wass DF (2011) Frustrated Lewis pairs Beyond the Main Group:
Cationic Zirconocene-Phosphinoaryloxide Complexes and Their Application in Catalytic
Dehydrogenation of Amine Boranes. J Am Chem Soc 133:8826–8829. https://doi.org/10.
1021/ja201989c
10. Chapman AM, Haddow MF, Wass DF (2011) Frustrated Lewis Pairs Beyond the Main
Group: Synthesis, Reactivity, and Small Molecule Activation with Cationic Zirconocene–
Phosphinoaryloxide Complexes. J Am Chem Soc 133:18463–18478. https://doi.org/10.1021/
ja207936p
11. Chapman AM, Haddow MF and Wass DF (2012) Cationic Group 4 Metallocene–(OPhosphanylaryl)oxido Complexes: Synthetic Routes to Transition-Metal Frustrated Lewis
Pairs. Eur J Inorg Chem 1546−1554. https://doi.org/10.1002/ejic.201100968
12. Xu X, Fr˝ ohlich R, Daniliuc CG, Kehr G, Erker G (2012) Reactions of a Methylzirconocene
Cation with Phosphinoalkynes: An Alternative Pathway for Generating Cp 2 Zr(II) Systems.
Chem Commun 48:6109−6111. https://doi.org/10.1039/C2CC31883K
13. Xu X, Kehr G, Daniliuc CG, Kehr G, Erker G (2013) Reactions of a Cationic Geminal
Zr + /P Pair with Small Molecules. J Am Chem Soc 135:6465–6476. https://doi.org/10.1021/
ja3110076
14. Wass DF, Chapman AM (2013) Frustrated Lewis Pairs Beyond the Main Group: Transition
Metal-Containing Systems. In: Erker G, Stephan D (eds) Frustrated Lewis Pairs II. Topics
in Current Chemistry. Springer, Berlin, Heidelberg, p 261−280. https://doi.org/10.1007/128_
2012_395
15. Flynn SR, Wass DF (2013) Transition Metal Frustrated Lewis Pairs. ACS Catal 3:2574–2581.
https://doi.org/10.1021/cs400754w
16. Lambic NS, Sommer RD, Ison EA (2016) Transition-Metal Oxos as the Lewis Basic Component of Frustrated Lewis Pairs. J Am Chem Soc 138:4832–4842. https://doi.org/10.1021/jacs.
6b00705
17. Zwettler N, Walg SP, Belaj F, Mösch-Zanetti NC (2018) Heterolytic Si-H Bond Cleavage at a
Molybdenum-Oxido-Based Lewis Pair. Chem Eur J 24:7149–7160. https://doi.org/10.1002/
chem.201800226