9 Frustrated Lewis Pairs Based on Transition Metals
351
50. Xu X, Kehr G, Daniliuc CG, Erker G (2013) 1,1-Carbozirconation: Unusual Reaction of
an Alkyne with a Methyl Zirconocene Cation and Subsequent Frustrated Lewis Pair Like
Reactivity. Angew Chem Int Ed 52:13629–13632. https://doi.org/10.1002/anie.201307493
51. Xu X, Kehr G, Daniliuc CG, Erker G (2013) Reactions of (Diphenylphosphinomethyl)Zirconocene Chloride with B(C 6 F 5 ) 3 : Competition Between P/B and P/Zr + Frustrated Lewis Pair Reactions. Organometallics 32:7306–7311. https://doi.org/10.1021/om4
00769y
52. Mo Z, Rit A, Campos J, Kolychev EL, Aldridge S (2016) Catalytic B-N Dehydrogenation
Using Frustrated Lewis Pairs: Evidence for a Chain-Growth Coupling Mechanism. J Am
Chem Soc 138:3306–3309. https://doi.org/10.1021/jacs.6b01170
53. Mo Z, Kolychev EL, Rit A, Campos J, Aldridge S (2015) Facile Reversibility by Design:
Tuning Small Molecule Capture and Activation by Single Component Frustrated Lewis Pairs.
J Am Chem Soc 137:12227–12230. https://doi.org/10.1021/jacs.5b08614
54. Ma G, Song G, Li ZH (2018) Designing Metal-Free Frustrated Lewis Pairs Catalyst for the
Efficient Dehydrogenation of Ammonia Borane. Chem Eur J 24:13238–13245. https://doi.
org/10.1002/chem.201801932
55. Boudjelel M, Sosa Carrizo ED, Mallet-Ladeira S, Massou S, Miqueu K, Bouhadir G,
Bourissou D (2018) Catalytic Dehydrogenation of (Di)amine-Boranes with a Geometrically
Constrained Phosphine-Borane Lewis Pair. ACS Catal 8:4459–4464. https://doi.org/10.1021/
acscatal.8b00152
56. Metters OJ, Flynn SR, Dowds CK, Sparkes HA, Manners I, Wass DF (2016) Catalytic Dehydrocoupling of Amine−Boranes Using Cationic Zirconium(IV)−Phosphine Frustrated Lewis
Pairs. ACS Catal 6:6601–6611. https://doi.org/10.1021/acscatal.6b02211
57. Treichel PM, Johnson JW, Wagner KP (1975) Electrochemical Oxidations of Various
Indenyl-Iron Complexes. J Organomet Chem 88:227–230. https://doi.org/10.1016/S0022-328
X(00)91464-5
58. Habib A, Tanke RS, Holt EM, Crabtree RH (1989) Ring Slip in Associative Reactions of Some
Indenyl and Phenylcyclopentadienyl Iridium Complexes. Organometallics 8:1225–1231.
https://doi.org/10.1021/om00107a016
59. Liu Y, Kehr G, Daniliuc CG, Erker G (2017) Utilizing the TEMPO Radical in Zirconocene
Cation and Hydrido Zirconocene Chemistry. Organometallics 36:3407–3414. https://doi.org/
10.1021/acs.organomet.7b00558
60. Budzelaar PHM, Hughes DL, Bochmann M, Macchionic A, Rocchigiani L (2020) H 2 Activation by Zirconaziridinium Ions: σ-Bond Metathesis Versus Frustrated Lewis Pairs Reactivity.
Chem Commun, Accepted Manuscript,. https://doi.org/10.1039/C9CC09466K
61. Xu X, Kehr G, Daniliuc CG, Erker G (2015) Frustrated Lewis Pair Behavior of
[Cp 2 ZrOCR 2 CH 2 PPh 2 ]+ Cations. Organometallics 34:2655–2661. https://doi.org/10.1021/
om501312a
62. Jian Z, Daniliuc CG, Kehr G, Erker G (2017) Frustrated Lewis Pair vs Metal−Carbon σBond Insertion Chemistry at an O-Phenylene-Bridged Cp 2 Zr + /PPh 2 System. Organometallics
36:424–434. https://doi.org/10.1021/acs.organomet.6b00828
63. Normand AT, Daniliuc CG, Wibbeling B, Kehr G, Le Gendre P, Erker G (2016) Insertion
Reactions of Neutral Phosphidozirconocene Complexes as a Convenient Entry into Frustrated
Lewis Pair Territory. Chem Eur J 22:4285–4293. https://doi.org/10.1002/chem.201504792
64. Metters OJ, Forrest SJK, Sparkes HA, Manners I, Wass DF (2016) Small Molecule Activation
by Intermolecular Zr(IV)-Phosphine Frustrated Lewis Pairs. J Am Chem Soc 138:1994–2003.
https://doi.org/10.1021/jacs.5b12536
65. Rocchigiani L, Ciancaleoni G, Zuccaccia C, Macchioni A (2014) Probing the Association of
Frustrated Phosphine−Borane Lewis Pairs in Solution by NMR Spectroscopy. J Am Chem
Soc 136:112–115. https://doi.org/10.1021/ja4119169
66. Flynn SR, Metters OJ, Manners I, Wass DF (2016) Zirconium-Catalyzed Imine Hydrogenation
Via a Frustrated Lewis Pair Mechanism. Organometallics 35:847–850. https://doi.org/10.
1021/acs.organomet.6b00027
351
50. Xu X, Kehr G, Daniliuc CG, Erker G (2013) 1,1-Carbozirconation: Unusual Reaction of
an Alkyne with a Methyl Zirconocene Cation and Subsequent Frustrated Lewis Pair Like
Reactivity. Angew Chem Int Ed 52:13629–13632. https://doi.org/10.1002/anie.201307493
51. Xu X, Kehr G, Daniliuc CG, Erker G (2013) Reactions of (Diphenylphosphinomethyl)Zirconocene Chloride with B(C 6 F 5 ) 3 : Competition Between P/B and P/Zr + Frustrated Lewis Pair Reactions. Organometallics 32:7306–7311. https://doi.org/10.1021/om4
00769y
52. Mo Z, Rit A, Campos J, Kolychev EL, Aldridge S (2016) Catalytic B-N Dehydrogenation
Using Frustrated Lewis Pairs: Evidence for a Chain-Growth Coupling Mechanism. J Am
Chem Soc 138:3306–3309. https://doi.org/10.1021/jacs.6b01170
53. Mo Z, Kolychev EL, Rit A, Campos J, Aldridge S (2015) Facile Reversibility by Design:
Tuning Small Molecule Capture and Activation by Single Component Frustrated Lewis Pairs.
J Am Chem Soc 137:12227–12230. https://doi.org/10.1021/jacs.5b08614
54. Ma G, Song G, Li ZH (2018) Designing Metal-Free Frustrated Lewis Pairs Catalyst for the
Efficient Dehydrogenation of Ammonia Borane. Chem Eur J 24:13238–13245. https://doi.
org/10.1002/chem.201801932
55. Boudjelel M, Sosa Carrizo ED, Mallet-Ladeira S, Massou S, Miqueu K, Bouhadir G,
Bourissou D (2018) Catalytic Dehydrogenation of (Di)amine-Boranes with a Geometrically
Constrained Phosphine-Borane Lewis Pair. ACS Catal 8:4459–4464. https://doi.org/10.1021/
acscatal.8b00152
56. Metters OJ, Flynn SR, Dowds CK, Sparkes HA, Manners I, Wass DF (2016) Catalytic Dehydrocoupling of Amine−Boranes Using Cationic Zirconium(IV)−Phosphine Frustrated Lewis
Pairs. ACS Catal 6:6601–6611. https://doi.org/10.1021/acscatal.6b02211
57. Treichel PM, Johnson JW, Wagner KP (1975) Electrochemical Oxidations of Various
Indenyl-Iron Complexes. J Organomet Chem 88:227–230. https://doi.org/10.1016/S0022-328
X(00)91464-5
58. Habib A, Tanke RS, Holt EM, Crabtree RH (1989) Ring Slip in Associative Reactions of Some
Indenyl and Phenylcyclopentadienyl Iridium Complexes. Organometallics 8:1225–1231.
https://doi.org/10.1021/om00107a016
59. Liu Y, Kehr G, Daniliuc CG, Erker G (2017) Utilizing the TEMPO Radical in Zirconocene
Cation and Hydrido Zirconocene Chemistry. Organometallics 36:3407–3414. https://doi.org/
10.1021/acs.organomet.7b00558
60. Budzelaar PHM, Hughes DL, Bochmann M, Macchionic A, Rocchigiani L (2020) H 2 Activation by Zirconaziridinium Ions: σ-Bond Metathesis Versus Frustrated Lewis Pairs Reactivity.
Chem Commun, Accepted Manuscript,. https://doi.org/10.1039/C9CC09466K
61. Xu X, Kehr G, Daniliuc CG, Erker G (2015) Frustrated Lewis Pair Behavior of
[Cp 2 ZrOCR 2 CH 2 PPh 2 ]+ Cations. Organometallics 34:2655–2661. https://doi.org/10.1021/
om501312a
62. Jian Z, Daniliuc CG, Kehr G, Erker G (2017) Frustrated Lewis Pair vs Metal−Carbon σBond Insertion Chemistry at an O-Phenylene-Bridged Cp 2 Zr + /PPh 2 System. Organometallics
36:424–434. https://doi.org/10.1021/acs.organomet.6b00828
63. Normand AT, Daniliuc CG, Wibbeling B, Kehr G, Le Gendre P, Erker G (2016) Insertion
Reactions of Neutral Phosphidozirconocene Complexes as a Convenient Entry into Frustrated
Lewis Pair Territory. Chem Eur J 22:4285–4293. https://doi.org/10.1002/chem.201504792
64. Metters OJ, Forrest SJK, Sparkes HA, Manners I, Wass DF (2016) Small Molecule Activation
by Intermolecular Zr(IV)-Phosphine Frustrated Lewis Pairs. J Am Chem Soc 138:1994–2003.
https://doi.org/10.1021/jacs.5b12536
65. Rocchigiani L, Ciancaleoni G, Zuccaccia C, Macchioni A (2014) Probing the Association of
Frustrated Phosphine−Borane Lewis Pairs in Solution by NMR Spectroscopy. J Am Chem
Soc 136:112–115. https://doi.org/10.1021/ja4119169
66. Flynn SR, Metters OJ, Manners I, Wass DF (2016) Zirconium-Catalyzed Imine Hydrogenation
Via a Frustrated Lewis Pair Mechanism. Organometallics 35:847–850. https://doi.org/10.
1021/acs.organomet.6b00027