7 Heterogeneous Catalysis by Frustrated Lewis Pairs
279
96. Wischert R, Laurent P, Copéret C, Delbecq F, Sautet P (2012) γ-Alumina: The Essential and
Unexpected Role of Water for the Structure, Stability, and Reactivity of “Defect” Sites. J Am
Chem Soc 134:14430–14449. https://doi.org/10.1021/ja3042383
97. Hoch LB, Wood TE, O’Brien PG, Liao K, Reyes LM, Mims CA, Ozin GA (2014) The Rational
Design of a Single-Component Photocatalyst for Gas-Phase CO 2 Reduction Using Both UV
and Visible Light. Adv Sci 1:1400013. https://doi.org/10.1002/advs.201400013
98. Ghuman KK, Wood TE, Hoch LB, Mims CA, Ozin GA, Singh CV (2015) Illuminating CO 2
Reduction on Frustrated Lewis Pair Surfaces: Investigating the Role of Surface Hydroxides
and Oxygen Vacancies on Nanocrystalline In 2 O 3−x (OH) y . Phys Chem Chem Phys 17:14623–
14635. https://doi.org/10.1039/C5CP02613J
99. Ghoussoub M, Yadav S, Ghuman KK, Ozin GA, Singh CV (2016) Metadynamics-Biased Ab
Initio Molecular Dynamics Study of Heterogeneous CO 2 Reduction via Surface Frustrated
Lewis Pairs. ACS Catal 6:7109–7117. https://doi.org/10.1021/acscatal.6b01545
100. Hoch LB, He L, Qiao Q, Liao K, Reyes LM, Zhu Y, Ozin GA (2016) Effect of Precursor
Selection on the Photocatalytic Performance of Indium Oxide Nanomaterials for Gas-Phase
CO 2 Reduction. Chem Mater 28:4160–4168. https://doi.org/10.1021/acs.chemmater.6b00301
101. Ghuman KK, Hoch LB, Szymanski P, Loh JYY, Kherani NP, El-Sayed MA, Ozin GA, Singh
CV (2016) Photoexcited Surface Frustrated Lewis Pairs for Heterogeneous Photocatalytic
CO 2 Reduction. J Am Chem Soc 138:1206–1214. https://doi.org/10.1021/jacs.5b10179
102. Hoch LB, Szymanski P, Ghuman KK, He L, Liao K, Qiao Q, Reyes LM, Zhu Y, El-Sayed MA,
Singh CV, Ozin GA (2016) Carrier Dynamics and the Role of Surface Defects: Designing a
Photocatalyst for Gas-Phase CO 2 Reduction. Proc Natl Acad Sci 113:E8011–E8020. https://
doi.org/10.1073/pnas.1609374113
103. He L, Wood TE, Wu B, Dong Y, Hoch LB, Reyes LM, Wang D, Kübel C, Qian C, Jia J, Liao
K, O’Brien PG, Sandhel A, Loh JYY, Szymanski P, Kherani NP, Sum TC, Mims CA, Ozin GA
(2016) Spatial Separation of Charge Carriers in In 2 O 3−x (OH) y Nanocrystal Superstructures
for Enhanced Gas-Phase Photocatalytic Activity. ACS Nano 10:5578–5586. https://doi.org/
10.1021/acsnano.6b02346
104. Dong Y, Ghuman KK, Popescu R, Duchesne PN, Zhou W, Loh JYY, Jelle AA, Jia J, Wang D,
Mu X, Kübel C, Wang L, He L, Ghoussoub M, Wang Q, Wood TE, Reyes LM, Zhang
P, Kherani NP, Singh CV, Ozin GA (2018) Tailoring Surface Frustrated Lewis Pairs of
In 2 O 3−x (OH) y for Gas-Phase Heterogeneous Photocatalytic Reduction of CO 2 by Isomorphous Substitution of In 3+ with Bi 3+ . Adv Sci 5:1700732. https://doi.org/10.1002/advs.201
700732
105. Wang L, Ghoussoub M, Wang H, Shao Y, Sun W, Tountas AA, Wood TE, Li H, Loh JYY,
Dong Y, Xia M, Li Y, Wang S, Jia J, Qiu C, Qian C, Kherani NP, He L, Zhang X, Ozin GA
(2018) Photocatalytic Hydrogenation of Carbon Dioxide With High Selectivity to Methanol
at Atmospheric Pressure. Joule 2:1369–1381. https://doi.org/10.1016/j.joule.2018.03.007
106. Wang L, Ghoussoub M, Wang H, Shao Y, Sun W, Tountas AA, Wood TE, Li H, Loh JYY,
Dong Y, Xia M, Li Y, Wang S, Jia J, Qiu C, Qian C, Kherani NP, He L, Zhang X, Ozin GA
(2018) Photocatalytic Hydrogenation of Carbon Dioxide with High Selectivity to Methanol
at Atmospheric Pressure. Joule 2:1382. https://doi.org/10.1016/j.joule.2018.04.013
107. Yan T, Wang L, Liang Y, Makaremi M, Wood TE, Dai Y, Huang B, Jelle AA, Dong Y, Ozin
GA (2019) Polymorph Selection Towards Photocatalytic Gaseous CO 2 Hydrogenation. Nat
Commun 10:1–10. https://doi.org/10.1038/s41467-019-10524-2
108. Wang L, Yan T, Song R, Sun W, Dong Y, Guo J, Zhang Z, Wang X, Ozin GA (2019)
Room-Temperature Activation of H 2 by a Surface Frustrated Lewis Pair. Angew Chem Int
Ed 58:9501–9505. https://doi.org/10.1002/anie.201904568
109. Zhang S, Huang Z-Q, Ma Y, Gao W, Li J, Cao F, Li L, Chang C-R, Qu Y (2017) Solid
Frustrated-Lewis-Pair Catalysts Constructed by Regulations on Surface Defects of Porous
Nanorods of CeO 2 . Nat Commun 8:15266. https://doi.org/10.1038/ncomms15266
110. Huang Z-Q, Liu L-P, Qi S, Zhang S, Qu Y, Chang C-R (2018) Understanding All-Solid
Frustrated-Lewis-Pair Sites on CeO 2 from Theoretical Perspectives. ACS Catal 8:546–554.
https://doi.org/10.1021/acscatal.7b02732
279
96. Wischert R, Laurent P, Copéret C, Delbecq F, Sautet P (2012) γ-Alumina: The Essential and
Unexpected Role of Water for the Structure, Stability, and Reactivity of “Defect” Sites. J Am
Chem Soc 134:14430–14449. https://doi.org/10.1021/ja3042383
97. Hoch LB, Wood TE, O’Brien PG, Liao K, Reyes LM, Mims CA, Ozin GA (2014) The Rational
Design of a Single-Component Photocatalyst for Gas-Phase CO 2 Reduction Using Both UV
and Visible Light. Adv Sci 1:1400013. https://doi.org/10.1002/advs.201400013
98. Ghuman KK, Wood TE, Hoch LB, Mims CA, Ozin GA, Singh CV (2015) Illuminating CO 2
Reduction on Frustrated Lewis Pair Surfaces: Investigating the Role of Surface Hydroxides
and Oxygen Vacancies on Nanocrystalline In 2 O 3−x (OH) y . Phys Chem Chem Phys 17:14623–
14635. https://doi.org/10.1039/C5CP02613J
99. Ghoussoub M, Yadav S, Ghuman KK, Ozin GA, Singh CV (2016) Metadynamics-Biased Ab
Initio Molecular Dynamics Study of Heterogeneous CO 2 Reduction via Surface Frustrated
Lewis Pairs. ACS Catal 6:7109–7117. https://doi.org/10.1021/acscatal.6b01545
100. Hoch LB, He L, Qiao Q, Liao K, Reyes LM, Zhu Y, Ozin GA (2016) Effect of Precursor
Selection on the Photocatalytic Performance of Indium Oxide Nanomaterials for Gas-Phase
CO 2 Reduction. Chem Mater 28:4160–4168. https://doi.org/10.1021/acs.chemmater.6b00301
101. Ghuman KK, Hoch LB, Szymanski P, Loh JYY, Kherani NP, El-Sayed MA, Ozin GA, Singh
CV (2016) Photoexcited Surface Frustrated Lewis Pairs for Heterogeneous Photocatalytic
CO 2 Reduction. J Am Chem Soc 138:1206–1214. https://doi.org/10.1021/jacs.5b10179
102. Hoch LB, Szymanski P, Ghuman KK, He L, Liao K, Qiao Q, Reyes LM, Zhu Y, El-Sayed MA,
Singh CV, Ozin GA (2016) Carrier Dynamics and the Role of Surface Defects: Designing a
Photocatalyst for Gas-Phase CO 2 Reduction. Proc Natl Acad Sci 113:E8011–E8020. https://
doi.org/10.1073/pnas.1609374113
103. He L, Wood TE, Wu B, Dong Y, Hoch LB, Reyes LM, Wang D, Kübel C, Qian C, Jia J, Liao
K, O’Brien PG, Sandhel A, Loh JYY, Szymanski P, Kherani NP, Sum TC, Mims CA, Ozin GA
(2016) Spatial Separation of Charge Carriers in In 2 O 3−x (OH) y Nanocrystal Superstructures
for Enhanced Gas-Phase Photocatalytic Activity. ACS Nano 10:5578–5586. https://doi.org/
10.1021/acsnano.6b02346
104. Dong Y, Ghuman KK, Popescu R, Duchesne PN, Zhou W, Loh JYY, Jelle AA, Jia J, Wang D,
Mu X, Kübel C, Wang L, He L, Ghoussoub M, Wang Q, Wood TE, Reyes LM, Zhang
P, Kherani NP, Singh CV, Ozin GA (2018) Tailoring Surface Frustrated Lewis Pairs of
In 2 O 3−x (OH) y for Gas-Phase Heterogeneous Photocatalytic Reduction of CO 2 by Isomorphous Substitution of In 3+ with Bi 3+ . Adv Sci 5:1700732. https://doi.org/10.1002/advs.201
700732
105. Wang L, Ghoussoub M, Wang H, Shao Y, Sun W, Tountas AA, Wood TE, Li H, Loh JYY,
Dong Y, Xia M, Li Y, Wang S, Jia J, Qiu C, Qian C, Kherani NP, He L, Zhang X, Ozin GA
(2018) Photocatalytic Hydrogenation of Carbon Dioxide With High Selectivity to Methanol
at Atmospheric Pressure. Joule 2:1369–1381. https://doi.org/10.1016/j.joule.2018.03.007
106. Wang L, Ghoussoub M, Wang H, Shao Y, Sun W, Tountas AA, Wood TE, Li H, Loh JYY,
Dong Y, Xia M, Li Y, Wang S, Jia J, Qiu C, Qian C, Kherani NP, He L, Zhang X, Ozin GA
(2018) Photocatalytic Hydrogenation of Carbon Dioxide with High Selectivity to Methanol
at Atmospheric Pressure. Joule 2:1382. https://doi.org/10.1016/j.joule.2018.04.013
107. Yan T, Wang L, Liang Y, Makaremi M, Wood TE, Dai Y, Huang B, Jelle AA, Dong Y, Ozin
GA (2019) Polymorph Selection Towards Photocatalytic Gaseous CO 2 Hydrogenation. Nat
Commun 10:1–10. https://doi.org/10.1038/s41467-019-10524-2
108. Wang L, Yan T, Song R, Sun W, Dong Y, Guo J, Zhang Z, Wang X, Ozin GA (2019)
Room-Temperature Activation of H 2 by a Surface Frustrated Lewis Pair. Angew Chem Int
Ed 58:9501–9505. https://doi.org/10.1002/anie.201904568
109. Zhang S, Huang Z-Q, Ma Y, Gao W, Li J, Cao F, Li L, Chang C-R, Qu Y (2017) Solid
Frustrated-Lewis-Pair Catalysts Constructed by Regulations on Surface Defects of Porous
Nanorods of CeO 2 . Nat Commun 8:15266. https://doi.org/10.1038/ncomms15266
110. Huang Z-Q, Liu L-P, Qi S, Zhang S, Qu Y, Chang C-R (2018) Understanding All-Solid
Frustrated-Lewis-Pair Sites on CeO 2 from Theoretical Perspectives. ACS Catal 8:546–554.
https://doi.org/10.1021/acscatal.7b02732