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112. Zhang S, Xia Z, Zou Y, Cao F, Liu Y, Ma Y, Qu Y (2019) Interfacial Frustrated Lewis Pairs
of CeO 2 Activate CO 2 for Selective Tandem Transformation of Olefins and CO 2 into Cyclic
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114. Wang J, Zhao X, Lei N, Li L, Zhang L, Xu S, Miao S, Pan X, Wang A, Zhang T (2016)
Hydrogenolysis of Glycerol to 1,3-Propanediol Under Low Hydrogen Pressure over WO x -
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org/10.1002/cssc.201501506
115. Zhao X, Wang J, Yang M, Lei N, Li L, Hou B, Miao S, Pan X, Wang A, Zhang T (2017)
Selective Hydrogenolysis of Glycerol to 1,3-Propanediol: Manipulating the Frustrated Lewis
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116. Su DS, Perathoner S, Centi G (2013) Nanocarbons for the Development of Advanced
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117. Primo A, Neatu F, Florea M, Parvulescu V, Garcia H (2014) Graphenes in the Absence of
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118. Trandafir M-M, Florea M, Nea¸ tu F, Primo A, Parvulescu VI, García H (2016) Graphene
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121. Sastre G, Forneli A, Almasan V, Parvulescu VI, Garcia H (2017) Isotopic H/D Exchange on
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Hydrogenation Promoted by Frustrated Lewis Acid-Base Pairs in Carbon Quantum Dots. J
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123. Liao C, Liu B, Chi Q, Zhang Z (2018) Nitrogen-Doped Carbon Materials for the Metal-Free
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org/10.1021/acsami.8b15300
124. Li B, Sun X, Su D (2015) Calibration of the Basic Strength of the Nitrogen Groups on the
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1039/C4CP05765A
125. Abakumov AA, Bychko IB, Nikolenko AS, Strizhak PE (2018) Catalytic Activity of N-Doped
Reduced Graphene Oxide in the Hydrogenation of Ethylene and Acetylene. Theor Exp Chem
54:218–224. https://doi.org/10.1007/s11237-018-9566-6
126. Chen X, Shen Q, Li Z, Wan W, Chen J, Zhang J (2020) Metal-Free H 2 Activation for Highly
Selective Hydrogenation of Nitroaromatics Using Phosphorus-Doped Carbon Nanotubes.
ACS Appl Mater Interfaces 12:654–666. https://doi.org/10.1021/acsami.9b17582
127. Sun X, Li B, Liu T, Song J, Su DS (2016) Designing Graphene as a New Frustrated Lewis Pair
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128. Ding Y, Huang X, Yi X, Qiao Y, Sun X, Zheng A, Su DS (2018) A Heterogeneous Metal-Free
Catalyst for Hydrogenation: Lewis Acid-Base Pairs Integrated Into a Carbon Lattice. Angew
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A. R. Jupp
111. Huang Z-Q, Zhang T, Chang C-R, Li J (2019) Dynamic Frustrated Lewis Pairs on Ceria for
Direct Nonoxidative Coupling of Methane. ACS Catal 9:5523–5536. https://doi.org/10.1021/
acscatal.9b00838
112. Zhang S, Xia Z, Zou Y, Cao F, Liu Y, Ma Y, Qu Y (2019) Interfacial Frustrated Lewis Pairs
of CeO 2 Activate CO 2 for Selective Tandem Transformation of Olefins and CO 2 into Cyclic
Carbonates. J Am Chem Soc 141:11353–11357. https://doi.org/10.1021/jacs.9b03217
113. Zhang S, Huang Z-Q, Chen X, Gan J, Duan X, Yang B, Chang C-R, Qu Y (2019) Hydrogen
Activation Enabled by the Interfacial Frustrated Lewis Pairs on Cobalt Borate Nanosheets. J
Catal 372:142–150. https://doi.org/10.1016/j.jcat.2019.02.033
114. Wang J, Zhao X, Lei N, Li L, Zhang L, Xu S, Miao S, Pan X, Wang A, Zhang T (2016)
Hydrogenolysis of Glycerol to 1,3-Propanediol Under Low Hydrogen Pressure over WO x -
Supported Single/Pseudo-Single Atom Pt Catalyst. ChemSusChem 9:784–790. https://doi.
org/10.1002/cssc.201501506
115. Zhao X, Wang J, Yang M, Lei N, Li L, Hou B, Miao S, Pan X, Wang A, Zhang T (2017)
Selective Hydrogenolysis of Glycerol to 1,3-Propanediol: Manipulating the Frustrated Lewis
Pairs by Introducing Gold to Pt/WO x . ChemSusChem 10:819–824. https://doi.org/10.1002/
cssc.201601503
116. Su DS, Perathoner S, Centi G (2013) Nanocarbons for the Development of Advanced
Catalysts. Chem Rev 113:5782–5816. https://doi.org/10.1021/cr300367d
117. Primo A, Neatu F, Florea M, Parvulescu V, Garcia H (2014) Graphenes in the Absence of
Metals as Carbocatalysts for Selective Acetylene Hydrogenation and Alkene Hydrogenation.
Nat Commun 5:5291. https://doi.org/10.1038/ncomms6291
118. Trandafir M-M, Florea M, Nea¸ tu F, Primo A, Parvulescu VI, García H (2016) Graphene
from Alginate Pyrolysis as a Metal-Free Catalyst for Hydrogenation of Nitro Compounds.
ChemSusChem 9:1565–1569. https://doi.org/10.1002/cssc.201600197
119. Patel M, Savaram K, Li Q, Buchspies J, Ma N, Szostak M, He H (2018) Carbon-Based,
Metal-Free Catalysts for Chemical Catalysis. In: Carbon-Based Metal-Free Catalysts. John
Wiley & Sons, Ltd, pp 597–657
120. Navalon S, Dhakshinamoorthy A, Alvaro M, Antonietti M, García H (2017) Active Sites on
Graphene-Based Materials as Metal-Free Catalysts. Chem Soc Rev 46:4501–4529. https://
doi.org/10.1039/C7CS00156H
121. Sastre G, Forneli A, Almasan V, Parvulescu VI, Garcia H (2017) Isotopic H/D Exchange on
Graphenes. A Combined Experimental and Theoretical Study. Appl Catal Gen 547:52–59.
https://doi.org/10.1016/j.apcata.2017.08.018
122. Wang B, Liu G, Deng X, Deng Z, Lin W, Li Z (2020) Replacement of Pd Nanoparticles:
Hydrogenation Promoted by Frustrated Lewis Acid-Base Pairs in Carbon Quantum Dots. J
Catal 383:304–310. https://doi.org/10.1016/j.jcat.2020.01.021
123. Liao C, Liu B, Chi Q, Zhang Z (2018) Nitrogen-Doped Carbon Materials for the Metal-Free
Reduction of Nitro Compounds. ACS Appl Mater Interfaces 10:44421–44429. https://doi.
org/10.1021/acsami.8b15300
124. Li B, Sun X, Su D (2015) Calibration of the Basic Strength of the Nitrogen Groups on the
Nanostructured Carbon Materials. Phys Chem Chem Phys 17:6691–6694. https://doi.org/10.
1039/C4CP05765A
125. Abakumov AA, Bychko IB, Nikolenko AS, Strizhak PE (2018) Catalytic Activity of N-Doped
Reduced Graphene Oxide in the Hydrogenation of Ethylene and Acetylene. Theor Exp Chem
54:218–224. https://doi.org/10.1007/s11237-018-9566-6
126. Chen X, Shen Q, Li Z, Wan W, Chen J, Zhang J (2020) Metal-Free H 2 Activation for Highly
Selective Hydrogenation of Nitroaromatics Using Phosphorus-Doped Carbon Nanotubes.
ACS Appl Mater Interfaces 12:654–666. https://doi.org/10.1021/acsami.9b17582
127. Sun X, Li B, Liu T, Song J, Su DS (2016) Designing Graphene as a New Frustrated Lewis Pair
Catalyst for Hydrogen Activation by Co-doping. Phys Chem Chem Phys 18:11120–11124.
https://doi.org/10.1039/C5CP07969A
128. Ding Y, Huang X, Yi X, Qiao Y, Sun X, Zheng A, Su DS (2018) A Heterogeneous Metal-Free
Catalyst for Hydrogenation: Lewis Acid-Base Pairs Integrated Into a Carbon Lattice. Angew
Chem Int Ed 57:13800–13804. https://doi.org/10.1002/anie.201803977