278
A. R. Jupp
78. Niu Z, Zhang W, Lan PC, Aguila B, Ma S (2019) Promoting Frustrated Lewis Pairs for
Heterogeneous Chemoselective Hydrogenation via the Tailored Pore Environment Within
Metal-Organic Frameworks. Angew Chem Int Ed 58:7420–7424. https://doi.org/10.1002/
anie.201903763
79. Shyshkanov S, Nguyen TN, Ebrahim FM, Stylianou KC, Dyson PJ (2019) In Situ Formation of
Frustrated Lewis Pairs in a Water-Tolerant Metal-Organic Framework for the Transformation
of CO 2 . Angew Chem Int Ed 58:5371–5375. https://doi.org/10.1002/anie.201901171
80. Zhang Z, Sun Q, Xia C, Sun W (2016) CO 2 as a C1 Source: B(C 6 F 5 ) 3 -Catalyzed Cyclization
of o-Phenylene-diamines to Construct Benzimidazoles in the Presence of Hydrosilane. Org
Lett 18:6316–6319. https://doi.org/10.1021/acs.orglett.6b03030
81. Shyshkanov S, Nguyen TN, Chidambaram A, Stylianou KC, Dyson PJ (2019) Frustrated
Lewis Pair-Mediated Fixation of CO 2 Within a Metal–Organic Framework. Chem Commun
55:10964–10967. https://doi.org/10.1039/C9CC04374H
82. Ashley AE, Thompson AL, O’Hare D (2009) Non-Metal-Mediated Homogeneous Hydrogenation of CO 2 to CH 3 OH. Angew Chem Int Ed 48:9839–9843. https://doi.org/10.1002/
anie.200905466
83. Zakharova MV, Masoumifard N, Hu Y, Han J, Kleitz F, Fontaine F-G (2018) Designed
Synthesis of Mesoporous Solid-Supported Lewis Acid-Base Pairs and Their CO 2 Adsorption
Behaviors. ACS Appl Mater Interfaces 10:13199–13210. https://doi.org/10.1021/acsami.8b0
0640
84. Zakharova MV, Kleitz F, Fontaine F-G (2017) Lewis Acidity Quantification and Catalytic
Activity of Ti, Zr and Al-Supported Mesoporous Silica. Dalton Trans 46:3864–3876. https://
doi.org/10.1039/C7DT00035A
85. Zhan Z, Manninger I, Paal Z, Barthomeuf D (1994) Reactions of n-Hexane over Pt-Zeolite
Catalysts of Different Acidity. J Catal 147:333–341. https://doi.org/10.1006/jcat.1994.1144
86. Thybaut JW, Narasimhan CSL, Marin GB, Denayer JFM, Baron GV, Jacobs PA, Martens JA
(2004) Alkylcarbenium Ion Concentrations in Zeolite Pores During Octane Hydrocracking
on Pt/H-USY Zeolite. Catal Lett 94:81–88. https://doi.org/10.1023/B:CATL.0000019335.483
50.24
87. Lee H, Choi YN, Lim D-W, Rahman MM, Kim Y-I, Cho IH, Kang HW, Seo J-H, Jeon C,
Yoon KB (2015) Formation of Frustrated Lewis Pairs in Pt x -Loaded Zeolite NaY. Angew
Chem Int Ed 54:13080–13084. https://doi.org/10.1002/anie.201506790
88. Long D-L, Tsunashima R, Cronin L (2010) Polyoxometalates: Building Blocks for Functional
Nanoscale Systems. Angew Chem Int Ed 49:1736–1758. https://doi.org/10.1002/anie.200
902483
89. Gumerova NI, Rompel A (2018) Synthesis, Structures and Applications of Electron-Rich
Polyoxometalates. Nat Rev Chem 2:1–20. https://doi.org/10.1038/s41570-018-0112
90. Chen W-P, Sang R-L, Wang Y, Xu L (2013) An Unprecedented [Mo IV 3 O 4 ]-Incorporated
Polyoxometalate Concomitant with MoO 2 Nucleophilic Addition. Chem Commun 49:5883–
5885. https://doi.org/10.1039/C3CC41954A
91. Xu X, Luo B, Wang L-L, Xu L (2018) An Unprecedented Nanocage-Like and Heterometallic
[Mo IV 3 O 4 ]-Polyoxomolybdate Hybrid. Dalton Trans 47:3218–3222. https://doi.org/10.1039/
C7DT04309K
92. Luo B, Sang R, Lin L, Xu L (2019) Mo IV 3 -Polyoxomolybdates with Frustrated Lewis Pairs
for High-Performance Hydrogenation Catalysis. Catal Sci Technol 9:65–69. https://doi.org/
10.1039/C8CY01771A
93. Luo B, Xu L (2019) POM-FLPs: [Mo IV 3 ] n -polyoxometalate Bifunctional Catalysis by
[Mo IV 3 ] n –O m Lewis Pairs Frustrated by Triangular Mo IV –Mo IV Bonds. Dalton Trans
48:6892–6898. https://doi.org/10.1039/C9DT00983C
94. Yu F, Xu L (2019) Highly Efficient Mo IV 3 ···Sb III Cluster Frustrated Lewis Pair Hydrogenation.
Dalton Trans 48:17445–17450. https://doi.org/10.1039/C9DT04138A
95. Wischert R, Copéret C, Delbecq F, Sautet P (2011) Optimal Water Coverage on Alumina: a
Key to Generate Lewis Acid-Base Pairs That are Reactive Towards the C-H Bond Activation
of Methane. Angew Chem Int Ed 50:3202–3205. https://doi.org/10.1002/anie.201006794
A. R. Jupp
78. Niu Z, Zhang W, Lan PC, Aguila B, Ma S (2019) Promoting Frustrated Lewis Pairs for
Heterogeneous Chemoselective Hydrogenation via the Tailored Pore Environment Within
Metal-Organic Frameworks. Angew Chem Int Ed 58:7420–7424. https://doi.org/10.1002/
anie.201903763
79. Shyshkanov S, Nguyen TN, Ebrahim FM, Stylianou KC, Dyson PJ (2019) In Situ Formation of
Frustrated Lewis Pairs in a Water-Tolerant Metal-Organic Framework for the Transformation
of CO 2 . Angew Chem Int Ed 58:5371–5375. https://doi.org/10.1002/anie.201901171
80. Zhang Z, Sun Q, Xia C, Sun W (2016) CO 2 as a C1 Source: B(C 6 F 5 ) 3 -Catalyzed Cyclization
of o-Phenylene-diamines to Construct Benzimidazoles in the Presence of Hydrosilane. Org
Lett 18:6316–6319. https://doi.org/10.1021/acs.orglett.6b03030
81. Shyshkanov S, Nguyen TN, Chidambaram A, Stylianou KC, Dyson PJ (2019) Frustrated
Lewis Pair-Mediated Fixation of CO 2 Within a Metal–Organic Framework. Chem Commun
55:10964–10967. https://doi.org/10.1039/C9CC04374H
82. Ashley AE, Thompson AL, O’Hare D (2009) Non-Metal-Mediated Homogeneous Hydrogenation of CO 2 to CH 3 OH. Angew Chem Int Ed 48:9839–9843. https://doi.org/10.1002/
anie.200905466
83. Zakharova MV, Masoumifard N, Hu Y, Han J, Kleitz F, Fontaine F-G (2018) Designed
Synthesis of Mesoporous Solid-Supported Lewis Acid-Base Pairs and Their CO 2 Adsorption
Behaviors. ACS Appl Mater Interfaces 10:13199–13210. https://doi.org/10.1021/acsami.8b0
0640
84. Zakharova MV, Kleitz F, Fontaine F-G (2017) Lewis Acidity Quantification and Catalytic
Activity of Ti, Zr and Al-Supported Mesoporous Silica. Dalton Trans 46:3864–3876. https://
doi.org/10.1039/C7DT00035A
85. Zhan Z, Manninger I, Paal Z, Barthomeuf D (1994) Reactions of n-Hexane over Pt-Zeolite
Catalysts of Different Acidity. J Catal 147:333–341. https://doi.org/10.1006/jcat.1994.1144
86. Thybaut JW, Narasimhan CSL, Marin GB, Denayer JFM, Baron GV, Jacobs PA, Martens JA
(2004) Alkylcarbenium Ion Concentrations in Zeolite Pores During Octane Hydrocracking
on Pt/H-USY Zeolite. Catal Lett 94:81–88. https://doi.org/10.1023/B:CATL.0000019335.483
50.24
87. Lee H, Choi YN, Lim D-W, Rahman MM, Kim Y-I, Cho IH, Kang HW, Seo J-H, Jeon C,
Yoon KB (2015) Formation of Frustrated Lewis Pairs in Pt x -Loaded Zeolite NaY. Angew
Chem Int Ed 54:13080–13084. https://doi.org/10.1002/anie.201506790
88. Long D-L, Tsunashima R, Cronin L (2010) Polyoxometalates: Building Blocks for Functional
Nanoscale Systems. Angew Chem Int Ed 49:1736–1758. https://doi.org/10.1002/anie.200
902483
89. Gumerova NI, Rompel A (2018) Synthesis, Structures and Applications of Electron-Rich
Polyoxometalates. Nat Rev Chem 2:1–20. https://doi.org/10.1038/s41570-018-0112
90. Chen W-P, Sang R-L, Wang Y, Xu L (2013) An Unprecedented [Mo IV 3 O 4 ]-Incorporated
Polyoxometalate Concomitant with MoO 2 Nucleophilic Addition. Chem Commun 49:5883–
5885. https://doi.org/10.1039/C3CC41954A
91. Xu X, Luo B, Wang L-L, Xu L (2018) An Unprecedented Nanocage-Like and Heterometallic
[Mo IV 3 O 4 ]-Polyoxomolybdate Hybrid. Dalton Trans 47:3218–3222. https://doi.org/10.1039/
C7DT04309K
92. Luo B, Sang R, Lin L, Xu L (2019) Mo IV 3 -Polyoxomolybdates with Frustrated Lewis Pairs
for High-Performance Hydrogenation Catalysis. Catal Sci Technol 9:65–69. https://doi.org/
10.1039/C8CY01771A
93. Luo B, Xu L (2019) POM-FLPs: [Mo IV 3 ] n -polyoxometalate Bifunctional Catalysis by
[Mo IV 3 ] n –O m Lewis Pairs Frustrated by Triangular Mo IV –Mo IV Bonds. Dalton Trans
48:6892–6898. https://doi.org/10.1039/C9DT00983C
94. Yu F, Xu L (2019) Highly Efficient Mo IV 3 ···Sb III Cluster Frustrated Lewis Pair Hydrogenation.
Dalton Trans 48:17445–17450. https://doi.org/10.1039/C9DT04138A
95. Wischert R, Copéret C, Delbecq F, Sautet P (2011) Optimal Water Coverage on Alumina: a
Key to Generate Lewis Acid-Base Pairs That are Reactive Towards the C-H Bond Activation
of Methane. Angew Chem Int Ed 50:3202–3205. https://doi.org/10.1002/anie.201006794