106
T. Wang et al.
References
1. Aubke F, Wang C (1994) Carbon Monoxide as a σ-Donor Ligand in Coordination Chemistry. Coord Chem Rev 137:483–524. https://doi.org/10.1016/0010-8545(94)03010-N and
references cited therein
2. Mingos DMP (2001) A Historical Perspective on Dewar’s Landmark Contribution to
Organometallic Chemistry. J Organomet Chem 635:1–8. https://doi.org/10.1016/S0022-328
X(01)01155-X
3. Dewar MJS (1951) A Review of π Complex Theory. Bull Soc Chim Fr 18:C71–C79
4. Chatt J, Duncanson, LA (1953) Olefin Co-ordination Compounds. Part III. Infra-red Spectra
and Structure: Attempted Preparation of Acetylene Complexes. J Chem Soc 0:2939–2947.
https://doi.org/10.1039/JR9530002939
5. Fischer EO, Maasböl A (1964) On the Existence of a Tungsten Carbonyl Carbene Complex.
Angew Chem Int Ed Engl 3:580–581. https://doi.org/10.1002/anie.196405801
6. Welch GC, San Juan RR, Masuda JD, Stephan DW (2006) Reversible, Metal-Free Hydrogen
Activation. Science 314(5802):1124–1126. https://doi.org/10.1126/science.1134230
7. Welch GC, Stephan DW (2007) Facile Heterolytic Cleavage of Dihydrogen by Phosphines
and Boranes. J Am Chem Soc 129(7):1880–1881. https://doi.org/10.1021/ja067961j
8. Spies P, Erker G, Kehr G, Bergander K, Fröhlich R, Grimme S, Stephan DW (2007)
Rapid Intramolecular Heterolytic Dihydrogen Activation by a Four-Membered Heterocyclic Phosphane–Borane Adduct. Chem Commun 43:5072–5074. https://doi.org/10.1039/
B710475H
9. Stephan DW, Erker G (2010) Frustrated Lewis pairs: Metal-Free Hydrogen Activation and
More. Angew Chem Int Ed 49:46–76. https://doi.org/10.1002/anie.200903708
10. Erker G, Stephan DW (2013) Frustrated Lewis Pairs I: Uncovering and Understanding. Top
Curr Chem Springer, Heidelberg, vol 332
11. Erker G, Stephan DW (2013) Frustrated Lewis Pairs II: Expanding the Scope. Top Curr Chem
Springer, Heidelberg, vol 334
12. Flynn SR, Wass DF (2013) Transition Metal Frustrated Lewis Pairs. ACS Catal 3:2574–2581.
https://doi.org/10.1021/cs400754w
13. Stephan DW, Erker G (2015) Frustrated Lewis Pair Chemistry: Development and Perspectives.
Angew Chem Int Ed 54:6400–6441. https://doi.org/10.1002/anie.201409800
14. Stephan DW, Erker G (2014) Frustrated Lewis pair Chemistry of Carbon, Nitrogen and Sulfur
Oxides. Chem Sci 5:2625–2641. https://doi.org/10.1039/C4SC00395K
15. Stephan DW (2015) Frustrated Lewis Pairs: From Concept to Catalysis. Acc Chem Res
48:306–316. https://doi.org/10.1021/ar500375j
16. Stephan DW (2015) Frustrated Lewis Pairs. J Am Chem Soc 137:10018–10032. https://doi.
org/10.1021/jacs.5b06794
17. Stephan DW (2016) The Broadening Reach of Frustrated Lewis Pair Chemistry. Science
354:aaf7229. https://doi.org/10.1126/science.aaf7229
18. Cardenas AJP, Hasegawa Y, Kehr G, Warren TH, Erker G (2016) Cooperative 1,1-Addition
Reactions of Vicinal Phosphane/Borane Frustrated Lewis Pairs. Coord Chem Rev 306:468–
482. https://doi.org/10.1016/j.ccr.2015.01.006
19. Kehr G, Erker G (2017) Frustrated Lewis Pair Chemistry: Searching for New Reactions. Chem
Rec 17:803–815. https://doi.org/10.1002/tcr.201700010
20. Fontaine F-G, Boudreau J, Thibault M-H (2008) Coordination Chemistry of Neutral (L n )–Z
Amphoteric and Ambiphilic Ligands. Eur J Inorg Chem 5439–5454. https://doi.org/10.1002/
ejic.200800784
21. Bouhadir G, Bourissou D (2016) Complexes of Ambiphilic Ligands: Reactivity and Catalytic
Applications. Chem Soc Rev 45:1065–1079. https://doi.org/10.1039/C5CS00697J
22. Devillard M, Declercq R, Nicolas E, Ehlers AW, Backs J, Saffon-Merceron N, Bouhadir G,
Slootweg JC, Uhl W, Bourissou D (2017) A Significant but Constrained Geometry Pt → Al
Interaction: Fixation of CO 2 and CS 2 , Activation of H 2 and PhCONH 2 . J Am Chem Soc
138:4917–4926. https://doi.org/10.1021/jacs.6b01320
T. Wang et al.
References
1. Aubke F, Wang C (1994) Carbon Monoxide as a σ-Donor Ligand in Coordination Chemistry. Coord Chem Rev 137:483–524. https://doi.org/10.1016/0010-8545(94)03010-N and
references cited therein
2. Mingos DMP (2001) A Historical Perspective on Dewar’s Landmark Contribution to
Organometallic Chemistry. J Organomet Chem 635:1–8. https://doi.org/10.1016/S0022-328
X(01)01155-X
3. Dewar MJS (1951) A Review of π Complex Theory. Bull Soc Chim Fr 18:C71–C79
4. Chatt J, Duncanson, LA (1953) Olefin Co-ordination Compounds. Part III. Infra-red Spectra
and Structure: Attempted Preparation of Acetylene Complexes. J Chem Soc 0:2939–2947.
https://doi.org/10.1039/JR9530002939
5. Fischer EO, Maasböl A (1964) On the Existence of a Tungsten Carbonyl Carbene Complex.
Angew Chem Int Ed Engl 3:580–581. https://doi.org/10.1002/anie.196405801
6. Welch GC, San Juan RR, Masuda JD, Stephan DW (2006) Reversible, Metal-Free Hydrogen
Activation. Science 314(5802):1124–1126. https://doi.org/10.1126/science.1134230
7. Welch GC, Stephan DW (2007) Facile Heterolytic Cleavage of Dihydrogen by Phosphines
and Boranes. J Am Chem Soc 129(7):1880–1881. https://doi.org/10.1021/ja067961j
8. Spies P, Erker G, Kehr G, Bergander K, Fröhlich R, Grimme S, Stephan DW (2007)
Rapid Intramolecular Heterolytic Dihydrogen Activation by a Four-Membered Heterocyclic Phosphane–Borane Adduct. Chem Commun 43:5072–5074. https://doi.org/10.1039/
B710475H
9. Stephan DW, Erker G (2010) Frustrated Lewis pairs: Metal-Free Hydrogen Activation and
More. Angew Chem Int Ed 49:46–76. https://doi.org/10.1002/anie.200903708
10. Erker G, Stephan DW (2013) Frustrated Lewis Pairs I: Uncovering and Understanding. Top
Curr Chem Springer, Heidelberg, vol 332
11. Erker G, Stephan DW (2013) Frustrated Lewis Pairs II: Expanding the Scope. Top Curr Chem
Springer, Heidelberg, vol 334
12. Flynn SR, Wass DF (2013) Transition Metal Frustrated Lewis Pairs. ACS Catal 3:2574–2581.
https://doi.org/10.1021/cs400754w
13. Stephan DW, Erker G (2015) Frustrated Lewis Pair Chemistry: Development and Perspectives.
Angew Chem Int Ed 54:6400–6441. https://doi.org/10.1002/anie.201409800
14. Stephan DW, Erker G (2014) Frustrated Lewis pair Chemistry of Carbon, Nitrogen and Sulfur
Oxides. Chem Sci 5:2625–2641. https://doi.org/10.1039/C4SC00395K
15. Stephan DW (2015) Frustrated Lewis Pairs: From Concept to Catalysis. Acc Chem Res
48:306–316. https://doi.org/10.1021/ar500375j
16. Stephan DW (2015) Frustrated Lewis Pairs. J Am Chem Soc 137:10018–10032. https://doi.
org/10.1021/jacs.5b06794
17. Stephan DW (2016) The Broadening Reach of Frustrated Lewis Pair Chemistry. Science
354:aaf7229. https://doi.org/10.1126/science.aaf7229
18. Cardenas AJP, Hasegawa Y, Kehr G, Warren TH, Erker G (2016) Cooperative 1,1-Addition
Reactions of Vicinal Phosphane/Borane Frustrated Lewis Pairs. Coord Chem Rev 306:468–
482. https://doi.org/10.1016/j.ccr.2015.01.006
19. Kehr G, Erker G (2017) Frustrated Lewis Pair Chemistry: Searching for New Reactions. Chem
Rec 17:803–815. https://doi.org/10.1002/tcr.201700010
20. Fontaine F-G, Boudreau J, Thibault M-H (2008) Coordination Chemistry of Neutral (L n )–Z
Amphoteric and Ambiphilic Ligands. Eur J Inorg Chem 5439–5454. https://doi.org/10.1002/
ejic.200800784
21. Bouhadir G, Bourissou D (2016) Complexes of Ambiphilic Ligands: Reactivity and Catalytic
Applications. Chem Soc Rev 45:1065–1079. https://doi.org/10.1039/C5CS00697J
22. Devillard M, Declercq R, Nicolas E, Ehlers AW, Backs J, Saffon-Merceron N, Bouhadir G,
Slootweg JC, Uhl W, Bourissou D (2017) A Significant but Constrained Geometry Pt → Al
Interaction: Fixation of CO 2 and CS 2 , Activation of H 2 and PhCONH 2 . J Am Chem Soc
138:4917–4926. https://doi.org/10.1021/jacs.6b01320