3 FLP Reduction of Carbon Monoxide and Related Reactions
107
23. Grimme S, Kruse H, Goerigk L, Erker G (2010) The Mechanism of Dihydrogen Activation
by Frustrated Lewis Pairs Revisited. Angew Chem Int Ed 49:1402–1405. https://doi.org/10.
1002/anie.200905484
24. Özgün T, Ye K-Y, Daniliuc CG, Wibbeling B, Liu L, Grimme S, Kehr G, Erker
G (2016) Why Does the Intramolecular Trimethylene-Bridged Frustrated Lewis Pair
Mes 2 PCH 2 CH 2 CH 2 B(C 6 F 5 ) 2 Not Activate Dihydrogen? Chem Eur J 22:5988–5995. https://
doi.org/10.1002/chem.201505200
25. Özgün T, Bergander K, Liu L, Daniliuc CG, Grimme S, Kehr G, Erker G (2016) A Frustrated
Phosphane-Borane Lewis Pair and Hydrogen: A Kinetics Study. Chem Eur J 22:11958–
11961. https://doi.org/10.1002/chem.201603050
26. Ekkert O, González Miera G, Wiegand T, Eckert H, Schirmer B, Petersen JL, Daniliuc
CG, Fröhlich R, Grimme S, Kehr G, Erker G (2013) Remarkable Coordination Behavior
of Alkyl Isocyanides Toward Unsaturated Vicinal Frustrated P/B Lewis Pairs. Chem Sci
4:2657–2664. https://doi.org/10.1039/C3SC00082F
27. Wrackmeyer B (1995) 1,1-Organoboration of Alkynylsilicon, -Germanium, -Tin and -Lead
Compounds. Coord Chem Rev 145:125–156. https://doi.org/10.1016/0010-8545(95)90220-1
28. Wrackmeyer B (2006) Metallacyclopentadienes and Related Heterocycles via 1,1Organoboration of Alkyn-1-ylmetal Compounds. Heteroat Chem 17:188–208. https://doi.
org/10.1002/hc.20222
29. Kehr G, Erker G (2012) 1,1-Carboboration. Chem Commun 48:1839–1850. https://doi.org/
10.1039/C1CC15628D
30. Kehr G, Erker G (2016) Advanced 1,1-Carboboration Reactions with Pentafluorophenylboranes. Chem Sci 7:56–65. https://doi.org/10.1039/C5SC03282B
31. Sajid M, Lawzer A, Dong W, Rosorius C, Sander W, Schirmer B, Grimme S, Daniliuc CG,
Kehr G, Erker G (2013) Carbonylation Reactions of Intramolecular Vicinal Frustrated Phosphane/Borane Lewis Pairs. J Am Chem Soc 135:18567–18574. https://doi.org/10.1021/ja4
08815k
32. Elmer L-M, Kehr G, Daniliuc CG, Siedow M, Eckert H, Tesch M, Studer A, Williams
K, Warren TH, Erker G (2017) The Chemistry of a Non-Interacting Vicinal Frustrated
Phosphane/Borane Lewis Pair. Chem Eur J 23:6056–6068. https://doi.org/10.1002/chem.201
603954
33. Dureen MA, Stephan DW (2010) Reactions of Boron Amidinates with CO 2 and CO and Other
Small Molecules. J Am Chem Soc 132:13559–13568. https://doi.org/10.1021/ja1064153
34. Cabrera AR, Rojas RS, Valderrama M, Plüss P, Berke H, Daniliuc CG, Kehr G, Erker G
(2013) Synthesis of New Asymmetric Substituted Boron Amidines - Reactions with CO and
Transfer Hydrogenations of Phenylacetylene. Dalton Trans 44:19606–19614. https://doi.org/
10.1039/C5DT01966D
35. Ríos-Gutiérrez M, Domingo LR, Rojas RS, Toro-Labbé A, Pérez P (2019) A Molecular Electron Density Theory Study of the Insertion of CO into Frustrated Lewis Pair Boronamidines:
a [4 + 1] Cycloaddition Reaction. Dalton Trans 48:9214–9224. https://doi.org/10.1039/C9D
T01489F
36. Ueno A, Tao X, Daniliuc CG, Kehr G, Erker G (2018) Unusual 1,1-Hydroboration Route
to a Reactive Unsaturated Vicinal Frustrated Phosphane/Borane Lewis Pair. Organometallics
37:2665–2668. https://doi.org/10.1021/acs.organomet.8b00481. Correction: Ueno A, Yu J,
Tao X, Daniliuc CG, Kehr G, Erker G (2019) Organometallics 38:2699. https://doi.org/10.
1021/acs.organomet.9b00395
37. Parks DJ, Spence REvH, Piers WE (1995) Bis(pentafluorophenyl)borane: Synthesis, Properties, and Hydroboration Chemistry of a Highly Electrophilic Borane Reagent. Angew Chem
Int Ed Engl 34:809–811. https://doi.org/10.1002/anie.199508091
38. Piers WE, Chivers T (1997) Pentafluorophenylboranes: From Obscurity to Applications.
Chem Soc Rev 26(5):345–354. https://doi.org/10.1039/CS9972600345
39. Piers WE (2004) The Chemistry of Perfluoroaryl Boranes. Adv Organomet Chem 52:1–
76. https://doi.org/10.1016/S0065-3055(04)52001-4
107
23. Grimme S, Kruse H, Goerigk L, Erker G (2010) The Mechanism of Dihydrogen Activation
by Frustrated Lewis Pairs Revisited. Angew Chem Int Ed 49:1402–1405. https://doi.org/10.
1002/anie.200905484
24. Özgün T, Ye K-Y, Daniliuc CG, Wibbeling B, Liu L, Grimme S, Kehr G, Erker
G (2016) Why Does the Intramolecular Trimethylene-Bridged Frustrated Lewis Pair
Mes 2 PCH 2 CH 2 CH 2 B(C 6 F 5 ) 2 Not Activate Dihydrogen? Chem Eur J 22:5988–5995. https://
doi.org/10.1002/chem.201505200
25. Özgün T, Bergander K, Liu L, Daniliuc CG, Grimme S, Kehr G, Erker G (2016) A Frustrated
Phosphane-Borane Lewis Pair and Hydrogen: A Kinetics Study. Chem Eur J 22:11958–
11961. https://doi.org/10.1002/chem.201603050
26. Ekkert O, González Miera G, Wiegand T, Eckert H, Schirmer B, Petersen JL, Daniliuc
CG, Fröhlich R, Grimme S, Kehr G, Erker G (2013) Remarkable Coordination Behavior
of Alkyl Isocyanides Toward Unsaturated Vicinal Frustrated P/B Lewis Pairs. Chem Sci
4:2657–2664. https://doi.org/10.1039/C3SC00082F
27. Wrackmeyer B (1995) 1,1-Organoboration of Alkynylsilicon, -Germanium, -Tin and -Lead
Compounds. Coord Chem Rev 145:125–156. https://doi.org/10.1016/0010-8545(95)90220-1
28. Wrackmeyer B (2006) Metallacyclopentadienes and Related Heterocycles via 1,1Organoboration of Alkyn-1-ylmetal Compounds. Heteroat Chem 17:188–208. https://doi.
org/10.1002/hc.20222
29. Kehr G, Erker G (2012) 1,1-Carboboration. Chem Commun 48:1839–1850. https://doi.org/
10.1039/C1CC15628D
30. Kehr G, Erker G (2016) Advanced 1,1-Carboboration Reactions with Pentafluorophenylboranes. Chem Sci 7:56–65. https://doi.org/10.1039/C5SC03282B
31. Sajid M, Lawzer A, Dong W, Rosorius C, Sander W, Schirmer B, Grimme S, Daniliuc CG,
Kehr G, Erker G (2013) Carbonylation Reactions of Intramolecular Vicinal Frustrated Phosphane/Borane Lewis Pairs. J Am Chem Soc 135:18567–18574. https://doi.org/10.1021/ja4
08815k
32. Elmer L-M, Kehr G, Daniliuc CG, Siedow M, Eckert H, Tesch M, Studer A, Williams
K, Warren TH, Erker G (2017) The Chemistry of a Non-Interacting Vicinal Frustrated
Phosphane/Borane Lewis Pair. Chem Eur J 23:6056–6068. https://doi.org/10.1002/chem.201
603954
33. Dureen MA, Stephan DW (2010) Reactions of Boron Amidinates with CO 2 and CO and Other
Small Molecules. J Am Chem Soc 132:13559–13568. https://doi.org/10.1021/ja1064153
34. Cabrera AR, Rojas RS, Valderrama M, Plüss P, Berke H, Daniliuc CG, Kehr G, Erker G
(2013) Synthesis of New Asymmetric Substituted Boron Amidines - Reactions with CO and
Transfer Hydrogenations of Phenylacetylene. Dalton Trans 44:19606–19614. https://doi.org/
10.1039/C5DT01966D
35. Ríos-Gutiérrez M, Domingo LR, Rojas RS, Toro-Labbé A, Pérez P (2019) A Molecular Electron Density Theory Study of the Insertion of CO into Frustrated Lewis Pair Boronamidines:
a [4 + 1] Cycloaddition Reaction. Dalton Trans 48:9214–9224. https://doi.org/10.1039/C9D
T01489F
36. Ueno A, Tao X, Daniliuc CG, Kehr G, Erker G (2018) Unusual 1,1-Hydroboration Route
to a Reactive Unsaturated Vicinal Frustrated Phosphane/Borane Lewis Pair. Organometallics
37:2665–2668. https://doi.org/10.1021/acs.organomet.8b00481. Correction: Ueno A, Yu J,
Tao X, Daniliuc CG, Kehr G, Erker G (2019) Organometallics 38:2699. https://doi.org/10.
1021/acs.organomet.9b00395
37. Parks DJ, Spence REvH, Piers WE (1995) Bis(pentafluorophenyl)borane: Synthesis, Properties, and Hydroboration Chemistry of a Highly Electrophilic Borane Reagent. Angew Chem
Int Ed Engl 34:809–811. https://doi.org/10.1002/anie.199508091
38. Piers WE, Chivers T (1997) Pentafluorophenylboranes: From Obscurity to Applications.
Chem Soc Rev 26(5):345–354. https://doi.org/10.1039/CS9972600345
39. Piers WE (2004) The Chemistry of Perfluoroaryl Boranes. Adv Organomet Chem 52:1–
76. https://doi.org/10.1016/S0065-3055(04)52001-4