212
S. Luo et al.
63. Xie S, Choi S, Lu N et al (2014) Atomic layer-by-layer deposition of Pt on Pd nanocubes
for catalysts with enhanced activity and durability toward oxygen reduction. Nano Lett
14(6):3570–3576
64. Yang P, Somorjai GA, Radmilovic V et al (2007) Shaping binary metal nanocrystals through
epitaxial seeded growth. Nat Mater 6(9):692–697
65. Peng X (2003) Mechanisms for the shape-control and shape-evolution of colloidal semiconductor nanocrystals. Adv Mater 15(5):459–463
66. Choi S, Shao M, Lu N et al (2014) Synthesis and characterization of Pd@Pt-Ni core-shell
octahedra with high activity toward oxygen reduction. ACS Nano 8(10):10363–10371
67. Niu Z, Wang D, Yu R et al (2012) Highly branched Pt-Ni nanocrystals enclosed by stepped
surface for methanol oxidation. Chem Sci 3(6):1925
68. Van der Vliet DF, Wang C, Tripkovic D et al (2012) Mesostructured thin films as electrocatalysts with tunable composition and surface morphology. Nat Mater 11(12):1051–1058
69. Debe MK, Steinbach ZAJ, Vernstrom GD et al (2011) Extraordinary oxygen reduction activity
of Pt 3 Ni 7 . J Electrochem Soc 158(8):B910–B918
70. Bang JH, Suslick KS (2010) Applications of ultrasound to the synthesis of nanostructured
materials. Adv Mater 22(10):1039–1059
71. Nagao D, Shimazaki Y, Saeki S et al (2007) Effect of ultrasonic irradiation on carbonsupported Pt-Ru nanoparticles prepared at high metal concentration. Colloids Surf A
302(1–3):623–627
72. Guo Z, Chen Y, Li L et al (2010) Carbon nanotube-supported Pt-based bimetallic catalysts
prepared by a microwave-assisted polyol reduction method and their catalytic applications in
the selective hydrogenation. J Catal 276(2):314–326
73. Song S, Wang Y, Shen PK (2007) Pulse-microwave assisted polyol synthesis of highly
dispersed high loading Pt/C electrocatalyst for oxygen reduction reaction. J Power Sources
170(1):46–49
74. Han B, Carlton CE, Kongkanand A et al (2015) Record activity and stability of dealloyed
bimetallic catalysts for proton exchange membrane fuel cells. Energy Environ Sci 8(1):258–
266
75. Zhao Z, Liu H, Gao W et al (2018) Surface-engineered PtNi-O nanostructure with record-high
performance for electrocatalytic hydrogen evolution reaction. J Am Chem Soc 140(29):9046–
9050
76. Wang Y, Long W, Wang L et al (2018) Unlocking the door to highly active ORR catalysts
for PEMFC applications: polyhedron-engineered Pt-based nanocrystals. Energy Environ Sci
11(2):258–275
77. Ge J, Li Z, Hong X et al (2019) Surface atomic regulation of core-shell noble metal catalysts.
Chem A Eur J 25(20):5113–5127
78. Zheng Y, Zeng J, Ruditskiy A et al (2013) Oxidative etching and its role in manipulating the
nucleation and growth of noble-metal nanocrystals. Chem Mater 26(1):22–33
79. Long R, Zhou S, Wiley BJ et al (2014) Oxidative etching for controlled synthesis of metal
nanocrystals: atomic addition and subtraction. Chem Soc Rev 43(17):6288–6310
80. Xiong Y, Chen J, Wiley B et al (2005) Understanding the role of oxidative etching in the polyol
synthesis of Pd nanoparticles with uniform shape and size. J Am Chem Soc 127(20):7332–
7333
81. Chen C, Kang Y, Huo Z et al (2014) Highly crystalline multimetallic nanoframes with threedimensional electrocatalytic surfaces. Science 343(6177):1339–1343
82. Ruditskiy A, Xia Y (2017) The science and art of carving metal nanocrystals. ACS Nano
11(1):23–27
83. Wang Y, Chen Y, Nan C et al (2015) Phase-transfer interface promoted corrosion from PtNi10
nanoctahedra to Pt 4 Ni nanoframes. Nano Res 8(1):140–155
84. Han S, Liu H, Chen P et al (2018) Porous trimetallic PtRhCu cubic nanoboxes for ethanol
electrooxidation. Adv Energy Mater 8(24):1801326
85. Wu Y, Wang D, Niu Z et al (2012) A strategy for designing a concave Pt-Ni alloy through
controllable chemical etching. Angew Chem Int Ed 51(50):12524–12528
S. Luo et al.
63. Xie S, Choi S, Lu N et al (2014) Atomic layer-by-layer deposition of Pt on Pd nanocubes
for catalysts with enhanced activity and durability toward oxygen reduction. Nano Lett
14(6):3570–3576
64. Yang P, Somorjai GA, Radmilovic V et al (2007) Shaping binary metal nanocrystals through
epitaxial seeded growth. Nat Mater 6(9):692–697
65. Peng X (2003) Mechanisms for the shape-control and shape-evolution of colloidal semiconductor nanocrystals. Adv Mater 15(5):459–463
66. Choi S, Shao M, Lu N et al (2014) Synthesis and characterization of Pd@Pt-Ni core-shell
octahedra with high activity toward oxygen reduction. ACS Nano 8(10):10363–10371
67. Niu Z, Wang D, Yu R et al (2012) Highly branched Pt-Ni nanocrystals enclosed by stepped
surface for methanol oxidation. Chem Sci 3(6):1925
68. Van der Vliet DF, Wang C, Tripkovic D et al (2012) Mesostructured thin films as electrocatalysts with tunable composition and surface morphology. Nat Mater 11(12):1051–1058
69. Debe MK, Steinbach ZAJ, Vernstrom GD et al (2011) Extraordinary oxygen reduction activity
of Pt 3 Ni 7 . J Electrochem Soc 158(8):B910–B918
70. Bang JH, Suslick KS (2010) Applications of ultrasound to the synthesis of nanostructured
materials. Adv Mater 22(10):1039–1059
71. Nagao D, Shimazaki Y, Saeki S et al (2007) Effect of ultrasonic irradiation on carbonsupported Pt-Ru nanoparticles prepared at high metal concentration. Colloids Surf A
302(1–3):623–627
72. Guo Z, Chen Y, Li L et al (2010) Carbon nanotube-supported Pt-based bimetallic catalysts
prepared by a microwave-assisted polyol reduction method and their catalytic applications in
the selective hydrogenation. J Catal 276(2):314–326
73. Song S, Wang Y, Shen PK (2007) Pulse-microwave assisted polyol synthesis of highly
dispersed high loading Pt/C electrocatalyst for oxygen reduction reaction. J Power Sources
170(1):46–49
74. Han B, Carlton CE, Kongkanand A et al (2015) Record activity and stability of dealloyed
bimetallic catalysts for proton exchange membrane fuel cells. Energy Environ Sci 8(1):258–
266
75. Zhao Z, Liu H, Gao W et al (2018) Surface-engineered PtNi-O nanostructure with record-high
performance for electrocatalytic hydrogen evolution reaction. J Am Chem Soc 140(29):9046–
9050
76. Wang Y, Long W, Wang L et al (2018) Unlocking the door to highly active ORR catalysts
for PEMFC applications: polyhedron-engineered Pt-based nanocrystals. Energy Environ Sci
11(2):258–275
77. Ge J, Li Z, Hong X et al (2019) Surface atomic regulation of core-shell noble metal catalysts.
Chem A Eur J 25(20):5113–5127
78. Zheng Y, Zeng J, Ruditskiy A et al (2013) Oxidative etching and its role in manipulating the
nucleation and growth of noble-metal nanocrystals. Chem Mater 26(1):22–33
79. Long R, Zhou S, Wiley BJ et al (2014) Oxidative etching for controlled synthesis of metal
nanocrystals: atomic addition and subtraction. Chem Soc Rev 43(17):6288–6310
80. Xiong Y, Chen J, Wiley B et al (2005) Understanding the role of oxidative etching in the polyol
synthesis of Pd nanoparticles with uniform shape and size. J Am Chem Soc 127(20):7332–
7333
81. Chen C, Kang Y, Huo Z et al (2014) Highly crystalline multimetallic nanoframes with threedimensional electrocatalytic surfaces. Science 343(6177):1339–1343
82. Ruditskiy A, Xia Y (2017) The science and art of carving metal nanocrystals. ACS Nano
11(1):23–27
83. Wang Y, Chen Y, Nan C et al (2015) Phase-transfer interface promoted corrosion from PtNi10
nanoctahedra to Pt 4 Ni nanoframes. Nano Res 8(1):140–155
84. Han S, Liu H, Chen P et al (2018) Porous trimetallic PtRhCu cubic nanoboxes for ethanol
electrooxidation. Adv Energy Mater 8(24):1801326
85. Wu Y, Wang D, Niu Z et al (2012) A strategy for designing a concave Pt-Ni alloy through
controllable chemical etching. Angew Chem Int Ed 51(50):12524–12528