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02.026
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la904907b
17. Sun YN, Gao GR, Du GL, Cheng YJ, Fu J (2014) Super tough, ultrastretchable, and
thermoresponsive hydrogels with functionalized triblock copolymer micelles as macro-crosslinkers. ACS Macro Lett 3(5):496–500. https://doi.org/10.1021/mz500221j
18. Wang P, Deng G, Zhou L, Li Z, Chen Y (2017) Ultrastretchable, self-healable hydrogels
based on dynamic covalent bonding and triblock copolymer micellization. ACS Macro Lett
6(8):881–886. https://doi.org/10.1021/acsmacrolett.7b00519
19. Qu J, Zhao X, Liang Y, Zhang T, Ma PX, Guo B (2018) Antibacterial adhesive injectable
hydrogels with rapid self-healing, extensibility and compressibility as wound dressing for joints
skin wound healing. Biomaterials 183:185–199. https://doi.org/10.1016/j.biomaterials.2018.
08.044
20. Song M-M, Wang Y-M, Wang B, Liang X-Y, Chang Z-Y, Li B-J, Zhang S (2018) Super tough,
ultrastretchable hydrogel with multistimuli responsiveness. ACS Appl Mater Interfaces
10:15021. https://doi.org/10.1021/acsami.8b01410
21. Yu X, Qin Z, Wu H, Lv H, Yang X (2019) Tuning hydrogel mechanics by kinetically dependent
cross-linking. Macromolecules 52(3):1249–1256. https://doi.org/10.1021/acs.macromol.
8b02410
22. Xu Z, Li J, Gao G, Wang Z, Cong Y, Chen J, Yin J, Nie L, Fu J (2018) Tough and selfrecoverable hydrogels crosslinked by triblock copolymer micelles and Fe
3+ coordination.
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23. Zhang Hui J, Sun Tao L, Zhang Ao K, Ikura Y, Nakajima T, Nonoyama T, Kurokawa T, Ito O,
Ishitobi H, Gong Jian P (2016) Tough physical double-network hydrogels based on amphiphilic
triblock copolymers. Adv Mater 28(24):4884–4890. https://doi.org/10.1002/adma.201600466
24. Xu D, Xu T, Gao G, Xiao Y, Wang Z, Chen J, Zhou Y, Wang R, Yin J, Fu J (2019) Effect of
solvent–matrix interactions on structures and mechanical properties of micelle-crosslinked gels.
J Polym Sci B Polym Phys 57(8):473–483. https://doi.org/10.1002/polb.24805
25. Chen H, Yang F, Chen Q, Zheng J (2017) A novel design of multi-mechanoresponsive and
mechanically strong hydrogels. Adv Mater 29(21):1606900
26. Lin Y, Qiao Y, Yan Y, Huang J (2009) Thermo-responsive viscoelastic wormlike micelle to
elastic hydrogel transition in dual-component systems. Soft Matter 5(16):3047–3053
27. Mandracchia D, Trapani A, Perteghella S, Di CF, Torre M, Calleri E, Tripodo G (2018) A
micellar-hydrogel nanogrid from a UV crosslinked insulin derivative for the simultaneous
delivery of hydrophobic and hydrophilic drugs. Pharmaceutics 10(3):97
28. Brandrup J, Immergut EH, Grulke EA, Abe A, Bloch DR (1989) Polymer handbook, vol
7. Wiley, New York
29. Liu Z, Calvert P (2000) Multilayer hydrogels as muscle-like actuators. Adv Mater 12
(4):288–291.
https://doi.org/10.1002/(SICI)1521-4095(200002)12:4<288::AIDADMA288>3.0.CO;2-1
30. Lee BP, Konst S (2014) Novel hydrogel actuator inspired by reversible mussel adhesive protein
chemistry. Adv Mater 26(21):3415–3419. https://doi.org/10.1002/adma.201306137
31. Takashima Y, Hatanaka S, Otsubo M, Nakahata M, Kakuta T, Hashidzume A, Yamaguchi H,
Harada A (2012) Expansion-contraction of photoresponsive artificial muscle regulated by hostguest interactions. Nat Commun 3:1270. https://doi.org/10.1038/ncomms2280
32. Yong Q, Kinam P (2001) Environment-sensitive hydrogels for drug delivery. Adv Drug Deliv
Rev 53:321–339
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239
2008.03.023
15. Li L, Lim LH, Wang Q, Jiang SP (2008) Thermoreversible micellization and gelation of a blend
of pluronic polymers. Polymer 49(7):1952–1960. https://doi.org/10.1016/j.polymer.2008.
02.026
16. Sun K, Raghavan SR (2010) Thermogelling aqueous fluids containing low concentrations of
pluronic f127 and laponite nanoparticles. Langmuir 26(11):8015–8020. https://doi.org/10.1021/
la904907b
17. Sun YN, Gao GR, Du GL, Cheng YJ, Fu J (2014) Super tough, ultrastretchable, and
thermoresponsive hydrogels with functionalized triblock copolymer micelles as macro-crosslinkers. ACS Macro Lett 3(5):496–500. https://doi.org/10.1021/mz500221j
18. Wang P, Deng G, Zhou L, Li Z, Chen Y (2017) Ultrastretchable, self-healable hydrogels
based on dynamic covalent bonding and triblock copolymer micellization. ACS Macro Lett
6(8):881–886. https://doi.org/10.1021/acsmacrolett.7b00519
19. Qu J, Zhao X, Liang Y, Zhang T, Ma PX, Guo B (2018) Antibacterial adhesive injectable
hydrogels with rapid self-healing, extensibility and compressibility as wound dressing for joints
skin wound healing. Biomaterials 183:185–199. https://doi.org/10.1016/j.biomaterials.2018.
08.044
20. Song M-M, Wang Y-M, Wang B, Liang X-Y, Chang Z-Y, Li B-J, Zhang S (2018) Super tough,
ultrastretchable hydrogel with multistimuli responsiveness. ACS Appl Mater Interfaces
10:15021. https://doi.org/10.1021/acsami.8b01410
21. Yu X, Qin Z, Wu H, Lv H, Yang X (2019) Tuning hydrogel mechanics by kinetically dependent
cross-linking. Macromolecules 52(3):1249–1256. https://doi.org/10.1021/acs.macromol.
8b02410
22. Xu Z, Li J, Gao G, Wang Z, Cong Y, Chen J, Yin J, Nie L, Fu J (2018) Tough and selfrecoverable hydrogels crosslinked by triblock copolymer micelles and Fe
3+ coordination.
J Polym Sci B Polym Phys 56:865–876. https://doi.org/10.1002/polb.24601
23. Zhang Hui J, Sun Tao L, Zhang Ao K, Ikura Y, Nakajima T, Nonoyama T, Kurokawa T, Ito O,
Ishitobi H, Gong Jian P (2016) Tough physical double-network hydrogels based on amphiphilic
triblock copolymers. Adv Mater 28(24):4884–4890. https://doi.org/10.1002/adma.201600466
24. Xu D, Xu T, Gao G, Xiao Y, Wang Z, Chen J, Zhou Y, Wang R, Yin J, Fu J (2019) Effect of
solvent–matrix interactions on structures and mechanical properties of micelle-crosslinked gels.
J Polym Sci B Polym Phys 57(8):473–483. https://doi.org/10.1002/polb.24805
25. Chen H, Yang F, Chen Q, Zheng J (2017) A novel design of multi-mechanoresponsive and
mechanically strong hydrogels. Adv Mater 29(21):1606900
26. Lin Y, Qiao Y, Yan Y, Huang J (2009) Thermo-responsive viscoelastic wormlike micelle to
elastic hydrogel transition in dual-component systems. Soft Matter 5(16):3047–3053
27. Mandracchia D, Trapani A, Perteghella S, Di CF, Torre M, Calleri E, Tripodo G (2018) A
micellar-hydrogel nanogrid from a UV crosslinked insulin derivative for the simultaneous
delivery of hydrophobic and hydrophilic drugs. Pharmaceutics 10(3):97
28. Brandrup J, Immergut EH, Grulke EA, Abe A, Bloch DR (1989) Polymer handbook, vol
7. Wiley, New York
29. Liu Z, Calvert P (2000) Multilayer hydrogels as muscle-like actuators. Adv Mater 12
(4):288–291.
https://doi.org/10.1002/(SICI)1521-4095(200002)12:4<288::AIDADMA288>3.0.CO;2-1
30. Lee BP, Konst S (2014) Novel hydrogel actuator inspired by reversible mussel adhesive protein
chemistry. Adv Mater 26(21):3415–3419. https://doi.org/10.1002/adma.201306137
31. Takashima Y, Hatanaka S, Otsubo M, Nakahata M, Kakuta T, Hashidzume A, Yamaguchi H,
Harada A (2012) Expansion-contraction of photoresponsive artificial muscle regulated by hostguest interactions. Nat Commun 3:1270. https://doi.org/10.1038/ncomms2280
32. Yong Q, Kinam P (2001) Environment-sensitive hydrogels for drug delivery. Adv Drug Deliv
Rev 53:321–339
Triblock Copolymer Micelle-Crosslinked Hydrogels
239