Scheme 3
Catalytic cycle of Zn-catalyzed aminofluorination proposed on the basis of DFT calculations. Red numbers are calculated Gibbs energies (kcal/mol)
for each intermediate and transition state relative to React
[79]
Mechanisms of Metal-Catalyzed Electrophilic F/CF 3 /SCF 3 Transfer Reactions. . .
45
Catalytic cycle of Zn-catalyzed aminofluorination proposed on the basis of DFT calculations. Red numbers are calculated Gibbs energies (kcal/mol)
for each intermediate and transition state relative to React
[79]
Mechanisms of Metal-Catalyzed Electrophilic F/CF 3 /SCF 3 Transfer Reactions. . .
45