70
3 Heterogeneous and Homogeneous Catalytic Partial Oxidations …
55. Grundner S, Markovits MAC, Li G, Tromp M, Pidko EA, Hensen EJM, Jentys A, SanchezSanchez M, Lercher JA (2015) Single-site trinuclear copper oxygen clusters in mordenite for
selective conversion of methane to methanol. Nat Commun 6:1–8
56. Markovits MAC, Jentys A, Tromp M, Sanchez-Sanchez M, Lercher JA (2016) Effect of location
and distribution of Al sites in ZSM-5 on the formation of Cu-oxo clusters active for direct
conversion of methane to methanol. Top Catal 59:1554–1563
57. Raja R, Ratnasamy P (1997) Direct conversion of methane to methanol. Appl Catal A Gen
158:L7–L15
58. Hammond C, Forde MM, Ab Rahim MH, Thetford A, He Q, Jenkins RL, Dimitratos N,
Lopez-Sanchez JA, Dummer NF, Murphy DM, Carley AF, Taylor SH, Willock DJ, Stangland
EE, Kang J, Hagen H, Kiely CJ, Hutchings GJ (2012) Direct catalytic conversion of methane
to methanol in an aqueous medium by using copper-promoted Fe-ZSM-5. Angew Chem Int
Ed 51:5129–5133
59. Panov GI, Uriarte AK, Rodkin MA, Sobolev VI (1998) Generation of active oxygen species
on solid surfaces. Opportunity for novel oxidation technologies over zeolites. Catal Today
41:365–385
60. Sushkevich VL, Palagin D, Ranocchiari M, van Bokhoven JA (2017) Selective anaerobic
oxidation of methane enables direct synthesis of methanol. Science 356:523–527
61. Wang W, Hunger M (2008) Reactivity of surface alkoxy species on acidic zeolite catalysts.
Acc Chem Res 41:895–904
62. Benlounes O, Mansouri S, Rabia C, Hocine S (2008) Direct oxidation of methane to oxygenates
over heteropolyanions. J Nat Gas Chem 17:309–312
63. Mansouri S, Benlounes Q, Rabia C, Thouvenot R, Bettahar MM, Hocine S (2013) Partial
oxidation of methane over modified Keggin-type polyoxotungstates. J Mol Catal A: Chem
379:255–262
64. Khokhar MD, Shukla RS, Jasra RV (2009) Selective oxidation of methane by molecular oxygen catalyzed by a bridged binuclear ruthenium complex at moderate pressures and ambient
temperature. J Mol Catal A: Chem 299:108–116
65. Shilov AE, Shul’pin GB (1997) Activation of C–H bonds by metal complexes. Chem Rev
3:2879–2932
66. Yamanaka I, Soma M, Otsuka K (1995) Oxidation of methane to methanol with oxygen
catalysed by europium trichloride at room temperature. J Chem Soc Chem Commun 2235–2236
67. Yamanaka I (2002) Reductive activation of O 2 and monooxygenation of hydrocarbons by Eu
catalyst. Catal Surv Asia 6:63–72
68. Yamanaka I, Soma M, Otsuka K (1996) Enhancing effect of titanium(II) for the oxidation of
methane with O2 by an EuCl3-Zn-CF3CO2H-catalytic system at 40 °C. Chem Lett 25:565–566
69. Piao D, Inoue K, Shibasaki H, Taniguchi Y, Kitamura T, Fujiwara Y (1999) An efficient
partial oxidation of methane in trifluoroacetic acid using vanadium-containing heteropolyacid
catalysts. J Organomet Chem 574:116–120
70. Periana RA, Taube DJ, Evitt ER, L ¨
offler DG, Wentrcek PR, Voss G, Masuda T (1993) A
mercury-catalyzed, high-yield system for the oxidation of methane to methanol. Science
259:340–343
71. Sen A, Benvenuto MA, Lin M, Hutson AC, Basickes N (1994) Activation of methane and ethane
and their selective oxidation to the alcohols in protic media. J Am Chem Soc 116:998–1003
72. Jones CJ, Taube D, Ziatdinov VR, Periana RA, Nielsen RJ, Oxgaard J, Goddard WA (2004)
Selective oxidation of methane to methanol catalyzed, with C-H activation, by homogeneous,
cationic gold. Angew Chem Int Ed 43:4626–4629
73. Periana RA, Taube DJ, Gamble S, Taube H, Satoh T, Fujii H (1998) Platinum catalysts for the
high-yield oxidation of methane to a methanol derivative. Science 280:560–564
74. Zimmermann T, Soorholtz M, Bilke M, Schueth F (2016) Selective methane oxidation catalyzed
by platinum salts in oleum at turnover frequencies of large-scale industrial processes. J Am
Chem Soc 138:12395–12400
75. Hashiguchi BG, Konnick MM, Bischof SM, Gustafson SJ, Devarajan D, Gunsalus N, Ess DH,
Periana RA (2014) Main-group compounds selectively oxidize mixtures of methane, ethane,
and propane to alcohol esters. Science 343:1232–1237
3 Heterogeneous and Homogeneous Catalytic Partial Oxidations …
55. Grundner S, Markovits MAC, Li G, Tromp M, Pidko EA, Hensen EJM, Jentys A, SanchezSanchez M, Lercher JA (2015) Single-site trinuclear copper oxygen clusters in mordenite for
selective conversion of methane to methanol. Nat Commun 6:1–8
56. Markovits MAC, Jentys A, Tromp M, Sanchez-Sanchez M, Lercher JA (2016) Effect of location
and distribution of Al sites in ZSM-5 on the formation of Cu-oxo clusters active for direct
conversion of methane to methanol. Top Catal 59:1554–1563
57. Raja R, Ratnasamy P (1997) Direct conversion of methane to methanol. Appl Catal A Gen
158:L7–L15
58. Hammond C, Forde MM, Ab Rahim MH, Thetford A, He Q, Jenkins RL, Dimitratos N,
Lopez-Sanchez JA, Dummer NF, Murphy DM, Carley AF, Taylor SH, Willock DJ, Stangland
EE, Kang J, Hagen H, Kiely CJ, Hutchings GJ (2012) Direct catalytic conversion of methane
to methanol in an aqueous medium by using copper-promoted Fe-ZSM-5. Angew Chem Int
Ed 51:5129–5133
59. Panov GI, Uriarte AK, Rodkin MA, Sobolev VI (1998) Generation of active oxygen species
on solid surfaces. Opportunity for novel oxidation technologies over zeolites. Catal Today
41:365–385
60. Sushkevich VL, Palagin D, Ranocchiari M, van Bokhoven JA (2017) Selective anaerobic
oxidation of methane enables direct synthesis of methanol. Science 356:523–527
61. Wang W, Hunger M (2008) Reactivity of surface alkoxy species on acidic zeolite catalysts.
Acc Chem Res 41:895–904
62. Benlounes O, Mansouri S, Rabia C, Hocine S (2008) Direct oxidation of methane to oxygenates
over heteropolyanions. J Nat Gas Chem 17:309–312
63. Mansouri S, Benlounes Q, Rabia C, Thouvenot R, Bettahar MM, Hocine S (2013) Partial
oxidation of methane over modified Keggin-type polyoxotungstates. J Mol Catal A: Chem
379:255–262
64. Khokhar MD, Shukla RS, Jasra RV (2009) Selective oxidation of methane by molecular oxygen catalyzed by a bridged binuclear ruthenium complex at moderate pressures and ambient
temperature. J Mol Catal A: Chem 299:108–116
65. Shilov AE, Shul’pin GB (1997) Activation of C–H bonds by metal complexes. Chem Rev
3:2879–2932
66. Yamanaka I, Soma M, Otsuka K (1995) Oxidation of methane to methanol with oxygen
catalysed by europium trichloride at room temperature. J Chem Soc Chem Commun 2235–2236
67. Yamanaka I (2002) Reductive activation of O 2 and monooxygenation of hydrocarbons by Eu
catalyst. Catal Surv Asia 6:63–72
68. Yamanaka I, Soma M, Otsuka K (1996) Enhancing effect of titanium(II) for the oxidation of
methane with O2 by an EuCl3-Zn-CF3CO2H-catalytic system at 40 °C. Chem Lett 25:565–566
69. Piao D, Inoue K, Shibasaki H, Taniguchi Y, Kitamura T, Fujiwara Y (1999) An efficient
partial oxidation of methane in trifluoroacetic acid using vanadium-containing heteropolyacid
catalysts. J Organomet Chem 574:116–120
70. Periana RA, Taube DJ, Evitt ER, L ¨
offler DG, Wentrcek PR, Voss G, Masuda T (1993) A
mercury-catalyzed, high-yield system for the oxidation of methane to methanol. Science
259:340–343
71. Sen A, Benvenuto MA, Lin M, Hutson AC, Basickes N (1994) Activation of methane and ethane
and their selective oxidation to the alcohols in protic media. J Am Chem Soc 116:998–1003
72. Jones CJ, Taube D, Ziatdinov VR, Periana RA, Nielsen RJ, Oxgaard J, Goddard WA (2004)
Selective oxidation of methane to methanol catalyzed, with C-H activation, by homogeneous,
cationic gold. Angew Chem Int Ed 43:4626–4629
73. Periana RA, Taube DJ, Gamble S, Taube H, Satoh T, Fujii H (1998) Platinum catalysts for the
high-yield oxidation of methane to a methanol derivative. Science 280:560–564
74. Zimmermann T, Soorholtz M, Bilke M, Schueth F (2016) Selective methane oxidation catalyzed
by platinum salts in oleum at turnover frequencies of large-scale industrial processes. J Am
Chem Soc 138:12395–12400
75. Hashiguchi BG, Konnick MM, Bischof SM, Gustafson SJ, Devarajan D, Gunsalus N, Ess DH,
Periana RA (2014) Main-group compounds selectively oxidize mixtures of methane, ethane,
and propane to alcohol esters. Science 343:1232–1237