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76. Gretz E, Oliver TF, Sen A (1987) Carbon-hydrogen bond activation by electrophilic transitionmetal compounds. Palladium(II)-mediated oxidation of arenes and alkanes including methane.
J Am Chem Soc 109:8109–8111
77. Sen A (1991) Homogeneous palladium(II) mediated oxidation of methane. Plat Metal Rev
35:126–132
78. Muehlhofer M, Strassner T, Herrmann WA (2000) New catalyst systems for the catalytic
conversion of methane into methanol. Angew Chem Int Ed 41:1745–1747
79. Munz D, Myyer D, Strassner T (2013) Methane CH activation by palladium complexes with
chelating bis(NHC) ligands: a DFT study. Organometal 32:3469–3480
80. Vargaftik MN, Stolarov IP, Moiseev II (1990) Highly selective partial oxidation of methane to
methyl trifluoroacetate. J Chem Soc Chem Commun 1049–1050
81. Strassner T, Ahrens S, Muehlhofer M, Munz D, Zeller A (2013) Cobalt-catalyzed oxidation of
methane to methyl trifluoroacetate by dioxygen. Eur J Inorg Chem 21:3659–3663
82. An Z, Pan X, Liu X, Han X, Bao X (2006) Combined redox couples for catalytic oxidation of
methane by dioxygen at low temperatures. J Am Chem Soc 128:16028–16029
83. Yuan J, Wang L, Wang Y (2011) Direct oxidation of methane to a methanol derivative using
molecular oxygen. Ind Eng Chem Res 50:6513–6516
84. Riess JG (2001) Oxygen carriers (“Blood substitutes”)-raison d’etre, chemistry and some
physiology. Chem Rev 101:2797–2920
85. Riess JG (2002) Fluorous micro- and nanophases with a biomedical perspective. Tetrahedron
58:4113–4131
86. Elibol M, Mavituna F (1999) A remedy to oxygen limitation problem in antibiotic production
addition of perfluorocarbon. Biochem Eng J 3:1–7
87. Kozhevnikov IV (1997) PMo 12-n V n O (3+n)- 40 heteropolyanions as catalysts for aerobic
oxidation. J Mol Catal A: Chem 117:151–158
88. Palkovits R, von Malotki C, Baumgarten M, Müllen K, Baltes C, Antonietti M, Kuhn P, Weber
J, Thomas A, Schüth F (2010) Development of molecular and solid catalysts for the direct
low-temperature oxidation of methane to methanol. Chemsuschem 22:277–282
89. Palkovits R, Antonietti M, Kuhn P, Thomas A, Schüth F (2009) Solid catalysts for the selective
low-temperature oxidation of methane to methanol. Angew Chem Int Ed 48:6909–6912
90. Ravi M, Ranocchiari M, van Bokhoven JA (2017) The direct catalytic oxidation of methane to
methanol—a critical assessment. Angew Chem Int Ed 22:16464–16483
91. Conley BL, Tenn WJ, Young KJH, Ganesh SK, Meier SK, Ziatdinov VR, Mironov O, Oxgaard
J, Gonzales J (2006) Goddard III WA, Periana RA. J Mol Catal A 251:8–23
92. Periana RA, Bhalla G, Tenn WJ, Young KJH, Liu XY, Mironov O, Jones CJ, Ziatdinov VR
(2004) J Mol Catal A 220:7–25
93. Furuto T, Takeguchi M, Okura I (1999) Semicontinuous methanol biosynthesis by Methylosinus
trichosporium OB3b. J Mol Catal A: Chem 144:257–261
94. Lee SG, Goo JH, Kim HG, Oh JI, Kim YM, Kim SW (2004) Optimization of methanol
biosynthesis from methane using Methylosinus trichosporium OB3b. Biotechnol Lett 26:947–
950
95. Duan C, Luo M, Xing X (2011) High-rate conversion of methane to methanol by Methylosinus
trichosporium OB3b. Bioresour Technol 102:7349–7353
71
76. Gretz E, Oliver TF, Sen A (1987) Carbon-hydrogen bond activation by electrophilic transitionmetal compounds. Palladium(II)-mediated oxidation of arenes and alkanes including methane.
J Am Chem Soc 109:8109–8111
77. Sen A (1991) Homogeneous palladium(II) mediated oxidation of methane. Plat Metal Rev
35:126–132
78. Muehlhofer M, Strassner T, Herrmann WA (2000) New catalyst systems for the catalytic
conversion of methane into methanol. Angew Chem Int Ed 41:1745–1747
79. Munz D, Myyer D, Strassner T (2013) Methane CH activation by palladium complexes with
chelating bis(NHC) ligands: a DFT study. Organometal 32:3469–3480
80. Vargaftik MN, Stolarov IP, Moiseev II (1990) Highly selective partial oxidation of methane to
methyl trifluoroacetate. J Chem Soc Chem Commun 1049–1050
81. Strassner T, Ahrens S, Muehlhofer M, Munz D, Zeller A (2013) Cobalt-catalyzed oxidation of
methane to methyl trifluoroacetate by dioxygen. Eur J Inorg Chem 21:3659–3663
82. An Z, Pan X, Liu X, Han X, Bao X (2006) Combined redox couples for catalytic oxidation of
methane by dioxygen at low temperatures. J Am Chem Soc 128:16028–16029
83. Yuan J, Wang L, Wang Y (2011) Direct oxidation of methane to a methanol derivative using
molecular oxygen. Ind Eng Chem Res 50:6513–6516
84. Riess JG (2001) Oxygen carriers (“Blood substitutes”)-raison d’etre, chemistry and some
physiology. Chem Rev 101:2797–2920
85. Riess JG (2002) Fluorous micro- and nanophases with a biomedical perspective. Tetrahedron
58:4113–4131
86. Elibol M, Mavituna F (1999) A remedy to oxygen limitation problem in antibiotic production
addition of perfluorocarbon. Biochem Eng J 3:1–7
87. Kozhevnikov IV (1997) PMo 12-n V n O (3+n)- 40 heteropolyanions as catalysts for aerobic
oxidation. J Mol Catal A: Chem 117:151–158
88. Palkovits R, von Malotki C, Baumgarten M, Müllen K, Baltes C, Antonietti M, Kuhn P, Weber
J, Thomas A, Schüth F (2010) Development of molecular and solid catalysts for the direct
low-temperature oxidation of methane to methanol. Chemsuschem 22:277–282
89. Palkovits R, Antonietti M, Kuhn P, Thomas A, Schüth F (2009) Solid catalysts for the selective
low-temperature oxidation of methane to methanol. Angew Chem Int Ed 48:6909–6912
90. Ravi M, Ranocchiari M, van Bokhoven JA (2017) The direct catalytic oxidation of methane to
methanol—a critical assessment. Angew Chem Int Ed 22:16464–16483
91. Conley BL, Tenn WJ, Young KJH, Ganesh SK, Meier SK, Ziatdinov VR, Mironov O, Oxgaard
J, Gonzales J (2006) Goddard III WA, Periana RA. J Mol Catal A 251:8–23
92. Periana RA, Bhalla G, Tenn WJ, Young KJH, Liu XY, Mironov O, Jones CJ, Ziatdinov VR
(2004) J Mol Catal A 220:7–25
93. Furuto T, Takeguchi M, Okura I (1999) Semicontinuous methanol biosynthesis by Methylosinus
trichosporium OB3b. J Mol Catal A: Chem 144:257–261
94. Lee SG, Goo JH, Kim HG, Oh JI, Kim YM, Kim SW (2004) Optimization of methanol
biosynthesis from methane using Methylosinus trichosporium OB3b. Biotechnol Lett 26:947–
950
95. Duan C, Luo M, Xing X (2011) High-rate conversion of methane to methanol by Methylosinus
trichosporium OB3b. Bioresour Technol 102:7349–7353