25 Photoresponsive Molecular Crystals …
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Fig. 25.6 Schematic illustration of the reactions in the mixed crystal of 4 and 5 upon irradiation
with 365 nm and 750 nm light and the bending response of the crystal. Adapted from Ref. [16] with
permission of The Royal Society of Chemistry
(a)
(b)
(c)
(d)
Fig. 25.7 a Molecular structure of 3, b photographs of photoinduced bending behavior of crystal
3, c curvature change as a function of UV irradiation time, and d the initial velocity of curvature
change (V init ) as a function of the power of the incident UV light for crystal 3 (thickness: 6.7 µm).
The power of the incident UV light was 174 (●), 132 (), 91.0 (◆), 70.2 (▲), 52.7 (▼), 44.8 (◯),
35.1 (), 26.3 (◇), 17.6 (), and 8.17 mW cm −2 (▽) for (c). Adapted with permission from Ref.
[21]. Copyright 2017 American Chemical Society
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