8. Morisaki Y, Chujo Y (2011) Through-space conjugated polymers consisting of [2.2]
paracyclophane. Polym Chem 2:1249–1257
9. Morisaki Y, Chujo Y (2012) π-electron-system-layered polymers based on [2.2]
paracyclophane. Chem Lett 41:840–846
10. Morisaki Y, Chujo Y (2019) Planar chiral [2.2]paracyclophanes: optical resolution and transformation to optically active π-stacked molecules. Bull Chem Soc Jpn 92:265–274
11. Mizogami S, Yoshimura S (1985) Synthesis of a new crystalline polymer: polymetacyclophane.
J Chem Soc Chem Commun 1985:1736–1738
12. Guyard L, Audebert P (2001) Synthesis and electrochemical polymerization of bis-dithienyl
cyclophane. Electrochem Commun 3:164–167
13. Guyard L, Audebert P, Dolbier WR Jr, Duan JX (2002) Synthesis and electrochemical polymerization of new oligothiophene functionalized fluorocyclophanes. J Electroanal Chem
537:189–193
14. Salhi F, Lee B, Metz C, Bottomley LA, Collard DM (2002) Influence of π-stacking. On the
redox properties of oligothiophenes: (α-alkyloligo-thienyl)para[2.2]cyclophane. Org Lett
4:3195–3198
15. Salhi F, Collard DM (2003) π-Stacked conjugated polymers: the influence of paracyclophane
π-stacks on the redox and optical properties of a new class of broken conjugated
polythiophenes. Adv Mater 15:81–85
16. Jagtap SP, Collard DM (2010) Multitiered 2D π-stacked conjugated polymers based on pseudogeminal disubstituted [2.2]paracyclophane. J Am Chem Soc 132:12208–12209
17. Cram DJ, Allinger NL (1955) Macro rings. XII. Stereochemical consequences of steric compression in the smallest paracyclophane. J Am Chem Soc 77:6289–6294
18. Rozenberg V, Sergeeva E, Hopf H (2004) Modern cyclophane chemistry. Wiley, Weinheim,
pp 435–462
19. Rowlands GJ (2008) The synthesis of enantiomerically pure [2.2]paracyclophane derivatives.
Org Biomol Chem 6:1527–1534
20. Gibson SE, Knight JD (2003) [2.2]Paracyclophane derivatives in asymmetric catalysis.
Org Biomol Chem 1:1256–1269
21. Aly AA, Brown AB (2009) Asymmetric and fused heterocycles based on [2.2]paracyclophane.
Tetrahedron 65:8055–8089
22. Paradies J (2011) [2.2]Paracyclophane derivatives: synthesis and application in catalysis.
Synthesis 23:3749–3766
23. Pye PJ, Rossen K, Reamer RA, Tsou NN, Volante RP, Reider PJ (1997) A new planar chiral
bisphosphine ligand for asymmetric catalysis: highly enantioselective hydrogenations under
mild conditions. J Am Chem Soc 119:6207–6208
24. Rossen K, Pye PJ, Maliakal A, Volante RP (1997) Kinetic resolution of rac-4,12-dibromo[2.2]
paracyclophane in a palladium [2.2]PHANEPHOS catalyzed amination. J Org Chem
62:6462–6463
25. Zhuravsky R, Starikova Z, Vorontsov E, Rozenberg V (2008) Novel strategy for the synthesis
of chiral pseudo-ortho-substituted Hydrxy[2.2]paracyclophane-based ligands from the resolved
4-bromo-12-hydroxy[2.2]paracyclophane as a parent compound. Tetrahedron-Asymmetry
19:216–222
26. Jiang B, Zhao XL (2004) A simple and efficient resolution of (Æ)-4,12-dihydroxy[2.2]
paracyclophane. Tetrahedron-Asymmetry 15:1141–1143
27. Jones PG, Hillmer J, Hopf H (2003) (S)-4,16-Dihydroxymethyl-[2.2]paracyclophane bis-(1S)camphanoate. Acta Cryst E 59:o24–o25
28. Pamperin D, Hopf H, Syldatk C, Pietzsch M (1997) Synthesis of planar chiral [2.2]
paracyclophanes by biotransformations: kinetic resolution of 4-formyl[2.2]paracyclophane by
asymmetric reduction. Tetrahedron-Asymmetry 8:319–325
29. Pamperin D, Ohse B, Hopf H, Pietzsch M (1998) Synthesis of planar-chiral [2.2]
paracyclophanes by biotransformations: screening for hydrolase activity for the kinetic resolution of 4-acetoxy-[2.2]paracyclophane. J Mol Cat B Enzym 5:317–319
50
Y. Morisaki
paracyclophane. Polym Chem 2:1249–1257
9. Morisaki Y, Chujo Y (2012) π-electron-system-layered polymers based on [2.2]
paracyclophane. Chem Lett 41:840–846
10. Morisaki Y, Chujo Y (2019) Planar chiral [2.2]paracyclophanes: optical resolution and transformation to optically active π-stacked molecules. Bull Chem Soc Jpn 92:265–274
11. Mizogami S, Yoshimura S (1985) Synthesis of a new crystalline polymer: polymetacyclophane.
J Chem Soc Chem Commun 1985:1736–1738
12. Guyard L, Audebert P (2001) Synthesis and electrochemical polymerization of bis-dithienyl
cyclophane. Electrochem Commun 3:164–167
13. Guyard L, Audebert P, Dolbier WR Jr, Duan JX (2002) Synthesis and electrochemical polymerization of new oligothiophene functionalized fluorocyclophanes. J Electroanal Chem
537:189–193
14. Salhi F, Lee B, Metz C, Bottomley LA, Collard DM (2002) Influence of π-stacking. On the
redox properties of oligothiophenes: (α-alkyloligo-thienyl)para[2.2]cyclophane. Org Lett
4:3195–3198
15. Salhi F, Collard DM (2003) π-Stacked conjugated polymers: the influence of paracyclophane
π-stacks on the redox and optical properties of a new class of broken conjugated
polythiophenes. Adv Mater 15:81–85
16. Jagtap SP, Collard DM (2010) Multitiered 2D π-stacked conjugated polymers based on pseudogeminal disubstituted [2.2]paracyclophane. J Am Chem Soc 132:12208–12209
17. Cram DJ, Allinger NL (1955) Macro rings. XII. Stereochemical consequences of steric compression in the smallest paracyclophane. J Am Chem Soc 77:6289–6294
18. Rozenberg V, Sergeeva E, Hopf H (2004) Modern cyclophane chemistry. Wiley, Weinheim,
pp 435–462
19. Rowlands GJ (2008) The synthesis of enantiomerically pure [2.2]paracyclophane derivatives.
Org Biomol Chem 6:1527–1534
20. Gibson SE, Knight JD (2003) [2.2]Paracyclophane derivatives in asymmetric catalysis.
Org Biomol Chem 1:1256–1269
21. Aly AA, Brown AB (2009) Asymmetric and fused heterocycles based on [2.2]paracyclophane.
Tetrahedron 65:8055–8089
22. Paradies J (2011) [2.2]Paracyclophane derivatives: synthesis and application in catalysis.
Synthesis 23:3749–3766
23. Pye PJ, Rossen K, Reamer RA, Tsou NN, Volante RP, Reider PJ (1997) A new planar chiral
bisphosphine ligand for asymmetric catalysis: highly enantioselective hydrogenations under
mild conditions. J Am Chem Soc 119:6207–6208
24. Rossen K, Pye PJ, Maliakal A, Volante RP (1997) Kinetic resolution of rac-4,12-dibromo[2.2]
paracyclophane in a palladium [2.2]PHANEPHOS catalyzed amination. J Org Chem
62:6462–6463
25. Zhuravsky R, Starikova Z, Vorontsov E, Rozenberg V (2008) Novel strategy for the synthesis
of chiral pseudo-ortho-substituted Hydrxy[2.2]paracyclophane-based ligands from the resolved
4-bromo-12-hydroxy[2.2]paracyclophane as a parent compound. Tetrahedron-Asymmetry
19:216–222
26. Jiang B, Zhao XL (2004) A simple and efficient resolution of (Æ)-4,12-dihydroxy[2.2]
paracyclophane. Tetrahedron-Asymmetry 15:1141–1143
27. Jones PG, Hillmer J, Hopf H (2003) (S)-4,16-Dihydroxymethyl-[2.2]paracyclophane bis-(1S)camphanoate. Acta Cryst E 59:o24–o25
28. Pamperin D, Hopf H, Syldatk C, Pietzsch M (1997) Synthesis of planar chiral [2.2]
paracyclophanes by biotransformations: kinetic resolution of 4-formyl[2.2]paracyclophane by
asymmetric reduction. Tetrahedron-Asymmetry 8:319–325
29. Pamperin D, Ohse B, Hopf H, Pietzsch M (1998) Synthesis of planar-chiral [2.2]
paracyclophanes by biotransformations: screening for hydrolase activity for the kinetic resolution of 4-acetoxy-[2.2]paracyclophane. J Mol Cat B Enzym 5:317–319
50
Y. Morisaki