high intensity CPL, with high quantum efficiency, and have high anisotropy as well
in other chiral scaffolds. The author believes that the planar chiral [2.2]
paracyclophane skeleton is an ideal scaffold for developing materials exhibiting
strong CPL.
References
1. Vögtle F (1993) Cyclophane chemistry: synthesis, structures and reactions. Wiley, Chichester
2. Gleiter R (2004) In: Hopf H (ed) Modern cyclophane chemistry. Wiley, Weinheim
3. Brown CJ, Farthing AC (1949) Preparation and Structure of Di-p-xylylene. Nature
164:915–916
4. Cram DJ, Steinberg H (1951) Macro rings. I. Preparation and spectra of the paracyclophanes.
J Am Chem Soc 73:5691–5704
5. Morisaki Y, Chujo Y (2006) Through-space conjugated polymers based on cyclophanes.
Angew Chem Int Ed 45:6430–6437
6. Morisaki Y, Chujo Y (2008) Cyclophane-containing polymers. Prog Polym Sci 33:346–364
7. Morisaki Y, Chujo Y (2009) Synthesis of π-stacked polymers on the basis of [2.2]
paracyclophane. Bull Chem Soc Jpn 8:1070–1082
Fig. 3.21 Simulations of the transition dipole moments of (S p )-18 and (S p )-16 in the excited states
by using the TD-DFT calculations at the ωB97XD/6-31G(d,p) level of theory with following
options: TD ¼ (N States ¼ 10, Root ¼ 1), SCRF ¼ (SOLVENT ¼ Chloroform). Lengths of the
dipole moments on the structures are based on the atomic units
3 Circularly Polarized Luminescence from Planar Chiral Compounds Based on. . .
49
in other chiral scaffolds. The author believes that the planar chiral [2.2]
paracyclophane skeleton is an ideal scaffold for developing materials exhibiting
strong CPL.
References
1. Vögtle F (1993) Cyclophane chemistry: synthesis, structures and reactions. Wiley, Chichester
2. Gleiter R (2004) In: Hopf H (ed) Modern cyclophane chemistry. Wiley, Weinheim
3. Brown CJ, Farthing AC (1949) Preparation and Structure of Di-p-xylylene. Nature
164:915–916
4. Cram DJ, Steinberg H (1951) Macro rings. I. Preparation and spectra of the paracyclophanes.
J Am Chem Soc 73:5691–5704
5. Morisaki Y, Chujo Y (2006) Through-space conjugated polymers based on cyclophanes.
Angew Chem Int Ed 45:6430–6437
6. Morisaki Y, Chujo Y (2008) Cyclophane-containing polymers. Prog Polym Sci 33:346–364
7. Morisaki Y, Chujo Y (2009) Synthesis of π-stacked polymers on the basis of [2.2]
paracyclophane. Bull Chem Soc Jpn 8:1070–1082
Fig. 3.21 Simulations of the transition dipole moments of (S p )-18 and (S p )-16 in the excited states
by using the TD-DFT calculations at the ωB97XD/6-31G(d,p) level of theory with following
options: TD ¼ (N States ¼ 10, Root ¼ 1), SCRF ¼ (SOLVENT ¼ Chloroform). Lengths of the
dipole moments on the structures are based on the atomic units
3 Circularly Polarized Luminescence from Planar Chiral Compounds Based on. . .
49