83
56. Paskevicius M, Jepsen LH, Schouwink P, Cerny R, Ravnsbaek DB, Filinchuk Y, Dornheim M,
Besenbacher F, Jensen TR (2017) Metal Borohydrides and derivatives - synthesis, structure,
and properties. Chem Soc Rev 46:1565
57. Udovic TJ, Matsuo M, Unemoto A, Verdal N, Stavila V, Skripov AV, Rush JJ, Takamura
H, Orimo S-I (2014) Sodium superionic conduction in Na2B12H12. Chem Commun
50:3750–3752
58. Kweon KE, Varley JB, Shea P, Adelstein N, Mehta P, Heo TW, Udovic TJ, Stavila V, Wood BC
(2017) Structural, chemical, and dynamical frustration: origins of Superionic conductivity in
closo-borate solid electrolytes. Chem Mater 29(21):9142–9153
59. Tang WS, Matsuo M, Wu H, Stavila V, Zhou W, Talin AA, Sonloninin AV, Skoryunov RV,
Babanova OA, Skripov AV, Unemoto A, Orimo S-I, Udovic TJ (2016) Liquid-like ionic conduction in solid lithium and solid monocarba-closo-decaborates near or at room temperature.
Adv Energy Mater 6:1502237
60. Tang WS, Yoshida K, Soloninin AV, Skoryunov RV, Babanova OA, Skripov AV, Dimitrievska
M, Stavila V, Orimo S-I, Udovic TJ (2016) Stabilizing superionic-conducting structures via
mixed-anion solid solutions of monocarba-closo-borate salts. ACS Energy Lett 1(4):659–664
61. Duchêne L, Kühnel RS, Stilp E, Cuervo Reyes E, Remhof A, Hagemann H, Battaglia C (2017)
A stable 3 V all-solid-state sodium–ion battery based on a closo-borate electrolyte. Energy
Environ Sci 10(12):2609–2615
62. Duchêne L, Kühnel RS, Rentsch D, Remhof A, Hagemann H, Battaglia C (2017) A highly
stable sodium solid-state electrolyte based on a dodeca/deca-borate equimolar mixture. Chem
Commun 53(30):4195–4198
63. Cairns EJ, Dunning JS (1976) High-temperature batteries. General Motors Corporation,
Detroit, MI
64. Ellis BL, Nazar LF (2012) Sodium and sodium-ion energy storage batteries. Curr Opinion
Solid State Mater Sci 16:168–177
65. Doughty DH, Butler PC, Akhil AA, Clark NH, Boyes JD (2010) Batteries for large-scale stationary electrical energy storage. Electrochem Soc Interface 19(3):49–53
66. Wei S, Xu S, Agrawral A, Choudhury S, Lu Y, Tu Z, Ma L, Archer LA (2016) A stable roomtemperature sodium-sulfur battery. Nat Commun 7:1–10
67. Lu X, Kirby BW, Xu W, Li G, Kim JY, Lemmon JP, Sprenkle VL, Yang Z (2013) Advanced
intermediate-temperature Na–S battery. Energy Environ Sci 6(1):299–306
68. Chang H-J, Lu X, Bonnett JF, Canfield NL, Son S, Park Y-C, Jung K, Sprenkle V, Li G (2018)
“Ni-less” cathodes for high energy density, intermediate temperature Na-NiCl2 batteries. Adv
Mater Interfaces 5(10):1701592
69. Kim J, Jo SH, Bhavaraju S, Eccleston A, Kang SO (2015) Low temperature performance
of sodium-nickel chloride batteries with NaSICON solid electrolyte. J Electroanal Chem
759:201–206
70. Kim J, Jo SH, Kim J-S, Bhavaraju S, Kang SO (2016) Investigation of manufacturing parameters for NaCl-Ni granule type cathodes used in low temperature NaSICON sodium-metal
chloride batteries. J Alloy Compd 665:288–293
71. Lu X, Lemmon JP, Kim JY, Sprenkle VL, Yang Z (2013) High energy density Na-S/NiCl2
hybrid battery. J Power Sources 224:312–316
72. Ratnakumar BV, Di Steefano S, Halpert G (1990) Electrochemistry of metal chloride cathodes
in sodium batteries. J Electrochem Soc 137(10):2991–2997
73. Ratnakumar BV, Attia AI, Halpert G (1991) Sodium-metal chloride battery research at the Jet
Propulsion Laboratory (JPL). J Power Sources 36(3):385–394
74. Yang Z, Zhang J, Kintner-Meyer MCW, Lu X, Choi D, Lemmon JP, Liu J (2011) Electrochemical
energy storage for green grid. Chem Rev 111(5):3577–3613
75. Virkar AV (2008) A high temperature electrochemical energy storage system based on sodium
beta"-alumina solid electrolyte (BASE). Department of Energy, The University Of Utah, Salt
Lake City
Molten Sodium Batteries
56. Paskevicius M, Jepsen LH, Schouwink P, Cerny R, Ravnsbaek DB, Filinchuk Y, Dornheim M,
Besenbacher F, Jensen TR (2017) Metal Borohydrides and derivatives - synthesis, structure,
and properties. Chem Soc Rev 46:1565
57. Udovic TJ, Matsuo M, Unemoto A, Verdal N, Stavila V, Skripov AV, Rush JJ, Takamura
H, Orimo S-I (2014) Sodium superionic conduction in Na2B12H12. Chem Commun
50:3750–3752
58. Kweon KE, Varley JB, Shea P, Adelstein N, Mehta P, Heo TW, Udovic TJ, Stavila V, Wood BC
(2017) Structural, chemical, and dynamical frustration: origins of Superionic conductivity in
closo-borate solid electrolytes. Chem Mater 29(21):9142–9153
59. Tang WS, Matsuo M, Wu H, Stavila V, Zhou W, Talin AA, Sonloninin AV, Skoryunov RV,
Babanova OA, Skripov AV, Unemoto A, Orimo S-I, Udovic TJ (2016) Liquid-like ionic conduction in solid lithium and solid monocarba-closo-decaborates near or at room temperature.
Adv Energy Mater 6:1502237
60. Tang WS, Yoshida K, Soloninin AV, Skoryunov RV, Babanova OA, Skripov AV, Dimitrievska
M, Stavila V, Orimo S-I, Udovic TJ (2016) Stabilizing superionic-conducting structures via
mixed-anion solid solutions of monocarba-closo-borate salts. ACS Energy Lett 1(4):659–664
61. Duchêne L, Kühnel RS, Stilp E, Cuervo Reyes E, Remhof A, Hagemann H, Battaglia C (2017)
A stable 3 V all-solid-state sodium–ion battery based on a closo-borate electrolyte. Energy
Environ Sci 10(12):2609–2615
62. Duchêne L, Kühnel RS, Rentsch D, Remhof A, Hagemann H, Battaglia C (2017) A highly
stable sodium solid-state electrolyte based on a dodeca/deca-borate equimolar mixture. Chem
Commun 53(30):4195–4198
63. Cairns EJ, Dunning JS (1976) High-temperature batteries. General Motors Corporation,
Detroit, MI
64. Ellis BL, Nazar LF (2012) Sodium and sodium-ion energy storage batteries. Curr Opinion
Solid State Mater Sci 16:168–177
65. Doughty DH, Butler PC, Akhil AA, Clark NH, Boyes JD (2010) Batteries for large-scale stationary electrical energy storage. Electrochem Soc Interface 19(3):49–53
66. Wei S, Xu S, Agrawral A, Choudhury S, Lu Y, Tu Z, Ma L, Archer LA (2016) A stable roomtemperature sodium-sulfur battery. Nat Commun 7:1–10
67. Lu X, Kirby BW, Xu W, Li G, Kim JY, Lemmon JP, Sprenkle VL, Yang Z (2013) Advanced
intermediate-temperature Na–S battery. Energy Environ Sci 6(1):299–306
68. Chang H-J, Lu X, Bonnett JF, Canfield NL, Son S, Park Y-C, Jung K, Sprenkle V, Li G (2018)
“Ni-less” cathodes for high energy density, intermediate temperature Na-NiCl2 batteries. Adv
Mater Interfaces 5(10):1701592
69. Kim J, Jo SH, Bhavaraju S, Eccleston A, Kang SO (2015) Low temperature performance
of sodium-nickel chloride batteries with NaSICON solid electrolyte. J Electroanal Chem
759:201–206
70. Kim J, Jo SH, Kim J-S, Bhavaraju S, Kang SO (2016) Investigation of manufacturing parameters for NaCl-Ni granule type cathodes used in low temperature NaSICON sodium-metal
chloride batteries. J Alloy Compd 665:288–293
71. Lu X, Lemmon JP, Kim JY, Sprenkle VL, Yang Z (2013) High energy density Na-S/NiCl2
hybrid battery. J Power Sources 224:312–316
72. Ratnakumar BV, Di Steefano S, Halpert G (1990) Electrochemistry of metal chloride cathodes
in sodium batteries. J Electrochem Soc 137(10):2991–2997
73. Ratnakumar BV, Attia AI, Halpert G (1991) Sodium-metal chloride battery research at the Jet
Propulsion Laboratory (JPL). J Power Sources 36(3):385–394
74. Yang Z, Zhang J, Kintner-Meyer MCW, Lu X, Choi D, Lemmon JP, Liu J (2011) Electrochemical
energy storage for green grid. Chem Rev 111(5):3577–3613
75. Virkar AV (2008) A high temperature electrochemical energy storage system based on sodium
beta"-alumina solid electrolyte (BASE). Department of Energy, The University Of Utah, Salt
Lake City
Molten Sodium Batteries